60results about How to "Large flocs" patented technology

The preparation process of polymerized iron phosphosulfate includes adding ferrous sulfate into water at 70-80 deg.c until reaching saturation, filtering, adding oxidant or catalyst to convert two-valent iron into three-valent iron, and adding sodium chlorate and sodium pyrophosphate to react for 20-30 min to obtain the product. The present invention introduces phosphate radical ion to ferrous sulfate skeleton to obtain extremely high alkalisation degree of ferrous sulfacte, and the polymerized iron phosphosulfate as flocculant is easy to hydrolyze, can form large flocculate with high settling rate and may be used to well eliminate BOD, COD, heavy metal, nitrite nitrogen, etc. from sewage.

The invention discloses polysilicate-metals composite flocculant and a preparation method thereof and relates to flocculant for water treatment and the preparation method thereof. The method aims to solve the technical problem that the alkalization degree and polymerization degree of flocculant are increased by externally increasing alkalizer so water treatment cost is increased in the conventional polysilicate-metals composite flocculant. The polysilicate-metals composite flocculant is prepared from silicate, aluminum salt, ferric salt, an assistant agent A and an assistant agent B in a weight ratio, wherein the assistant agent A is one or combination of phosphate, calcium oxide, polyacrylamide, and chitosan; and the assistant agent B is one or combination of sodium hydroxide, potassium hydroxide, sodium carbonate, potassium carbonate, sodium bicarbonate or potassium bicarbonate. The method comprises the following steps of: adjusting pH of the aqueous solution of silicate, stirring and standing to obtain solution of polysilicate, and then adding the aluminum salt, the ferric salt, the assistant agent A and the assistant agent B, and mixing uniformly to obtain the polysilicate-metals composite flocculant. Other agents are not needed to be added, and the polysilicate-metals composite flocculant is low in cost and can be used for the field of water treatment.

The invention discloses a method for producing a polymeric aluminium ferric sulfate solution from industrial waste sulfuric acid generated during purification of acetylene gas and red mud. The method comprises the following steps: adding water to the red mud to pulp the red mud, mixing the pulped red mud with waste sulfuric acid in a weight ratio of (2-5) to 1, stirring and mixing the materials to react for 1-4 hours to obtain a reaction mixture, standing to leach the mixture for 6-12 hours to obtain leachate, filtering the leachate to obtain filtrate, extracting rare metal impurities in the filtrate with di(isooctyl) phosphate, extracting organic matter impurities in a solution with an extracting agent and alkalifying and polymerizing raffinate to obtain the polymeric aluminium ferric sulfate solution with polymeric aluminium ferric sulfate mass content not less than 8% (in terms of aluminium ferric oxide). The method has the positive beneficial effects that the existing and potential environmental problems caused by discharge of the waste sulfuric acid after neutralizing treatment or direct discharge of the waste sulfuric acid and stacking and storage of the red mud on the land are solved; the polymeric aluminium ferric sulfate product capable of purifying sewage is produced from the waste sulfuric acid and the red mud, thus reducing environmental pollution caused by the waste sulfuric acid and the red mud; the process is simple and is easy to operate, so that the waste treatment cost is reduced; when serving as a flocculating agent, the prepared polymeric aluminium ferric sulfate product has the advantages of high settling time, large flocs, few metal residues and good sewage purifying effects.

The invention relates to a biological composite flocculating agent for adsorbing heavy metal ions in heavy metal wastewater and applications thereof. The composite flocculating agent is prepared by compounding polyglutamic acid, polymeric aluminum chloride, and poly(aspartic acid) according to a weight ratio of 1: 4-6: 15-17. When the flocculating agent is used, at first, the pH value of heavy metal wastewater is adjusted to 6-9; then the biological composite flocculating agent is added into the heavy metal wastewater, the system is vibrated and stirred for 15 to 20 minutes, after vibration and stirring, centrifugal separation or static settlement is performed, and the flocculent precipitates that adsorb heavy metal ions are recovered and processed. The adsorbing performance and application range of the biological composite flocculating agent are both enhanced. The processing mode is simple and environmentally friendly. Furthermore, polyglutamic acid and poly(aspartic acid) can be easily degraded by organisms and will not generate secondary pollution; the preparation and application are convenient, and the cost is low.

The invention discloses a system for treating antimony-containing printing and dyeing sewage. The system mainly comprises a regulating tank, a cooling tower, a primary sedimentation tank, an aerobic tank, a second sedimentation tank, an immersing-type ultrafiltration MCR tank, a reverse osmosis membrane system, a final sedimentation tank and an outer drainage tank which are used for collecting theprinting and dyeing sewage and connected sequentially through pipelines, wherein a PAC agent is added into the primary sedimentation tank so as to perform a flocculation reaction, and microorganismsare adsorbed in the aerobic tank; after sedimentation, the treated sewage is discharged from a sludge treatment system, so that the total amount of antimony in the sewage is reduced, and the application amount of a PAFC reagent which is used in a terminal process of mixing and sedimentation; RO concentrate is generated through the immersing-type ultrafiltration MCR tank and the reverse osmosis membrane system so as to achieve the concentration and enrichment of the antimony element and thus reduce the amount of sewage for antimony removing treatment, so that the efficiency of utilization of the PAFC reagent is improved, the generated RO clean water can be reused in a workshop, and therefore requirements for the reuse of reclaimed water by a printing and dyeing company are met.

The invention relates to a green environment-friendly flocculant and a method for preparing the same, wherein the green environment-friendly flocculant is applied to the solid-liquid separation treatment of a waste drilling fluid. The green environment-friendly flocculant comprises the following components: water glass, starch, sodium carboxymethylcellulose, a cross-linking agent and water. The method for preparing the flocculant comprises the following steps of: (1) preparing water glass solution and adjusting the pH of the solution to a range of 3-7 for later use; and (2) adding the starch and sodium carboxymethylcellulose to the water glass solution, stirring the mixture so that the mixture is evenly dissolved, adding the cross-linking agent to the mixture and reacting at 60-90 DEG C for 2-5 h. In case of the same dosage, the solid phase moisture content of the waste drilling fluid treated by the flocculant provided by the invention is lowest, while the solid phase removal ratio and supernatant light transmittance are highest; and the flocculating water separation capability of the flocculant is superior to that of the common inorganic flocculant and the common organic high-molecular flocculant. The flocculant prepared by the method provided by the invention has the advantages of wide raw material source, low cost, low dosage, good flocculantion effect, high adsorption capability, large formed floc, high sedimentation velocity, easiness in separation, greenness and environmental friendliness, innocuity, biodegradability and the like.

The invention discloses a phosphorus removal agent for sewage treatment. The phosphorus removal agent is prepared from the following raw materials in parts by weight: 45-55 parts of ferrous sulfate pentahydrate, 12-16 parts of polyaluminum chloride, 20-27 parts of polyaluminum ferric silicate and 25-33 parts of hydroxyl iron modified montmorillonite. According to the phosphorus removal agent for sewage treatment, the raw material composition is carefully selected, the content of each raw material is optimized, ferrous sulfate pentahydrate, polyaluminum chloride, polyaluminum ferric silicate and specially-made hydroxyl iron modified montmorillonite in a proper proportion are selected, the advantages of each raw material are fully exerted, mutual complementation and mutual promotion are achieved, the product quality is greatly improved, the prepared phosphorus removal agent for sewage treatment is high in phosphorus removal rate and low in turbidity of treated water, and is an efficientphosphorus removal agent for sewage treatment.

The invention discloses a method for preparing modified flocculant from organic wastewater by diatomite and belongs to the technical field of organic wastewater treatment. The method uses diatomite asraw materials, SiO2 is extracted to synthesize sodium metasilicate pentahydrate, then polyaluminium ferric silicate is prepared, and carboxymethyl starch (CMS) is used for modifying the prepared polyaluminium ferric silicate (PAFCSC) flocculant to obtain the modified flocculant. The preparation of the flocculant by diatomite meets the requirement of comprehensive utilization of natural resources.Moreover, the demand for the flocculant is very high in China and even in the whole world, aluminum and iron flocculants occupy a large market because of good treatment effects and low cost, therefore, the preparation of the PAFCS flocculant by diatomite has great economic and social significance.

The invention relates to a preparation method and application of a flocculant for treating urban sewage. The method comprises the following steps: diluting water glass of which the modulus is 2.8 to 3.5 by using water until the content of silicon dioxide is adjusted as 2 to 10 percent by weight, adding a solution to an exchange column filled with cation exchange resin to obtain a silicate gel diluent of which the content of sodium oxide is smaller than 1 percent and the pH value is smaller than 4; adding the solution into metal aluminum salt of which the silicate mole ratio is 5 to 30 under the high-rotation-speed stirring condition that the Reynolds number is greater than 6,000; adjusting the pH value of a mixture obtained by stirring as 5 to 6 by using a sodium aluminate solution of which the concentration is 5 to 10 percent by weight, so that the flocculant can be used; or performing spray drying, wherein an obtained solid also has the same effect. According to the method, multiple pollutants are flocculated and aggregated by using an aggregate with various functional groups. The flocculant is suitable for treating wastewater with various qualities, the pollutant treatment range is wide, the effect is good, the source of production raw materials is wide, the cost is low, the performance is stable, and any environmental pollution is avoided.

The invention provides a preparation method of a sewage treatment flocculating agent. The method comprises the steps of mixing onium diallyl pyrrole bromide and onium diallyl piperidine bromide uniformly to obtain a mixture, then adding a certain amount of calcium silicate and kieselguhr into the mixture, and mixing uniformly to obtain the sewage treatment flocculating agent. The sewage treatmentflocculating agent has many functional groups, the floc formed is large, the flocculation speed is fast, the time required for treatment is short, the treatment effect is good, the dosage is small, the sludge production amount is small, the turbidity removal rate of domestic sewage reaches 90%, and the COD removal rate reaches 80%.

The invention relates to a composite coagulant for advanced treatment of biochemical tail water, as well as a preparation method and application thereof. The inorganic polymer composite coagulant containing boron, silicon, aluminum and iron, which is prepared by adopting an iron source, a boron source and a silicon-aluminum source as raw materials, is applied to coagulation purification processing coagulant of all kinds of waste water, and is particularly applied to advanced treatment of the biochemical tail water. The iron source, the boron source and the silicon-aluminum source are adopted as the raw materials; the inorganic polymer composite coagulant is prepared through alkaline hydrolysis, acid leaching oxidation, hydrolysis and polymerization under heating; and the prepared composite coagulant contains 20 percent-35 percent of silicon, 15 percent-25 percent of aluminum, 6 percent-11 percent of iron, and 3 percent-6 percent of boron. The coagulant has easy-to-get raw materials and concise process, and is economic and applicable. The obtained inorganic polymer composite coagulant has good capacities of absorption and bridging, charge neutrality, bonding aggregation and decoloration, and less dosage, and is widely applied to waste water treatment field, in particular to advanced treatment of the biochemical tail water; and the flocs are big and are fast in sedimentation velocity.

The invention discloses a method for conditioning sludge through an amphoteric polymeric flocculant and biological nano zero-valent iron. The method comprises the following steps that 1, the biological nano zero-valent iron is used for conditoning the sludge, wherein a fresh biological nano zero-valent iron suspension is put into the sludge and stirred, so that heavy metal in the sludge is stablized; 2, the amphoteric polymeric flocculant P(AM-DAC-SMAS which is called as PADS for short) is used for conditioning the sludge, wherein the PADS is put in the conditioned sludge and stirred, and sludge flocculating and dewatering are achieved through a good flocculating function of PADS; 3, the sludge mixture obtained after flocculating is subjected to centrifugal dewatering. The combined use ofthe amphoteric polymeric flocculant and the biological nano zero-valent iron can reduce the migration and transformation capacity of the heavy metal, and the biological nano zero-valent iron can alsoachieve functions of a flocculating auxiliary. The method has the advantages of being low in PADS consumption, high in dewatering efficiency and wide in pH value application range; a foundation is laid for subsequent resource utilization of the sludge.

The invention discloses a method and a device for promoting free radical conditioning and pressure-vertical electric field dewatering of sludge through microelectrolysis. The method comprises main steps as follows: sludge is stirred, a direct-current electric field is applied, and iron powder and a conditioning agent are added for conditioning; the sludge enters a pressure-vertical electric fielddewatering device for dewatering. According to the method, the microelectrolysis process of an iron powder induction electrode is enhanced through the electric field, generation of Fe<2+> is promoted,activation of sulfate is realized, sulfate free radicals and high-valence iron ions are produced, electrolysis-oxidation-flocculation coordinated conditioning is performed on the sludge, the functions of cracking of the sludge structure, bound water release and floc reconstitution are played, and the dewatering effect of the conditioned sludge in the pressure-vertical electric field is enhanced.The dewatering efficiency is high, the water content of the sludge can be reduced to 50% or below, and the water content of the sludge is effectively reduced. Besides, the method and the device also have the advantages that the reaction time is short, operation is simple, the application range is wide and the like.

The invention discloses a flocculating agent for treating coking wastewater, and a preparation method and application thereof. The flocculating agent is prepared from the following raw materials in parts by weight: 30 to 38 parts of erionite, 8 to 16 parts of rosin glycerin ester, 1 to 8 parts of aluminum stearate and 5 to 13 parts of acrylic emulsion. The erionite and the rosin glycerin ester are mixed and pulverized; a prepared aluminum stearate solution is added for sealed soaking; hot stirring is performed to obtain pretreatment materials; the acrylic emulsion is added; in the ozone atmosphere, heating and sealed stirring, ultrasonic treatment and high-temperature calcination are performed to obtain the flocculating agent. The flocculating agent is used for treating the coking wastewater; the coking wastewater color intensity and the COD (chemical oxygen demand) removal effect are more excellent; flocs generated by the flocculating agent are great, and can be easily settled. The flocculating agent has the advantages that the material taking is simple; the preparation process is simple; the operation is easy; the property of the flocculating agent is stable; the activity is high; the adsorption capacity is high; the buffer capability is high; no corrosiveness exists; safety, non-toxicity and harmlessness are realized; the secondary pollution cannot be caused on the water quality; the flocculating agent is applicable to industrial production.

The present invention provides a food sewage treatment flocculant preparation method, which comprises: dissolving dimethyl diallyl ammonium chloride and an acrylamide monomer in distilled water according to a ratio of 1:1-10 to form a solution with a concentration of 20-40 wt%; respectively preparing potassium persulfate and sodium sulfite as initiators, and preparing cerium sulfate as a catalyst; taking liquid water glass with a modulus of 2.8-3.5, diluting the water glass with water, adjusting the content to achieve a silica content of 2-10 wt%, loading the solution onto an exchange column filled with a cation exchange resin to obtain a silica sol dilute solution with a sodium oxide content of less than 1 wt% and the pH value of less than 1-4; and carrying out reaction polymerization to obtain the food sewage treatment polysilicic acid/polyacrylamide composite flocculant. According to the present invention, the flocculant is used for food sewage treatment or drinking water and wastewater treatment, can effectively remove floating impurities and water-soluble pigments in food sewage, and is suitable for industrial production and applications.

The invention relates to a preprocessing method for black liquor in diffusion dialysis recycling pulp manufacture, and belongs to the technical field of pulp manufacture. The preprocessing method comprises the following steps: adding flocculant into the black liquor, which contains sodium hydroxide with the concentration of 8-30 g/L, for flocculation, and keeping the concentration of the flocculant at 5-10 mg/L; filtering through a sheet frame filter with the bore diameter of 1,100-1,300 g/m<2>; then filtering through a millipore filtration membrane with the bore diameter of 0.1-1 micrometer to reduce the concentration of large particle impurity; recycling lignin to obtain the preprocessing liquid used for diffusion dialysis treating for a cation exchange membrane. Through adopting specific preprocessing method to process the black liquor before entering the diffusion dialysis process, the preprocessing method can increase the recovery rate of alkali and hemicelluloses in the black liquor, reduce damage to the diffusion dialysis membrane system caused by the alkali liquid, prevent blockage of the diffusion dialysis membrane, prolong the service life of the membrane, and guarantee the smooth progress of diffusion dialysis and follow-up handling.

The invention relates to a preprocessing technology for black liquor in diffusion dialysis recycling pulp manufacture, and belongs to the technical field of pulp manufacture. The preprocessing method comprises the following steps: adding flocculant into the black liquor, which contains sodium hydroxide with the concentration of 8-30 g/L, for flocculation, and keeping the concentration of the flocculant at 5-10 mg/L; filtering through a sheet frame filter with the bore diameter of 1,100-1,300 g/m<2>; then filtering through an ultrafiltration membrane with the bore diameter of 20-1,000 angstroms to reduce the concentration of large particle impurity; recycling lignin to obtain the preprocessing liquid used for diffusion dialysis treating for a cation exchange membrane. Through adopting specific preprocessing method to process the black liquor before entering the diffusion dialysis process, the preprocessing method can increase the recovery rate of alkali and hemicelluloses in the black liquor, reduce damage to the diffusion dialysis membrane system caused by the alkali liquid, prevent blockage of the diffusion dialysis membrane, prolong the service life of the membrane, and guarantee the smooth progress of diffusion dialysis and follow-up handling.