574 results about "Trisodium citrate" patented technology

The invention relates to the technical field of cosmetics, and provides a composition containing a dendrobium officinale enzymolysis extract, which is prepared from the following components in percentage by mass: 18 to 22 percent of dendrobium officinale enzymolysis extract, 9 to 11 percent of chitosan oligosaccharide, 6.5 to 7.5 percent of bionic moisturizing enhancer, 0.1 to 0.2 percent of sodium alginate, 0.05 to 0.15 percent of citric acid / sodium citrate buffer pair and 60.4 to 65.4 percent of solvent matrix. By combining low-temperature enzymolysis with a biological purification process, efficient extraction of dendrobium candidum polysaccharides and phenolic substances is realized, dendrophenol oxidation inactivation caused by high temperature can be effectively avoided, hydrochloric acid residues in chitosan oligosaccharide preparation are effectively removed, formula irritation is remarkably reduced, and the dendrobium candidum extract is more suitable for sensitive skin care; the components in the composition have a synergistic effect, the dendrobium officinale enzymolysis extract and the enzymolysis chitosan oligosaccharide form a composite moisturizing network, the moisturizing rate is remarkably increased, the oxidation resistance is remarkably improved, and the composition can be applied to products such as essence, masks and freeze-dried powder.

The invention discloses a preparation method of a silicon-based quantum dot tracer. The silicon-based quantum dot tracer agent disclosed by the invention is prepared by taking 3-aminopropyltrimethoxysilane, sodium citrate, urea and deionized water as raw materials and adopting a hydrothermal synthesis method. The silicon-based quantum dot tracer agent is synthesized by using 3-aminopropyltrimethoxysilane as a silicon source and using the synergistic effect of double reducing agents of sodium citrate and urea, the synthesized silicon-based quantum dot tracer agent can overcome the influence of temperature and environment on the silicon-based quantum dot tracer agent, the fluorescence lifetime is prolonged, and the silicon-based quantum dot tracer agent has a relatively small particle size and can be used for preparing the quantum dot tracer agent. And inter-well tracer testing and single-well chemical testing technology research of an on-site oil field are facilitated.

The invention discloses a paclitaxel drug resistance SERS (Surface Enhanced Raman Scattering) substrate and a detection method. Belongs to the technical field of drug resistance detection. The SERS substrate is mixed with ultrapure water after centrifuging a silver nanoparticle-sodium citrate suspension, and the mixture is dropwise added to a silicon wafer and dried to form a coffee ring structure. During detection, cancer tissue crushing liquid is dropwise added to the center of the substrate, SERS signals are collected through a Raman spectrometer and compared with a pre-established drug resistance / sensitivity spectrum database, and drug resistance is judged according to characteristic peaks at 820 cm <-1 >, 1180 cm <-1 >, 1270 cm <-1 > and 1450 cm <-1 >. The method is easy and convenient to operate, short in detection time (within 10 minutes), high in sensitivity and suitable for rapid screening of paclitaxel drug resistance of breast cancer patients.

The invention belongs to the field of conductive films, and discloses a preparation method of a conductive film based on PEDOT: PSS and silver nanowires, and the preparation method specifically comprises the following steps: after carrying out surface hydroxylation treatment on the silver nanowires AgNWs, under the action of a silane coupling agent 3-(trimethoxymethylsilyl) propyl methacrylate TMSPMA, mixing the silver nanowires AgNWs with PEDOT: PSS to prepare a PEDOT: PSS / AgNWs base solution; the preparation method comprises the following steps: adjusting the pH value of a base solution to be nearly neutral through sodium citrate, then mixing the base solution with a PEA emulsion, carrying out spin coating to form a film, and finally, carrying out ultrafast laser treatment to improve the conductivity so as to obtain the conductive film based on PEDOT: PSS and silver nanowires. The conductive film provided by the invention has high conductivity (gt; 1200 S / cm), good stability and excellent mechanical properties, and is suitable for a flexible electronic device and stable work in a certain humidity environment.

The invention provides a chemical nickel-plating solution based on microcapsules and a method for preparing a coating. The chemical nickel-plating solution based on the microcapsules comprises the following components: 20-30g / L of nickel sulfate hexahydrate; 15-20 g / L of sodium hypophosphite; 10 to 15g / L of trisodium citrate; 2-5 g / L of microcapsules; 10-15 g / L of a stabilizer; the pH regulator is used for regulating the pH value to 4.5 to 5.0; and the balance of deionized water. According to the invention, the microcapsules containing the same components as the chemical nickel plating solution are introduced, so that the automatic repairing function of the coating after being damaged is realized. The coating has high mechanical strength and excellent self-repairing characteristic, and is suitable for surface protection of industrial equipment needing long service life and corrosion resistance.

The invention discloses collagen polypeptide firming and anti-wrinkle freeze-dried powder, and relates to the technical field of cosmetics. The invention relates to a biological preservative which is prepared from water, butanediol, a bacillus / soybean fermentation product extract, soluble collagen, acetyl hexapeptide-8, panthenol, 1, 2, 4-trimethyl-1, 3-pentanediol and a proper amount of water. The cosmetic is prepared from 1, 2-hexanediol, tetrahydromethylpyrimidine carboxylic acid, hydroxypropyl tetrahydropyrantriol, tremella polysaccharide, saccharide isomeride, a bifidus yeast fermentation product lysate, sodium hyaluronate, DNA sodium, a radix gentianae extract, mannitol, palmitoyl tripeptide-1, palmitoyl tetrapeptide-7, oligopeptide-1, decapeptide-4, oligopeptide-3, hydrolyzed royal jelly protein, folic acid and disodium hydrogen phosphate. The additive is composed of sodium dihydrogen phosphate, citric acid and sodium citrate. The mask can provide rich nutrients for skin, deeply care the skin, moisturize and relieve the skin, tighten the skin, resist wrinkles and make the skin moisturized, glossy, elastic and tight, and is high in use safety and wide in application prospect.

The invention relates to a stainless steel flux-cored wire and a preparation method thereof, and relates to the technical field of flux-cored wires. The stainless steel flux-cored wire comprises a stainless steel strip and a double-layer flux core, the stainless steel strip is filled with the double-layer flux core, and the filling amount of the double-layer flux core accounts for 20-25% of the total mass of the stainless steel flux-cored wire; the double-layer flux core comprises a rapid reaction layer and an alloy transition layer, the rapid reaction layer comprises an oil stain oxidizing agent, the oil stain oxidizing agent comprises a high-temperature decomposition type organic matter and an inorganic composition, and the inorganic composition comprises copper oxide and ferric oxide with the mass ratio being (1-1.5): 1. The high-temperature decomposition type organic matter comprises polytetrafluoroethylene micro powder and trisodium citrate according to the mass ratio of 1: (3-5), and the alloy transition layer comprises 316L stainless steel powder, metal powder, silicon powder, niobium carbide and rare earth oxide. The invention can effectively avoid hydrogen embrittlement caused by diffusible hydrogen easily formed by compounds in anti-rust oil remaining on the surface of the welding wire during welding and entering a welding seam.

The invention discloses a method for preparing an iridescent cuprous oxide nanoparticle photonic crystal, which is characterized in that monodisperse spherical particles are obtained through a method for controlling the crystal form of cuprous oxide nanoparticles, so that the monodisperse spherical particles can be self-assembled into a three-dimensional ordered photonic crystal structure, thereby generating gorgeous iridescent color. The invention relates to a method for preparing iridescent cuprous oxide nanoparticle photonic crystals, which adopts monodisperse spherical cuprous oxide nanoparticles with a polycrystalline structure as a structural unit, and is synthesized by the following steps: 1) dissolving high-molecular-weight polyvinylpyrrolidone, trisodium citrate and soluble bivalent copper salt in a mixed solvent of polyethylene glycol and water; stirring until the materials are completely dissolved; (2) dropwise adding a strong alkali solution into the solution prepared in the step (1), vigorously stirring, quickly adding a reducing agent, and stopping after the reaction is completed under stirring; and 3) separating a reaction product, washing and drying in vacuum.

The invention provides high-sphericity nanogold sol and a preparation method thereof, and belongs to the field of nanomaterials, according to the preparation method, the nanogold sol is prepared from a base solution, a gold source precursor, a morphology stabilizer, a reducing agent, a nucleating agent and a protective agent under the heating condition, and the high-sphericity nanogold sol is obtained by accurately controlling reaction conditions, reagent types and concentrations. The high-sphericity nanogold sol can be prepared by adjusting the usage ratio of the tannic acid to the reducing agent and the adding time of the tannic acid, the growth speed of the nanogold sol is increased and the size distribution is reduced through the combined action of the citric acid / sodium citrate dual reducing agent, and the content of the tannic acid in the nanogold sol is increased by adjusting the usage ratio of the tannic acid to the reducing agent and the adding time of the tannic acid. The generation speed and size of the crystal nucleus are controlled, so that the effect of regulating and controlling the size is achieved. The prepared nanogold sol is high in stability and low in biotoxicity, raw materials are non-toxic and pollution-free, and the nanogold sol can be applied to the field of biomedical treatment.

The invention provides a separation and purification method of urokinase, and relates to the technical field of separation and extraction. The separation and purification method comprises the following steps: S1, regulating the pH value of male urine to 8.5, standing, and taking supernate; s2, mixing the supernate with an adsorption material, and eluting with an eluent to obtain a urokinase crude product solution; the adsorption material is a core-shell silica gel polymer, Fe3O4atSiO2-NH2 is taken as a core, and polystyrene is taken as a shell; the eluent is a sodium citrate buffer solution with the concentration of 0.5 to 0.15 M, acetonitrile with the concentration of 1 to 5 weight percent and EDTA (Ethylene Diamine Tetraacetic Acid) with the concentration of 0.5 to 1.5 mM; and S3, carrying out anion exchange column chromatography on the urokinase crude product solution, eluting with an eluent, and precipitating to obtain the urokinase. The urokinase prepared by the method has the advantages of high polymer urokinase content, high recovery rate and high activity yield.

The invention discloses a nitrogen-containing carbon hollow sphere supported cobalt-based catalyst as well as a preparation method and application thereof, and belongs to the technical field of catalyst preparation. According to the preparation method, ammonia water, tetraethyl orthosilicate, polyoxyethylene polyoxypropylene ether triblock copolymer, resorcinol and a formaldehyde solution are fully reacted in a mixed solvent of deionized water and ethanol by virtue of a template method, and the nitrogen-containing carbon hollow spheres are obtained after calcination and etching; then carrying out surface modification on the nitrogen-containing carbon hollow spheres, and uniformly loading cobalt metal by virtue of the structure guiding effect of hexamethyleneimine and sodium citrate dehydrate; the prepared nitrogen-containing carbon hollow sphere supported cobalt-based catalyst has abundant highly-exposed Co-N-C active sites, has wide substrate universality, has good catalytic activity and selectivity for amination reactions with various long-chain fatty aldehydes, fatty ketones, cyclic fatty ketones, aromatic aldehydes and ketones as raw materials, and can realize efficient catalytic amination reactions of carbonyl compounds.

The invention provides a copper-nickel alloy foil and a preparation method and application thereof, and belongs to the technical field of lithium ion battery negative electrode current collectors, and the preparation method comprises the following steps: preparing a copper-nickel composite electrolyte, and adding a coordination agent, a pH buffer agent and an additive into the copper-nickel composite electrolyte to obtain a mixed electrolyte; the coordination agent comprises a main coordination agent and an auxiliary coordination agent, and the main coordination agent comprises at least one of trisodium citrate, potassium sodium tartrate and sodium pyrophosphate; the auxiliary coordination agent comprises at least one of ammonia water, glycine and triethanolamine; and a cathode and an anode are placed in the mixed electrolyte, the pH of the mixed electrolyte is controlled to be 6-10, direct current is applied for electrochemical deposition, and the copper-nickel alloy foil is obtained. According to the method, the alkalescence system is adopted, the main coordination agent and the auxiliary coordination agent are used, full coordination of free Cu < 2 + > and Ni < 2 + > is achieved, precipitation is avoided, the hydrogen evolution phenomenon is greatly reduced, and the alloy foil quality is improved.

The invention discloses nano-engineered microalgae for photoimmunotherapy of melanoma and a preparation method of the nano-engineered microalgae. The preparation method comprises the following steps: S1, respectively putting tannic acid, potassium carbonate, sodium citrate and HAuCl4. 3H2O into water to prepare a tannic acid solution with the concentration of 4.3 mg / mL, a potassium carbonate solution with the concentration of 20.7 mg / mL, a sodium citrate reduction solution with the concentration of 0.7 mg / mL and a HAuCl4 solution with the concentration of 10.0 mg / mL; s2, dissolving a tannic acid solution and a potassium carbonate solution in the sodium citrate reduction solution to obtain a mixed solution; s3, the mixed solution is heated under stirring, a HAuCl4 solution is dropwise added, stirring continues, and AuNP is obtained; and S4, mixing the AuNP obtained in the step S3 with the microalgae PCC 7942, standing, incubating, and centrifugally washing, so as to obtain the nano-engineered microalgae PCC-coated AuNP. The functionalized microalgae drug delivery system (PCC-coated AuNP) prepared by the invention has the performance of respectively generating O2 and H2 through photosynthesis and photocatalytic reaction under the irradiation of 635 nm red light.

The invention relates to the technical field of nano-enzyme preparation and electrochemical and colorimetric dual-mode sensing, and particularly discloses a Mn3Fe2.7-atC nano-enzyme, a preparation method thereof and application of the Mn3Fe2.7-atC nano-enzyme in determination of amoxicillin content. The preparation method of the Mn3Fe2.7 at C nano-enzyme is characterized by comprising the following steps: dissolving manganese chloride and trisodium citrate in water to prepare a solution A; dissolving potassium ferricyanide in water to prepare a solution B; adding the solution B into the solution A under a stirring condition, continuously stirring for 16-32 hours after the solution B is added, carrying out suction filtration, and drying the obtained precipitate to obtain a ferromanganese prussian blue analogue precursor; and placing the ferromanganese prussian blue analogue precursor in a tubular furnace, carrying out pyrolysis, and after the pyrolysis is finished, carrying out acid soaking, washing and drying to obtain the Mn3Fe2.7 at C nano-enzyme. When the Mn3Fe2.7 (at) C nano-enzyme is used for measuring the content of amoxicillin, the accuracy is good, and meanwhile, the Mn3Fe2.7 (at) C nano-enzyme has the advantages of interference resistance, stability, good recovery rate and the like.

The invention discloses a zinc-bromine flow battery multifunctional electrolyte and a preparation method thereof, and belongs to the technical field of electrochemical energy storage, and the method comprises the following steps: dissolving an electrolyte in a solvent, and sequentially adding a supporting electrolyte, a positive electrode complexing agent and a positive electrode additive to obtain a positive electrode electrolyte; the positive electrode additive is zinc iodide; i <-> in zinc iodide and Br2 in a Br2 / Br <-> reaction system form mixed halide ions, so that the bromine resistance function is achieved, and the overall conductivity and comprehensive electrochemical performance of the electrolyte are improved; dissolving an electrolyte in a solvent, and sequentially adding a supporting electrolyte and a first negative electrode additive to obtain a negative electrode electrolyte; the first negative electrode additive comprises sodium acetate and sodium citrate; sodium acetate and sodium citrate are combined to form a wide-range buffer system, the pH value of the electrolyte can be dynamically adjusted and stabilized, the long-term stability of the battery is improved, the cycle life is prolonged, and the positive electrode electrolyte and the negative electrode electrolyte form the multifunctional electrolyte for the zinc-bromine flow battery; and the zinc deposition behavior is cooperatively regulated and controlled through sodium salt buffering and ion coordination.

The present invention discloses a preparation method and production system for sodium nitroprusside. The preparation process comprises the following steps: first, reacting ferrocyanide with nitric acid to obtain a hydrogen nitroprusside aqueous solution; adding alcohol to the concentrated hydrogen nitroprusside aqueous solution to remove inorganic salts generated by the reaction, thereby obtaining a hydrogen nitroprusside alcohol solution; then, adding trisodium citrate to the hydrogen nitroprusside alcohol solution to react to obtain sodium nitroprusside and disodium citrate; separating and removing the citrate to obtain a sodium nitroprusside alcohol solution; and finally, concentrating, crystallizing, separating, and drying the sodium nitroprusside alcohol solution to obtain a sodium nitroprusside product. The present invention also provides a production system based on the preparation method. The production method of the present invention is simple to operate, operates under mild conditions, has a short production cycle, effectively prevents product oxidation, and has high purity. The obtained product is suitable for industrial production, and the production system requires less equipment and has low equipment requirements.

According to the method for preparing the nanocrystalline nickel foil through the electro-deposition method and the nanocrystalline nickel foil prepared through the method, a nickel plate serves as an anode, a titanium plate serves as a cathode, the anode and the cathode are both placed in electrolyte, and the nanocrystalline nickel foil is prepared on the titanium plate through electro-deposition by adopting a pulse power source; the electrolyte comprises water and the following components by concentration: 300-500g / L of nickel sulfate; 5-15 g / L of nickel chloride; 0.01 to 0.2 g / L of a wetting agent; 20-60 g / L of a buffer agent; 0.05-2 g / L of a brightener; the pH value of the electrolyte is 2-4, and the electro-deposition temperature is 40-60 DEG C; the buffering agent is selected from one or two of citric acid and sodium citrate; and the brightener is selected from one or more of butynediol propoxide, butynediol ethoxylate, sodium sulfopropyne ether, propynol ethoxylate and glycerol monopropyne ether. Based on the method, the problem that in the prior art, the nickel foil prepared through an electro-deposition method is large in fine grain size is solved.

The invention relates to the technical field of fluorescent hydrogel, in particular to high-strength and high-stability fluorescent hydrogel as well as a preparation method and application thereof, the fluorescent hydrogel is formed by physical crosslinking of a hydrogel matrix, a rare earth fluorescent complex and a stabilizer, the hydrogel matrix is of a double-network structure formed by physical crosslinking of polyvinyl alcohol and carboxymethyl cellulose; the rare earth fluorescent complex is formed by connecting rare earth metal ions and an organic antenna material through coordination; the stabilizer is trisodium citrate. Compared with other fluorescent hydrogel, the fluorescent hydrogel with high strength and high stability provided by the invention has the advantages that the phenomena of fluorescence decay and fluorescence quenching caused by metal ions and saturated salt solution are avoided, and the fluorescence is kept stable in a wide pH range. Because the fluorescence characteristic is not influenced by environmental corrosion factors, the information can be stably displayed for a long time, and the method can be used for information encryption and anti-counterfeiting in an extreme environment.

The invention discloses a preparation process of a strong hygroscopic slow-release fertilizer based on resin gel, which comprises the following steps: uniformly and fully mixing modified plant fiber and a fertilizer body according to a weight ratio of 3: 5, then adding a diatomite agent accounting for 10-15% of the total amount of the modified plant fiber, and fully stirring to obtain the strong hygroscopic slow-release fertilizer based on the resin gel. According to the strong-hygroscopicity slow-release fertilizer based on the resin gel, modified plant fibers and a fertilizer body are matched, then a diatomite agent is used for blending and improving, the modified plant fibers are prepared into an additive by performing thermal improvement on nano attapulgite, blending biomass carbon and a sodium citrate solution, and the additive is matched with raw materials such as titanium oxide to prepare a modified liquid.

The invention discloses a phage inhibitor and application thereof. The phage inhibitor is prepared from the following components in parts by weight: 30 to 60 parts of carboxymethylated hippophae rhamnoides polysaccharide, 1.8 to 2.2 parts of citric acid, 2.3 to 2.7 parts of sodium citrate, 0.8 to 1.2 parts of D-sodium gluconate, 4 to 6 parts of dihydroxyethyl glycine, 1.8 to 2.2 parts of sodium hexametaphosphate and 0.8 to 1.2 parts of oxalic acid, and the amount of sodium hydroxide is added according to the pH value during solution preparation. The product is designed into a mixed prefabricated product; or liquid with various concentrations can be prepared and diluted according to needs during use. When the product is applied to a prokaryotic expression system, the pollution of phage to cells can be effectively inhibited, the efficiency and quality of scientific research and production are remarkably improved, and a more leisurely fermentation environment is provided for scientific research personnel. Meanwhile, the carboxymethylated sea-buckthorn polysaccharide, the citric acid, the sodium citrate and the oxalic acid contained in the phage inhibitor have a synergistic effect, so that the inhibition effect of the phage inhibitor on the phage can be remarkably improved.

The invention discloses a preparation process of a rare earth precipitation resistant electrophoretic coating for an automobile body. The preparation process comprises the following steps: S1, preparing a stable solution; s2, preparing a rare earth chelating solution; adding lanthanum lactate into the stable solution for multiple times, and adding ammonium ceric sulfate for multiple times after the lanthanum lactate is completely dissolved; s3, preparing a resin base solution; s4, preparing mixed slurry; s5, adding a solvent and an auxiliary agent; a five-membered ring chelate with thermodynamic stability is formed by carboxyl, hydroxyl and rare earth elements in sodium citrate, rare earth ions can be tightly wrapped through strong coordination bonds, namely, empty orbits of the rare earth ions and lone pair electrons of a chelating agent form coordination bonds, so that the rare earth ions cannot be dissociated in a system, and the rare earth ions are prevented from being dissociated in the system. And a path of generating hydroxide precipitates by free rare earth ions is thoroughly blocked, so that rare earth elements are effectively ensured to be uniformly distributed in the electrophoretic paint, and the surface of a raw material treated by a subsequent electrophoresis process is more uniform.

The invention discloses a urease-producing microorganism induced calcium carbonate deposition solution for foundation reinforcement and a preparation method and application thereof, and belongs to the technical field of foundation reinforcement. The urease-producing microorganism induced calcium carbonate deposition solution comprises a bacterial solution, a cementing solution and a sodium citrate solution, the bacterial liquid comprises bacteria capable of generating urease and citrobacter freundii. Sodium citrate in the urease-producing microorganism induced calcium carbonate deposition solution can chelate free calcium ions in advance, the concentration of the free calcium ions is reduced, the risk of precipitation at an injection port in the single-phase injection process is eliminated, and the solution can smoothly permeate into a deep layer; citrobacter freundii produces acid through metabolism and utilizes citric acid radicals through metabolism to ensure gradual release of calcium ions, so that uniform deposition of calcium carbonate is triggered. Through the synergistic effect of sodium citrate chelated calcium ions and citrobacter freundii metabolism, the solution can be uniformly distributed in the soil sample, and the problem of uniformity of single-phase perfusion is successfully solved.

The application provides a kind of superfine copper powder and its preparation method and application, the preparation method of the above-mentioned superfine copper powder uses two-step liquid phase reduction method to prepare superfine copper powder, and improves process conditions, using dropwise feeding mode. Among them, the first step uses alkaline ascorbic acid solution to reduce copper chloride to cuprous chloride with narrow particle size distribution; the second step uses ferrous sulfate and sodium citrate as mixed reducing agent, and sodium citrate can also be used as a complexing agent, which helps to reduce the cuprous chloride to spherical, well-dispersed, uniform particle size distribution of superfine copper powder. At the same time, the raw materials used by the application are easy to obtain, the reaction process is mild, and organic solvents and toxic and hazardous reagents such as sodium borohydride and hydrazine hydrate are not needed, the preparation process has cost effectiveness, is friendly to the environment, and is suitable for industrial production.

The invention belongs to the technical field of hydrogen production electrolytic cells, and particularly relates to a preparation method of an electrode for a hydrogen production electrolytic cell, and the preparation method at least comprises the following steps: providing a base material; forming a first catalyst layer on the substrate; and forming a second catalyst layer on the first catalyst layer, when the second catalyst layer is formed, a stabilizer is added into the electrochemical liquid medicine, and the stabilizer comprises one or a combination of more of sodium citrate, potassium citrate, sodium gluconate, disodium ethylene diamine tetraacetate and sodium tartrate. By means of the preparation method of the electrode for the hydrogen production electrolytic cell, the stability of the catalyst on the base material can be improved, exertion of the activity of the catalyst is not affected, then the performance of the water electrolysis hydrogen production electrode is improved, the preparation cost can be reduced, and the preparation process can be simplified.

The invention relates to a hemoglobin peptide capable of promoting iron absorption and a preparation method thereof, the mass content of polypeptide in the hemoglobin peptide is greater than 90%, and the hemoglobin peptide contains at least one of FERF and FDGL; the preparation method comprises the following steps: S1, adding trisodium citrate into fresh animal blood, centrifuging, adding a NaCl solution for washing, preparing the solution, and performing high-pressure homogenization wall breaking for 2-5 times to obtain a hemoglobin solution; s2, adding 10-200 U / mL of neutral protease, carrying out heat preservation treatment, then adding 5-50 U / mL of flavourzyme, carrying out enzymolysis, and carrying out enzyme deactivation to obtain an enzymatic hydrolysate; s3, filtering with an ultrafiltration membrane, and collecting permeate; s4, adjusting the pH value, adding into an anion exchange chromatographic column, eluting with a NaCl solution, and collecting the eluent; s5, desalting, concentrating and drying to obtain hemoglobin peptide; and S6, carrying out mass spectrometric detection, and screening bioactive peptides to obtain the oligopeptide with the activity of promoting iron absorption. The hemoglobin peptide obtained by the preparation method disclosed by the invention has relatively good iron chelation capability and iron absorption promoting capability, and the bioavailability of iron ions can be remarkably improved.

The invention relates to a preparation method of a porous sodium-ion battery ferric phosphate sodium pyrophosphate positive electrode material, and belongs to the technical field of sodium-ion battery positive electrode materials. The method comprises the steps of precursor slurry preparation, sanding, spray drying, low-temperature heat treatment, surface activation, double-stage etching, high-temperature calcination and the like. Wherein an isopropanol-hydrofluoric acid system is adopted to perform first-stage etching on the precursor so as to open the carbon coating layer and improve the permeability of subsequent etching liquid; and then, carrying out second-stage deep etching under a heating condition by adopting a hydrofluoric acid-sodium citrate system, so as to effectively remove the silicon dioxide template and form a through type porous structure. The obtained positive electrode material has a good pore structure and a conductive network, and electrolyte infiltration and construction of a sodium ion diffusion channel are facilitated, so that the rate capability and the cycle stability of the positive electrode material are improved. The preparation method disclosed by the invention is simple and convenient in process and suitable for large-scale preparation of the high-performance sodium-ion battery positive electrode material.

A nanotag includes a gold core, the gold core is sequentially coated with a silver shell and a gold shell, and a Raman dye is arranged between the silver shell and the gold shell; further it discloses a making method for a high-stability SERS nanotag that includes the following steps: a. adding tetrachloroauric acid into ultrapure water, after boiling, quickly adding trisodium citrate, continuously boiling for a few minutes, stopping heating, and cooling; b. adding hexadecyl trimethyl ammonium chloride (CTAC) into product obtained in the step a, stirring, and then adding ascorbic acid and AgNO3, and centrifugating and resuspending in the CTAC; c. adding CTAC into product obtained in the step b, stirring, adding a Raman dye, ascorbic acid and sodium hydroxide, injecting a mixture of tetrachloroauric acid and potassium iodide, and centrifuge the mixture and resuspending in the CTAC.

The invention relates to the technical field of electrolytic copper foil processing, and particularly provides an ultra-low profile RTF copper foil surface treatment process which comprises the following steps of acid pickling, coarsening, curing, ashing, passivation, anti-oxidation, silanization and drying, and a coarsening additive is one or a mixture of two of NaWO4, NaMoO4, D-sodium gluconate and trisodium citrate. Through alternate circulation of multiple roughening and curing processes, the bonding force between crystal grains and the surface of the copper foil is remarkably enhanced, the copper powder falling phenomenon is thoroughly eliminated, and the anti-stripping strength is higher; the reverse copper foil prepared by the production process provided by the invention has ultra-low profile tolerance, the roughened surface Rz is less than or equal to 1.8 mu m, and the peel strength is more than or equal to 0.5 N / mm. The roughness is reduced on the basis of maintaining the peel strength of the copper foil, so that the obtained electrolytic copper foil is more beneficial to high-frequency signal transmission, and the applicability is wider.

The invention discloses a seawater initiation preparation method of metal wet gel and aerogel and application of the seawater initiation preparation method in electro-catalysis ethylene glycol oxidation. Comprising the following steps: 1) sequentially adding a metal salt, sodium citrate and a reducing agent into pure water, 2) adding seawater into a reaction solution to obtain wet gel, and 3) washing and drying the wet gel to obtain the aerogel. Seawater can be used for replacing expensive drugs used in a large amount in a salting-out method and an excessive sodium borohydride method, so that the metal nanoparticle solution is unstable, the metal aerogel material is prepared, and the preparation cost of the metal aerogel is greatly reduced. The metal aerogel obtained by the invention shows excellent catalytic performance in the application of electro-catalysis of ethylene glycol oxidation.

The invention discloses an electrochemical preparation method of a component-controllable indium-indium oxide nanosphere composite catalyst and CO2 reduction application of the component-controllable indium-indium oxide nanosphere composite catalyst. The component-controllable indium-indium oxide nanosphere composite catalyst is prepared from indium nitrate, urea, trisodium citrate, deionized water, absolute ethyl alcohol, a carbon paper electrode and Nafion. Different indium oxide nanosphere precursors are synthesized under the high-temperature and high-pressure reaction conditions of a one-step hydrothermal method, the precursors are placed in a muffle furnace to be subjected to high-temperature calcination to obtain indium oxide nanospheres, the obtained indium oxide nanospheres are subjected to electrode sheet preparation, and the indium-indium oxide nanosphere composite catalyst with controllable components is obtained through electrochemical reduction treatment. The composite material is applied to CO2 electrochemical reduction.