The invention belongs to the technical field of wastewater treatment, and particularly relates to a method for converting titanium dioxide red gypsum into white gypsum and enriching titanium and iron.The method comprises the following steps: preparing white gypsum, preparing the red gypsum, converting the red gypsum into acid white gypsum, and converting the acid white gypsum into the white gypsum; through control of a process and an end point of the reaction, the produced white gypsum can be directly used for a cement factory, and can be deeply processed into building material gypsum with higher added value; through dissolution of the red gypsum by a waste concentrated acid, the red gypsum is converted into the acid white gypsum, and a TiOSO4 and FeSO4 acidic solution with a high concentration is obtained, wherein the recovery utilization rate is 95% or more; and the acid white gypsum is diluted by using titanium dioxide wastewater, and after primary neutralization is performed, thewhite gypsum is obtained. The method provided by the invention has a simple technological process, a stable treatment effect, less equipment investment, no secondary pollution, low treatment costs, considerable economic benefits and broad market prospects.