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47results about How to "Strong adsorption and bridging ability" patented technology

Experimental method for preparation of poly-iron-based flocculating agent for coking wastewater advanced treatment

The invention relates to an experimental method for the preparation of a poly-iron-based flocculating agent for coking wastewater advanced treatment. The experimental method comprises the specific operating steps that 1, the optimal preparation conditions of polymeric ferric sulfate are determined through an orthogonal experiment method; 2, on the basis of the optimal conditions of the polymeric ferric sulfate, an aluminum ingredient is added, and the optimal molar ratio of Fe to Al is determined through a coagulation experiment; 3, on the basis of polymeric ferric aluminum sulfate, activated silicic acid and positive polyacrylamide ingredients are added, and the optimal iron-aluminum proportion is determined through a coagulation experiment; 4, polysilicate ferro-alumium sulfate is applied to the coking wastewater advanced treatment, and the optimal technological conditions of the flocculating agent are determined. According to the experimental method for the preparation of the poly-iron-based flocculating agent for coking wastewater advanced treatment, under the conditions that the pH value of the flocculating agent is 7 and the dosing quantity is 0.83 mL / L, the CODcr removing rate of a coking wastewater sample can reach 50%, the turbidity removing rate reaches 95.96%, the chroma removing rate reaches 50%, through the research and development of the optimal flocculating agent matching, the efficiency of coking wastewater coagulation treatment is improved, and the load of follow-up treatment units is reduced.
Owner:辽宁中冠环境工程股份有限公司

Preparation method and application of PCAMT (polymeric aluminium magnesium titanium chloride)

The invention relates to a preparation method and an application of PCAMT (polymeric aluminium magnesium titanium chloride). The preparation method comprises the following steps: an aluminium chloridesolution and a magnesium chloride solution are prepared and mixed in the mole ratio of Mg/Al being 0.1-0.6:1, an aluminium magnesium chloride solution is obtained, placed in a refrigerator for 20-30min and taken out, 0.11-0.66 mL of a titanium tetrachloride liquid is pipetted to the aluminium magnesium chloride solution in the mole ratio of Ti/Al being 0.1-0.6:1, the mixed solution is sufficiently stirred and uniformly mixed, an aluminium magnesium titanium chloride solution is obtained, a sodium hydroxide solution with concentration being 2 mol/L is added dropwise to the aluminium magnesiumtitanium chloride solution, the mixed solution is stirred and mixed uniformly during addition, thermostatic water bath and continuous stirring are performed after addition, curing is performed in a light avoiding manner at room temperature, and PCAMT is obtained. The process is simple, the cost is low, an obtained composite polymeric coagulant has better charge neutralizing and adsorption bridging effects on pollutants, and the coagulation effect is better.
Owner:HUNAN UNIV OF SCI & TECH

Method for preparing polymeric silicic acid polymeric titanium chloride inorganic polymer composite flocculant through copolymerization method

The invention relates to a method for preparing a polymeric silicic acid polymeric titanium chloride inorganic polymer composite flocculant through a copolymerization method. The polymeric silicic acid polymeric titanium chloride inorganic polymer composite flocculant is prepared and obtained under the condition that chloride ions exist. The polymeric silicic acid polymeric titanium chloride inorganic polymer composite flocculant is prepared in the mode that titanium tetrachloride and sodium silicate serve as raw materials, and a titanium tetrachloride solution and polymeric silicic acid are o-polymerized. The method has the advantages that titanium tetrachloride serves as one of the raw materials, the chloride ions are introduced in the preparation process, excessive sulfate ions are avoided, product hydrolysis is avoided, product stability is improved under the high titanium ion concentration, the turbidity and the organic matter removal rate are high under the same dosing quantity, medicine stability is obviously enhanced, the adsorption bridging capacity for colloidal matter is high, the flocculation effect is good, the application range is wide, an outflow water pH value is close to the neutral value, and follow-up treatment is convenient.
Owner:SHANDONG UNIV

Preparation of cationic taro starch flocculant with high-efficiency decolorization performance

The invention relates to a cationic taro starch and a preparation method thereof, belonging to the field of environment-friendly material preparations. The preparation method for a flocculating agent,i.e., the cationic taro starch, comprises the following steps: cutting taro slices and soaking the taro slices in a NaOH solution with a pH value of 8-10, wherein a material-water ratio is 1: 1 to 1:5; performing homogenization, sieving, centrifugation, washing and drying successively so as to obtain taro starch; then spraying a solution containing NaOH and 2,3-epoxypropyltrimethylammonium chloride into the taro starch, wherein the usage amount of the NaOH accounts for 0.5-3 wt% of the usage amount of the taro starch, and the usage amount of the 2,3-epoxypropyltrimethylammonium chloride accounts for 12-20 wt% of the usage amount of the taro starch; and performing uniform mixing under stirring, allowing the water content of a formed system to be in a range of 20%-30%, and carrying out a reaction at 50-70 DEG C for 1-4 h. The preparation method of the invention is simple in process and low in cost; and the obtained cationic taro starch is environmentally friendly, non-toxic and easilydegradable, and has excellent decolorization effect, wherein decolorization effect on dyes can reach 95% or more.
Owner:邱业先 +2

Polyaluminum silicate-acrylamide copolymer composite flocculant and preparation method thereof

The invention discloses a polyaluminum silicate iron-acrylamide copolymer composite flocculant and a preparation method thereof, which is characterized in that 20 parts of Na2SiO3 are added to 250 parts of deionized water, the pH value is 2 to 5, and the reaction is carried out at room temperature for 2 to 3 hours. Prepare activated silicic acid; use aluminum-containing waste, iron-containing waste hydrochloric acid and industrial hydrochloric acid to obtain mixed crystals of AlCl3 and FeCl2; add 1.2 to 25.0 parts of mixed crystals to 25 parts of activated silicic acid, react, stand and mature, and obtain poly Aluminum iron silicate PAFSI; add 20 parts of acrylamide, 75-450 parts of deionized water, 5-20 parts of ionic monomer, and 0.3-6 parts of macromonomer into the reaction bottle, stir, pH value 5-9, pass N2 , add 0.008-0.4 parts of potassium persulfate at 40-70°C, react for 12-36 hours, and prepare the copolymer PAME; add 100 parts of 5 g / L PAME solution into the reaction bottle, and add 12-350 parts under rapid stirring 100 g / L PAFSI solution, pH value 1-4, react at 30-40°C for 2-3 hours, then react at 50-75°C for 2-4 hours, and mature for 24 hours to prepare PAFSI-PAME composite flocculant.
Owner:CHENGDU UNIVERSITY OF TECHNOLOGY
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