The invention discloses
silicon-based
solvent-free
polyurethane composite artificial leather and a preparation method thereof.The composite artificial leather comprises a
surface layer, a middle layer, a bonding layer and a base cloth layer from top to bottom, and the
surface layer is prepared by
coating release paper with
surface layer slurry and
drying the release paper; the surface layer
slurry comprises water-based resin containing carboxyl
siloxane polyurethane resin
copolymer, and the preparation method comprises the following steps: carrying out
polymerization reaction on hydroxyl polyether-terminated dihydroxyl
polydimethylsiloxane,
carboxylic acid with double hydroxyl groups and diisocyanate, adding inorganic alkali to obtain carboxyl
siloxane polyurethane resin
copolymer water dispersion liquid, and adding the water-based resin containing carboxyl
siloxane polyurethane resin
copolymer into the water-based resin containing carboxyl siloxane polyurethane resin copolymer to obtain the water-based resin containing carboxyl siloxane polyurethane resin copolymer. Adding the mixture into waterborne polyurethane resin; the molecular formula of the hydroxyl polyether-terminated dihydroxyl
polydimethylsiloxane is H-O-R-[Si (CH3) 2O] m-R-O-H, m is a positive integer from 25 to 95, R represents a polyether
chain segment with the following structure:-O-(C2H4O) p-(C3H6O) q-, p and q are integers from 0 to 15, and p + q is greater than or equal to 1 and less than or equal to 15. The composite artificial leather disclosed by the invention is easy to clean and care, super soft, glossy and transparent, low in
odor and VOC (Volatile Organic Compounds) and good in
wear resistance.