393 results about "Radical ion" patented technology

The invention discloses a modulating method of LiFePO4 particle shape, which comprises the following steps: blending one or more composition with lithium ion, ferric ion and phosphate radical ion; adding solvent and certain quantity of crystal growing inhibitor; proceeding solvent heat reaction under certain temperature; washing; filtering; drying; sintering to improve crystallizing property; obtaining the product with regular shape and size.

The invention relates to a preparation method of lithium iron phosphate for the carbon cladding of a lithium ion battery. The prior lithium iron phosphate preparation technical art is complex, and has high cost. The invention has the synthetic process that: ferric oxide, phosphoric acid, simple organics and doped element compound are mixed and dried, the mol ratio of phosphate radical ion, ferric ion and doped element ion is 1:y:z, wherein, y is larger than or equal to 0.95 and smaller than or equal to 1, and y plus z is equal to 1; the mixture is added with lithium source compound, added with water to be mixed and dried, the mol ratio of lithium ion and phosphate radical ion is x:1, and x is larger than or equal to 0.95 and smaller than or equal to 1.05; the mixture which reacts for 2 to 20 hours under 500 to 800 DEG C is cooled in a furnace. The invention finally produces the precursor uniformly mixed with superfine crystal grain, and during the subsequent high temperature solid phase reaction, the end product lithium iron phosphate can be produced through shorter distance diffuseness of atoms. The end product has high purity, the crystallisation is good, the capacity is high, and the cycle stability is good.

The present invention discloses one kind of ternary Zn-Ni-Mn phosphorizing solution and its preparation process. The ternary Zn-Ni-Mn phosphorizing solution consists of zinc ion, phosphate radical ion, nickel ion, manganese ion, chlorate radical ion, nitrate radical ion, fluorine ion, promoter A, additive B and complexing agent C in certain proportion. The present invention can form compact and homogeneous phosphide film with high base resistance and high corrosion resistance, and is suitable for the phosphorizing treatment of cathode before electrophoresis coating.

The present invention relates to a process for preparing hydroxylapatite bio-ceramic membranes at titanium or titanium alloy surfaces by utilizing differential arc oxidation process. Firstly, preparing electrolytic solution A by using calcium ion salts and phosphate radical ion-containing salts, or preparing electrolytic solution B by adding metal silver ions to the electrolytic solution A; or preparing electrolytic solution C by adding metal silicon ions to the electrolytic solution A; and then, selecting titanium or titanium alloy as anodes and putting them respectively into the electrolytic solution A, B and C, selecting the non-corrodible steel container for containing the electrolytic solutions as cathodes, controlling conditions such as impulse electrical source positive phase voltage, frequency for differential arc oxidation of titanium or titanium alloy, then hydroxylapatite bio-ceramic membrane layers possessing different performances are prepared. Said titanium based bio-ceramic compound material prepared according to said process possesses not only intensity and toughness of metals but also biological activity of hydroxylapatites, and is capable of being applied in the fields such as jackstraw chirurgery implantation body and tooth planting body.

The invention discloses a sewage treatment method for simultaneously removing phosphor and nitrogen in a process of reinforcing autotrophic denitrification of sulfur and belongs to the technical field of sewage treatment. According to the method, pyrite, sulfur and siderite are adopted for strengthening a denitrification process of the wastewater and the effect of simultaneously removing phosphor and nitrogen is promoted. According to the method, pyrite and sulfur are used as sulfur sources and siderite is used as a carob source in a reaction system. The synergistic effect of the pyrite and sulfur can strengthen the utilization of the thalli for the siderite, so that the denitrification capacity can be reinforced. The ferric and ferrous ions, which are released by pyrite and siderite, and phosphate radical ions can form the ferric phosphate sediment, so that the dephosphorization capacity is reinforced. The method has an excellent effect, is low in cost and is suitable for engineering application.

The invention discloses a method for removing lithium ion battery nickel-rich material surface lithium residues by a liquid phase precipitation method. The method for removing the lithium ion battery nickel-rich material surface lithium residues by the liquid phase precipitation method includes the steps: dispersing lithium ion battery nickel-rich materials into phosphate solution, combining the nickel-rich material surface lithium residues with phosphate radical ions so as to form precipitation, nucleating on the material surface, and calcining so that a material with the surface wrapped with a compact Li3PO4 layer is obtained. The wrapping layer prepared by the method is more uniform and compact than a traditional wrapping layer, and storage performance of the material in air is obviously improved; and the moisture absorption performance of the nickel-rich materials can be improved while water brought into electrolyte by electrode materials is reduced, and structural stability of the material is enhanced. Moreover, Li3PO4 is better in stability in the electrolyte than in the battery materials, so that the comprehensive electrochemical performance of a positive electrode material can be effectively improved. The method for removing the lithium ion battery nickel-rich material surface lithium residues by the liquid phase precipitation method is simple in preparation process, short in flow path and low in production cost, and the prepared positive electrode material is excellent in physical performance and electrochemical performance.

The present disclosure belongs to the technical field of biomass refining, and particularly relates to an eutectic solvent and an application of the eutectic solvent in lignin extraction. Eutectic solvents are composed of a certain amount of hydrogen-bond donors and hydrogen-bond acceptors, and are economical and environment-friendly green solvents, and among the eutectic solvents, choline-based eutectic solvents are widely used in lignocellulose extraction. Inventors find that due to the presence of chloride ions in the choline chloride-based eutectic solvents, negative charges can be intensively distributed, the extraction efficiency can be reduced, and the aging of an instrument can be accelerated. The present disclosure provides the eutectic solvent with a low halogen content, and organic acid radical ions are adopted to replace halogen anions in choline chloride. Research of the present disclosure proves that the method has a high lignin extraction rate, high purity, simple operation, an obvious effect, high practicability, small pollution, and easy promotion.

The invention discloses a preparation method of precursor iron phosphate of cathode material lithium iron phosphate of a lithium ion battery, which comprises the following steps: simultaneously addingferrous ion aqueous solution with the concentration of 0.05-2mol/L and phosphate radical aqueous solution into a reactor according to the stoichiometric ratio of ferrous ions and phosphate radical ions of 0.8-1.2: 1 and at the speed of 400-1000mL/h, and reacting for 0.2-2h under the conditions that the reaction temperature is 50-90 DEG C and the stirring speed is 400-1200rpm; adding hydrogen peroxide with excessive stoichiometry and reacting for 0.2-2h, and ageing for 2-8h, filtering, washing and drying to obtain iron phosphate powder with two crystallization water; and in the obtained iron phosphate, the total ferric content (Fe) is 29.5-30.5 percent, the P content is 16.0-16.9 percent, the particle size is 0.1-1Mum, and D50 is 1-5Mum. The invention has simple and convenient operation process, simple device, easy control, low energy consumption, even and fine particle size distribution and high reaction activity and is suitable for preparing the lithium ion battery cathode material lithium iron phosphate.

The invention discloses a method for finishing a noble metal coating of a porous gold and the method comprises the following steps: the nanoporous gold is made by corroding gold-silver alloy; the nanoporous gold is soaked into a certain concentration of a solution containing chloroplatinic acid radical ions (or chloroplatinous acid radical ions, or chloropalladic acid radical ions, or chloropalladic acid radical ions, or the mixture) for an appropriate time to cause the surface of the nanoporous gold to absorb some noble metal ions, the other noble metal ions except for the noble metal ions absorbed on the surface of the nanoporous gold are washed clean, and the noble metal ions absorbed are reduced to a noble metal simple substance under proper electrochemical conditions, and the noble metal simple substance is tightly bonded on the pore wall of the nanoporous gold. The method of the invention can be used for preparing a catalyst which combines porous metals with ultra-low content of noble metals and can be applied in the catalytic fields of fuel cells and the like.

The invention discloses a method for preparing a novel efficient composite visual light catalytic material Ag3PO4@g-C3N4. First, g-C3N4 in a flaky structure is processed in a silver salt solution under ultrasonic action so as to load silver ions on the surface of g-C3N4. Then, a sodium phosphate solution is dropped in and continuously agitated, and the composite material Ag3PO4@g-C3N4 is formed through the in-situ precipitation reaction of the silver ions loaded on the surface of the g-C3N4 and phosphate radical ions. The method has the advantages of simple and easily-controlled preparing process, convenience in operation, low cost and high product visual light catalytic activity.

The invention provides a nonaqueous electrolyte, which comprises an organic solvent and a lithium salt, wherein the organic solvent is selected from a non-carbonate solvent. The provided nonaqueous electrolyte has relatively good nucleophilic attack resistance; high-activity radical ions O2.<-> and these solvents are not easily subjected to nucleophilic reaction, so that Li2O loss in the material is effectively inhibited; the structure of a lithium-rich cathode material is stabilized; and the voltage hysteresis phenomenon of the material is effectively relieved. Meanwhile, the provided nonaqueous electrolyte has good oxidation resistance and non-combustible characteristics, so that a lithium-rich battery prepared from the nonaqueous electrolyte has relatively good cycle performance and relatively high safety.

The invention relates to a method for removing hydrogen sulfide from gas, and belongs to the technical field of gas purification. The method mainly comprises the steps: firstly introducing the gas containing hydrogen sulfide to a kinetic wave absorber for removing a large amount of hydrogen sulfide, and then entering the gas containing a small amount of hydrogen sulfide to a filled tower for fine desulfurization; converting hydrogen sulfide in the gas into sulfhydryl radical ion in the absorption process by using a complex iron absorbing liquid; oxidizing rich solution absorbing hydrogen sulfide with air for regeneration so as to convert the sulfhydryl radical ion into simple substance sulfur harmless to environment, wherein the treated gas achieves the discharge requirement; and entering the gas containing sulfur into the kinetic wave absorber, and carrying out countercurrent contact with a complex iron desulfurizing liquid sprayed from bottom to top so as to form a stable form layer, so that the absorbing liquid carries out quick rotary cutting, and the gas and liquid are sufficiently contacted, thus the mass transfer efficiency is obviously improved, and the purification requirements that the hydrogen sulfide gas is quickly absorbed, most of hydrogen sulfide is removed by the kinetic wave, and a small amount of hydrogen sulfide in the gas is removed by the filled tower are achieved.

The present invention relates to uniformly coordinating precipitation process of preparing nanometer zinc oxide. The technological scheme includes the reaction between zinc oxide or zinc salt material and ammonia and carbonate as coordinating agent to produce water soluble coordinating compound tetraammonium-zinc carbonate solution; adding sulfide solution to eliminate heavy metal ion inside the coordinating compound solution; adding surfactant, water for dilution or heating decomposing the coordinating compound solution to separate zinc ion and to react with carbonate radical ion to produce fine basic zinc carbonate precipitate; washing the precipitate with ethanol, methanol or acetone, filtering, stoving at 40-80 deg.c and heating at 200-800 deg.c to decompose into nanometer zinc oxide. The production process is simple and has low cost.

The invention provides a method for treating glyphosate mother liquor by an oxidation method, which comprises the following steps: firstly, using regulating agents for regulating the pH value of the glyphosate mother liquor with organic phosphor or glyphosate or nitrogenous compounds or salt to 0.1 to 14; then, carrying out the pressurized oxidation reaction with strong oxidizing gas under the condition of the existence of catalysts; oxidizing phosphorus-containing impurities such as glyphosate, glyphosine, orthophosphorous acid, methyl glyphosate, aminomethyl phosphonic acid, N-(Phosphonomethyl) iminodiacetic acid and the like into phosphate radical ions; oxidizing nitrogenous organic impurities such as glycin, triethylene ammonia, diethanolameine, aminomethyl phosphonic acid, hydroxyethyl glycine and the like into ammonia radical ions; and then, carrying out concentration and separation to obtain phosphate and amine salt inorganic compounds for recovery and reuse. The invention can effectively oxidize the complicated organic phosphor and the nitrogenous compounds in the glyphosate mother liquor into single phosphate radicals and amine salt inorganic compounds for convenient recovery and reuse, and can simultaneously reduce the environment pollution and the soil hardening caused by the mother liquor. Thereby, the total conversion rate of the phosphorus-containing compounds reaches 60 to 90 percent, the conversion rate of the nitrogenous compounds reaches more than 90 percent, in addition, the removal rate of the glyphosate reaches 95 to 99 percent, a large amount of produced phosphate and amine salt can be used for agricultural fertilizers, and the goal of changing waste materials into valuable materials is achieved.

The invention provides a method for preparing calcium carbonate by using catalysis of microbial carbonic anhydrase, which comprises the following steps of: adding the carbonic anhydrase extracted from a microbial culture into a liquid system containing calcium ion and bicarbonate radical ion solution or a gas diffusion system containing calcium ion solution and releasing CO2 by using ammonium hydrogen carbonate solution, performing oscillating reaction at room temperature, controlling initial pH at 5 to 10, taking out the produced sediment, and performing filtration, washing and drying to obtain the calcium carbonate. The method makes full use of microbial resources and characteristics of specificity and high efficiency of enzyme catalytic reaction, prepares the calcium carbonate by accelerated deposition, and has the advantages of riche resources, simple process, clean environment, low cost, high efficiency, quickness and the like. The calcium carbonate prepared by deposition has high purity, is calcite crystal calcium carbonate, can be used as an industrial filler, and can also be used for repairing cracks of building engineering, buildings, stone landscapes and carved stone cultural relics.

The invention discloses a method for simultaneously determining inorganic anions and organic acid radical ions in salt lake brine. The method is characterized by preprocessing a certain quantity of samples of the salt lake brine, simultaneously separating and determining 6 types of inorganic anions comprising F<-1>, Cl<-1>, NO2<-1>, Br<-1>, NO3<-1> an SO4<2-> and 3 types of organic acid radical ions comprising CH3COO<-1>, HCOO<-1> and C2O4<2-> in the salt lake brine by carrying out secondary gradient elution through an ion chromatography. The result shows that the method is simple and convenient, high in accuracy and capable of providing the important reference basis for simultaneously separating and determining a plurality of anions in the salt lake brine and exploring resources of the salt lake.

The invention relates to a preparation method for shape-controllable nano iron oxide and particularly relates to a hydro-thermal synthesis method for shape-controllable nano iron oxide. The hydro-thermal synthesis method comprises the following steps: (1) weighing dihydric phosphate, strong acid and strong alkali salts and trivalent iron salt; mixing and adding a mixture into de-ionized water; agitating until the mixture is completely dissolved to obtain a precursor solution, wherein the mol ratio of phosphate radical ions to trivalent iron ions in the precursor solution is (0-3) to 10; the mole ratio of the strong acid and strong alkali salts to the trivalent iron ions is (0-5) to 10; the mass of the de-ionized water is 50-300 times as much as the total mass of the dihydric phosphate, the strong acid and strong alkali salts and the trivalent iron salt; and (2) putting the precursor solution into a reaction kettle and heating to 150-250 DEG C and preserving the heat for 2-4 hours; cooling to the room temperature and adding the de-ionized water and alcohol into an obtained product; sufficiently shaking and centrifuging; removing liquid supernatant and transferring content matters into an electric heating vacuum drying box; drying until the weight is constant to obtain the nano iron oxide.