2499 results about "Sulfur hydride" patented technology

The invention relates to the technical field of equipment fault prediction, in particular to a coal mine equipment fault prediction system and method based on big data, and the method comprises the following steps: collecting the thickness of a biological membrane on the surface of equipment, synchronously collecting the vibration acceleration of the equipment and the environmental hydrogen sulfide concentration, and constructing a corrosion multi-mode data set; performing electrochemical noise separation on the corrosion multi-modal data set, and constructing a corrosion activity fingerprint spectrum; decoupling a coupling effect of mechanical vibration and microbial corrosion, and generating a corrosion-fatigue damage correlation map; and constructing a dual-channel life prediction model based on the corrosion-fatigue damage correlation map, and setting an early warning mechanism. Microbial corrosion characteristic current is accurately extracted through wavelet packet decomposition and wavelet entropy analysis, a corrosion-vibration heterogeneous graph is established by adopting a graph attention network, corrosion-induced structural vibration enhancement effect analysis is realized, and compared with a traditional prediction method based on a single signal, the method has the advantages that the method is simple and convenient to operate. And the problems of limited local corrosion influence range, unstable vibration response and the like are effectively solved.

A process system and process method for treating hydrogen sulfide-containing acid gas. The process system comprises a sulfur recovery unit, a tail gas treatment unit having an acid gas concentration function, and a flue gas alkaline scrubbing unit. The method comprises: subjecting sulfur-containing tail gas to concentration treatment by means of an absorption column (1) of the tail gas treatment unit, and then introducing same into the sulfur recovery unit to undergo a Claus reaction for separation, so as to obtain sulfur and sulfur recovery tail gas; introducing the sulfur recovery tail gas into the tail gas treatment unit, successively carrying out combustion and hydrotreating, and introducing the obtained gas into the absorption column (1) of the tail gas treatment unit; and in the tail gas treatment unit, introducing gas absorbed by the absorption column (1) into the flue gas alkaline scrubbing unit, and successively carrying out incineration and alkaline scrubbing, so as to discharge desulfurized gas. The content of SO2 in the tail gas treated by the process system is ≤50 mg / Nm3, and the requirements for full-period standard reaching of sulfur dioxide emission of tail gas during startup, shutdown and normal operations can be satisfied.

The invention discloses a hydrogen sulfide leakage abnormity monitoring method and system, and relates to the technical field of gas monitoring. A hydrogen sulfide leakage abnormity monitoring system comprises a data monitoring module, an airflow correction module, a twinborn inversion module, an association judgment module, a leakage confirmation module, a linkage control module and a monitoring updating module. According to the invention, the gas flow field correction is carried out on the hydrogen sulfide concentration by constructing the gas flow vector model and calculating the gas diffusion disturbance coefficient, so that the monitoring result is closer to the real gas distribution, and the space precision and reliability of leakage detection are improved; by establishing a double-physical-field digital twinborn model of a battery thermal field and an airflow field, corrected concentration data is introduced into a coupling domain for numerical evolution, and space inversion positioning and diffusion path prediction of hydrogen sulfide concentration abnormity are realized.

The invention relates to a rabbit meat freshness detection method based on an electronic nose technology. The volatile gas release mode of the rabbit meat under different storage conditions including temperature, humidity and time is analyzed through experiments, and key putrefying gas including dimethylamine, hydrogen sulfide and aldehydes and the concentration change trend are recognized; a metal oxide semiconductor (MOS) or an electrochemical sensor matched with the gas is screened according to the identified main decay gas, and a sensitive material means comprising a tin oxide thin film doped with platinum is optimized; a response matrix of different sensors to target gas is established through experiments, and a multi-sensor signal fusion algorithm is optimized; a temperature and humidity sensor is introduced, and environmental noise correction is performed in combination with odor signals; adopting a convolutional neural network feature extraction method to extract nonlinear features associated with the rabbit meat decay stage; docking the extracted smell features with the dynamic distribution model, and unifying the quantization dimension through a feature standardization algorithm; and correcting the predicted corruption trend in real time in combination with a smell distribution dynamic model.

The invention relates to the technical field of auxiliary devices of detection equipment, in particular to a robot and method for detecting the stability of the wall of a pile hole and poisonous gas in the hole, and the robot can be automatically clamped according to the size of the pile hole and automatically ascends and descends for detection after being clamped. The method for detecting the soil texture of the poison gas in the deep pit comprises the following steps: according to the types of harmful gases possibly existing, oxygen, methane, hydrogen sulfide, carbon monoxide and the like, detecting the soil texture of the poison gas in the deep pit, and detecting the soil texture of the poison gas in the deep pit. A multi-parameter gas detector capable of detecting the gases is selected, so that all operators are properly trained to know how to correctly use the detector and deal with emergency situations; and determining that the sensor works normally and is not damaged or blocked, and placing the gas detector at different heights of the pile hole, generally performing detection once from the bottom to the top at a certain distance so as to obtain comprehensive data.

The invention relates to the technical field of odor emission reduction, in particular to an odor emission reduction control system and method for livestock and poultry manure compositing. According to the system and the method, concentration changes of ammonia gas, hydrogen sulfide and volatile organic compounds and temperature and humidity data in a composting environment are accurately obtained through real-time performance and multi-parameter association of gas monitoring in the composting process; the method comprises the following steps of: calculating a diffusion path, a speed and a coverage area of gas in a compost body through finite element analysis, quantifying the distribution characteristics of gas concentration in space, optimizing the wind speed, the wind quantity and the layout of a ventilation system, and improving the ventilation efficiency. Pattern recognition is performed on compost environment gas emission data through the convolutional neural network, the turning frequency and the compost microenvironment are dynamically adjusted in combination with the gas concentration, a gas emission high-value area and a main guide source are accurately positioned, accurate control over compost fermentation odor emission is achieved, and the systematicness and refinement level of compost odor treatment is improved.

The invention provides a gas extraction multi-parameter monitoring method and system based on edge calculation, and relates to the technical field of coal mine gas extraction. The method comprises the following steps: arranging multi-parameter sensor nodes in drill holes, pipelines and gas gathering stations, and accessing an edge calculation unit; performing time synchronization, zero drift correction, outlier elimination and normalization on the data of the gas concentration, the negative pressure, the flow, the temperature, the humidity and the hydrogen sulfide concentration to generate feature vectors; calling a lightweight neural network model for reasoning, and outputting an extraction efficiency score and a leakage risk degree; when the risk degree exceeds the limit, an acousto-optic alarm is triggered and a speed reduction instruction is issued; when the efficiency is insufficient, the negative pressure is adjusted; compressing and encrypting the result, and reporting the result to a cloud platform through a wireless network at regular time; and the cloud performs model incremental training based on historical data and feedback, and issues an update model through hot replacement. According to the invention, local intelligent analysis, rapid early warning and dynamic adaptive optimization are realized.

The invention discloses a gas sensing material based on Ag / Pd-LaFeO3 and application of the gas sensing material in detection of hydrogen sulfide gas in municipal sewage, and relates to the technical field of gas sensing materials. The chemical formula of the gas sensing material based on Ag / Pd-LaFeO3 is X wt% of Ag-Y wt% of Pd-LaFeO3, wherein 0 lt; x < = 5, 0lt; y < = 5. According to the invention, on the basis of LaFeO3, the humidity interference resistance of the gas sensing material based on Ag / Pd-LaFeO3 can be improved through double noble metal surface modification of Ag and Pd. In addition, through double noble metal doping of Ag and Pd, the response sensitivity and selectivity of the prepared gas-sensitive material to H2S gas can be improved, and the working temperature of the gas-sensitive material is reduced. Specifically, at the working temperature of 110 DEG C, the response value of the prepared double noble metal modified LaFeO3 to 1ppm H2S gas is 46.16.

The present invention relates to a hydrogen sulfide content detection device, and in particular to a hydrogen sulfide content detection device inside a biogas tank. Provided is a hydrogen sulfide content detection device inside a biogas tank that can be easily moved and has accurate detection results. A hydrogen sulfide content detection device inside a biogas tank includes a mounting block, rollers, a bracket, a detector, a pipeline, etc.; rollers are rotatably provided on the front and rear sides of the left and right sides of the lower part of the mounting block, a bracket is provided on the top of the mounting block, a detector is provided on the upper part of the bracket, and pipelines are connected to the left and right sides of the upper part of the detector, and the upper part of the pipeline passes through the top of the bracket. After the straight pipe moves downward, it enters the biogas tank, thereby extracting the gas inside the biogas tank for the detector to detect the hydrogen sulfide content, so that the detection result is more accurate. At the same time, because the device is easy to move, it is convenient for the staff to detect other biogas tanks in turn.

The invention discloses a hydrogen sulfide pretreatment system and relates to the technical field of waste gas treatment. Comprising a tower body, the tower body is sequentially provided with a liquid outlet, a gas inlet and a gas outlet from bottom to top, and the tower body is fixedly connected with a liquid circulation system communicated with the liquid outlet; the cap-shaped part is fixedly connected to the tower body, a liquid storage push rod is installed on the cap-shaped part, a sealing plate is connected into the cap-shaped part in a sealed and sliding mode, and the sealing plate and the cap-shaped part jointly form a liquid storage cavity communicated with the liquid circulation system. Part of spraying liquid is temporarily stored in the liquid storage cavity, the spraying liquid in the liquid storage cavity is sprayed out when the liquid-gas ratio is imbalanced due to the fact that the valves, the pipelines and the liquid conveying pump go wrong, the flow of the spraying liquid in the tower body is adjusted, the stable liquid-gas ratio is maintained, and then the absorption and dissolution efficiency of the spraying liquid to hydrogen sulfide in waste gas is kept; and meanwhile, shutdown maintenance is not needed, so that economic loss caused by shutdown of a production line is avoided.

The invention belongs to the technical field of lithium battery materials, and particularly relates to a preparation method of high-purity lithium sulfide. Comprising the following steps: putting lithium hydroxide and pure water into a reaction kettle, replacing air in the reaction kettle with nitrogen, starting the reaction kettle, and stirring and heating; introducing quantitative hydrogen sulfide gas from the bottom of the reaction kettle, and circulating the gas in the reaction kettle between liquid in the reaction kettle and a gas space through a gas circulating pump; and after the temperature of the reaction liquid in the kettle is reduced to 20-30 DEG C, filtering in a nitrogen atmosphere, washing the residual solid with quantitative ammonia water, transferring the filtered solid into a drying box, and purging and drying with nitrogen until no water exists, thereby obtaining the high-purity lithium sulfide. In the solvent method, water is used for replacing an organic solvent for reaction, the problems of organic solvent separation and recovery, hazardous waste treatment and the like are avoided, the cost is reduced, and the method is environment-friendly.

The invention provides a preparation method of high-purity and low-cost lithium sulfide and lithium sulfide prepared by the preparation method, and relates to the field of lithium sulfide materials. According to the preparation method of the high-purity and low-cost lithium sulfide, on the basis of the characteristics of high-efficiency heat and mass transfer and uniform dispersion of a fluidized bed fluidization technology, lithium source small liquid drops are coated on the surface of a fluidized precursor, then hydrogen sulfide gas is introduced, the lithium source melt liquid drops or the precursor coated with the lithium source solution liquid drops are subjected to a contact reaction with the hydrogen sulfide gas, and the high-purity and low-cost lithium sulfide is obtained. The lithium sulfide is prepared. According to the preparation method of the high-purity and low-cost lithium sulfide, the problems of more reaction byproducts, low hydrogen sulfide gas utilization rate, easiness in product agglomeration and non-uniform particle size distribution in the existing lithium sulfide preparation process can be effectively solved, the reaction temperature is further reduced, and the production safety is improved; and the problem that the product purity and quality are influenced by water vapor in the preparation process is effectively avoided, and stable and efficient lithium sulfide production is realized.

The invention relates to the field of gas sensors, and discloses a hydrogen sulfide gas sensor and a method for detecting the concentration of hydrogen sulfide in gas. The hydrogen sulfide gas sensor comprises a substrate and a gas sensitive material, a cavity is formed in the substrate, the gas-sensitive material is located above the cavity, and the two ends of the gas-sensitive material are connected with the gold electrodes on the substrate; the gas sensitive material comprises graphene fiber and metal oxide loaded on the graphene fiber. The metal oxide is selected from one or more than two of oxides of Zn, Cd, Cu, Ni, Pd, Pt, Co, Ir, Fe, Mn, Cr, Mo, W, V, Ti, Mg and Al; the specific surface area of the gas sensitive material is 80-150m < 2 > / g; the loading capacity of the metal oxide is 0.05 to 5 weight percent. The hydrogen sulfide gas sensor can be self-heated, has high sensitivity to hydrogen sulfide gas, and is suitable for being applied to the field of gas monitoring.

The invention belongs to the technical field of preparation of hydrogen sulfide stress corrosion resistant oil well pipes, and relates to a 125ksi steel grade hydrogen sulfide stress corrosion resistant oil well pipe material suitable for a normal temperature environment containing 1MPa H2S and a preparation method of the 125ksi steel grade hydrogen sulfide stress corrosion resistant oil well pipe material. B, Ti, V and Nb elements are added, and the contents of Si, Mn and Ni elements, the Cr / Mo ratio and the sum of Nb, V and Ti in steel are controlled; the refined 100% sorbite structure, various compounds and microalloying are obtained through the processes of pure steel smelting, forging, controlled rolling and secondary heat treatment, so that high strength and high toughness in the 125 ksi range are obtained, and meanwhile the hydrogen sulfide corrosion resistance is high. The pipe product obtained by the process method disclosed by the invention has no corrosion cracking phenomenon after being subjected to a corrosion resistance test under the partial pressure of hydrogen sulfide of 1MPa.

Disclosed are a resin substrate-based iron oxyhydroxide desulfurizing agent and a preparation method therefor, falling within the technical field of gas purification and treatment. In the present disclosure, sodium percarbonate is used as a raw material to prepare iron oxyhydroxide. Sodium percarbonate serves both as an alkaline precipitant and as an oxidant. P-aminophenol and formaldehyde are subjected to condensation polymerization to form linear phenolic resin, which is then modified with terephthalyl alcohol to connect into a cross-linked network structure resin. The resin is used as a substrate to obtain the resin substrate-based iron oxyhydroxide desulfurizing agent. The preparation method of the present disclosure is simple and achieves a larger sulfur capacity and desulfurization efficiency, making it suitable for the removal of hydrogen sulfide from waste gas.

The invention discloses a rectification mechanism and a carbon disulfide production system containing the same. The rectification mechanism comprises an integrated rectification tower, and an inner cavity of a shell of the integrated rectification tower is sequentially divided into a function-integrated pre-separation and sulfur removal area, a main rectification and hydrogen sulfide removal area and a condensation reflux area from bottom to top in the vertical direction; the pre-separation and sulfur removal area comprises a settling tank arranged at the lower part of the shell, a gathering cover arranged above the inner wall of the settling tank, and a gas rising pipe I arranged above the gathering cover; the invention belongs to the technical field of chemical separation, and achieves the technical effects that multi-stage functions of pre-separation, main rectification, precise purification, final condensation and the like are innovatively integrated in a single tower, so that the fundamental simplification and compactness of the equipment structure are realized; in the traditional process, separate coarse removal, fine removal and finished product towers are replaced by unique expanded settling tanks in the towers, filler layers of integrated plate heat exchangers, tower tops with spiral condensation channels and side-draw systems.

The invention provides a method for preparing high-purity lithium sulfide from lithium carbonate, and belongs to the technical field of lithium material preparation, and the method comprises the following steps: heating a ball-milled mixture of industrial-grade lithium carbonate and an alumina additive to 750-900 DEG C, and carrying out heat preservation and calcination to generate lithium oxide; performing hydrolysis reaction on lithium oxide in hot water, and filtering to obtain a high-purity lithium hydroxide solution; mixing the lithium hydroxide solution with the sulfur-containing protein, and performing spray drying to obtain a mixed precursor; calcining the mixed precursor at a low temperature of 210-340 DEG C in an inert atmosphere; and heating to 550-660 DEG C, calcining at a high temperature, introducing hydrogen sulfide gas, reacting lithium hydroxide to generate lithium sulfide, and cooling to obtain the high-purity lithium sulfide. The invention provides the method for preparing the high-purity lithium sulfide, the purity, the production efficiency and the raw material utilization rate of the lithium sulfide are remarkably improved, and the technical defects of low purity, incomplete raw material reaction, non-uniform precursor mixing, complicated process, difficulty in large-scale production and the like in the traditional lithium sulfide preparation method are overcome.

The invention provides a nitrogen-sulfur double-doped layered manganese dioxide material as well as a preparation method and application thereof, and relates to an electrochemical energy storage material. Thiourea is placed in a first temperature area, manganese dioxide is placed in a second temperature area (150-200 DEG C), the thiourea is decomposed into hydrogen sulfide and ammonia gas in the first temperature area, the hydrogen sulfide and the ammonia gas are carried by carrier gas to be conveyed into the second temperature area to be subjected to doping reaction with the manganese dioxide, and the nitrogen-sulfur double-doped layered manganese dioxide material is obtained. The manganese dioxide is delta-phase layered manganese dioxide. Nitrogen and sulfur elements are doped into manganese dioxide through a low-temperature roasting method, the intrinsic conductivity and structural stability of manganese dioxide are improved, the material has high reversible capacity, and the formation of part of oxygen vacancies can help the material expose active sites, so that the overall capacity of the material is improved. The nitrogen-sulfur double-doped layered manganese dioxide material is used as a positive electrode material for a zinc ion battery, and has excellent electrochemical performance.

The invention discloses an oil field desulfurizer and a preparation method thereof. The preparation method comprises the following steps: dissolving 1, 3-propane sultone in toluene, dropwise adding equimolar 1-methylimidazole under an ice-water bath, and heating to room temperature for reaction after dropwise adding; separating out a product after the reaction is finished, and dropwise adding equimolar concentrated sulfuric acid to obtain imidazole ionic liquid; mixing the imidazole ionic liquid with a catalytic promoter to obtain a catalyst; the preparation method comprises the following steps: adding paraformaldehyde, a triazine compound and a catalyst into a solvent, heating to 50-90 DEG C, controlling a reflux reaction for 6-9 hours, and after the reaction is finished, carrying out reduced pressure distillation to remove the solvent and separate out the catalyst, thereby obtaining the oil field desulfurizer. The desulfurizer is a modified triazine compound with a novel structure, N and lateral branch functional groups on a triazine ring of the desulfurizer can react with hydrogen sulfide, and compared with a conventional triazine desulfurizer, a plurality of desulfurization points are added, so that the sulfur capacity is greatly improved.

The invention discloses an experimental device and an experimental method for researching a hydrogen sulfide elutriation mechanism of a sulfur-containing gas reservoir, and belongs to the technical field of natural gas exploitation, the experimental device for researching the hydrogen sulfide elutriation mechanism of the sulfur-containing gas reservoir comprises an artificial core model; at least one acquisition element; and at least one pipe body part and an injection-production assembly. By arranging the pipe body part composed of the inner pipe part and the outer pipe part which can rotate oppositely, the position relation between the inner outlet set on the inner pipe part and the outer outlet set on the outer pipe part can be correspondingly adjusted through relative rotation between the inner pipe part and the outer pipe part, so that the pipe body part and the artificial rock core model are communicated at different layer positions, and the artificial rock core model can be conveniently and rapidly constructed. Therefore, the control operation of the gas injection-production layer is realized, and the simulation of different reservoirs is realized.

The invention relates to the technical field of baby diapers, in particular to an intelligent baby diaper replacement reminding system integrated with hydrogen sulfide detection, which is used for determining a reference acquisition frequency of each time interval in a time period based on historical multi-dimensional monitoring data of a target user; then determining the necessity of hydrogen sulfide detection at the current acquisition moment based on the multi-dimensional monitoring data in the backtracking time window at the current acquisition moment, and then adjusting the reference acquisition frequency of the current time interval based on the necessity of hydrogen sulfide detection at the current acquisition moment to obtain a final acquisition frequency; acquiring multi-dimensional monitoring data based on the final acquisition frequency in the remaining time interval in the current time interval; and finally, based on the multi-dimensional monitoring data acquired in real time, generating a diaper replacement reminding signal.

The invention discloses a method for preparing 12-mercaptan through solid organic acid catalysis, belongs to the technical field of 12-mercaptan preparation, and aims to solve the problems of low catalyst activity, harsh reaction conditions, serious pollution, high cost and dependence on import in the prior art. N-dodecanol and hydrogen sulfide are used as raw materials and are mixed according to the molar ratio of 1: 1.2-1: 1.3; the method comprises the following steps: gasifying n-dodecanol, mixing with purified hydrogen sulfide, preheating to 210-240 DEG C, introducing into a fixed bed reactor filled with a solid organic acid catalyst, and reacting at-0.08-3.0 MPa for 3.5-4 hours; and cooling and condensing the reaction product, carrying out gas-liquid separation, rectifying and purifying the liquid product to obtain 12-mercaptan with the purity of more than or equal to 99.5%, and recycling unreacted hydrogen sulfide. The solid organic acid can be a catalyst of p-toluenesulfonic acid and the like or mesoporous silica loaded nickel, cobalt and molybdenum metal oxides. The method has the advantages of high catalytic activity, mild reaction conditions, high product yield (the conversion rate of n-dodecanol is greater than or equal to 94.5%), environmental protection and low cost, can realize the domestic mass production of 12-mercaptan, and meets the market demand.

The invention provides high-toughness hydrogen sulfide corrosion-resistant steel for a seamless steel pipe for drilling and production, a production method of the high-toughness hydrogen sulfide corrosion-resistant steel, a seamless steel pipe heat treatment process and application of the high-toughness hydrogen sulfide corrosion-resistant steel. The high-toughness hydrogen sulfide corrosion-resistant steel comprises the following components: 1.00-1.30% of Cr, 0.50-0.70% of Ni, 0.90-1.10% of Mo, 0.020-0.050% of Al, 0.10-0.20% of V, 0.10-0.20% of Nb, 0.20-0.25% of C, 0.15-0.30% of Si, 0.50-0.70% of Mn, less than or equal to 0.010% of P, less than or equal to 0.0015% of S and the balance of Fe and inevitable impurities. A Cr-Mo-Ni system is adopted and supplemented with microalloy elements such as Nb and V to improve the obdurability and improve the SSC resistance. And through two times of thermal refining, the dislocation density of the material is reduced, and the loading strength of a NACE TM0177 standard A solution is met.

The invention relates to a spherical hydrotalcite phase desulfurization adsorbent as well as a preparation method and application thereof, the preparation method comprises the following steps: mixing an iron source, a nickel source and organic carboxylate, and then carrying out hydrothermal carbonization reaction to obtain the spherical hydrotalcite phase desulfurization adsorbent. The nickel source and the iron source are selected as the raw materials, hydroxide radicals of laminates and carbonate ions between the laminates of the prepared hydrotalcite phase desulfurization adsorbent can increase the alkalinity of the surface of the desulfurization adsorbent and improve the adsorption capacity to hydrogen sulfide, and meanwhile, the hydrotalcite phase desulfurization adsorbent can react with hydrogen sulfide in a catalytic oxidation manner, so that the removal efficiency is improved. Organic carboxylate is selected as a hydrothermal auxiliary agent, carboxylate radicals can chelate metal ions through multidentate coordination to form a stable complex, so that the nucleation rate of hydrotalcite is delayed, the particle size uniformity is improved, meanwhile, a carbon coating layer is generated through hydrothermal carbonization, and pores in the carbon coating layer and pores in hydrotalcite can form hierarchical pore channels, so that the composite material is prepared. The mass transfer efficiency is synergistically improved, so that the adsorption capacity of the adsorbent is improved.

The invention provides paracoccus pantotrophus, a deodorant composed of the paracoccus pantotrophus and application of the deodorant, and belongs to the technical field of microbial agents. According to the invention, a paracoccus pantotrophus strain is screened from biogas residues of a pig farm, is named as Paracoccus pantotrophus SZZ1 and is preserved in the China Center for Type Culture Collection, the preservation address is Wuhan University, Wuhan, China, and the biological preservation number is CCTCC M20242509. The SZZ1 strain is used for animal manure fermentation, and results show that the microbial inoculum can effectively reduce odor generated during manure fermentation, and especially has a significant inhibition effect on release of hydrogen sulfide. Therefore, the method not only enriches the types of existing deodorization strains, but also has an excellent removal effect on hydrogen sulfide and a stable and lasting deodorization effect, and is suitable for popularization and application.

The invention discloses a sulfur-containing natural gas detection method and a sulfur-containing natural gas detection system, and relates to the technical field of oil and gas measurement. A detection system based on a sulfur-containing natural gas medium comprises a standard flow measurement unit, a hydrogen sulfide filling system, a detected flow measurement unit and a hydrogen sulfide recovery system. The standard flow measurement unit, the detected flow measurement unit and the hydrogen sulfide recovery system are sequentially arranged in the natural gas inlet direction. The hydrogen sulfide filling system, the detected flow measurement unit and the hydrogen sulfide recovery system are connected in series; the standard flow measuring unit and the hydrogen sulfide filling system are connected in parallel, flow detection of the detected flow measuring unit is not affected by the content of hydrogen sulfide components in an upstream gas source by adjusting the hydrogen sulfide filling system, the gas quality condition and the detection flow of the high-sulfur-content natural gas flowmeter are covered more widely, and stability is better. And the accuracy of the measurement result of the flowmeter used on site is improved.

A method for synergistically preparing lithium sulfide by vacuum molten salt based on hydrogen sulfide-lithium salt reaction belongs to the technical field of battery materials, and comprises the following steps: placing a lithium salt solid in a reactor, introducing a molten salt medium on the surface of the lithium salt or in a reaction system, introducing purified hydrogen sulfide gas under a vacuum auxiliary condition, controlling the reaction temperature to be 200-500 DEG C, and reacting for 1-2 hours; and adjusting the flow rate of hydrogen sulfide to be 50-1000mL / min and the retention time to be 5-180min, continuously exhausting gas to discharge water vapor in the reaction process, stopping introducing hydrogen sulfide gas after the reaction is finished, cooling the system to room temperature under the protection of inert gas, taking out the product, washing to remove residual fused salt, and carrying out vacuum drying to obtain the high-purity lithium sulfide. The prepared lithium sulfide has high purity (greater than or equal to 99.90%), low defect density and an excellent crystal structure, and can be widely applied to lithium-sulfur batteries, all-solid-state batteries and novel energy storage technologies, so that the energy density is improved, the cycle life is prolonged, and the energy consumption is reduced.

The invention provides a sulfur-tolerant shift pre-transformation protective agent as well as a preparation method and application thereof, and relates to the technical field of sulfur-tolerant shift. The magnesium aluminate spinel, the nickel aluminate spinel and the activated carbon are used as composite carriers, the cobalt is used as a main conversion active component, the detoxification carriers have good adsorption and removal effects on arsenic compounds and small-particle impurities, the arsenic capacity is large and is not influenced by the content of hydrogen sulfide, the conversion activity of the protective agent is moderate, the temperature rise of a bed layer is controllable, and the conditions of large temperature rise and overtemperature are avoided; the influence of a water-carrying working condition on the catalyst is greatly avoided, and the catalyst is suitable for a pre-shift furnace and a detoxification tank in a sulfur-tolerant shift process.

The invention relates to the technical field of gas detection, in particular to response type aerogel and application thereof. The response type aerogel is prepared according to the following steps: mixing and dissolving a metal organic framework material and lead acetate to obtain an adsorption and response integrated probe; mixing silk fibroin, polyethylene glycol diacrylate and the adsorption-response integrated probe, and performing light curing reaction under the action of a photo-crosslinking agent to obtain the adsorption-response integrated probe. Wherein a double-grid aerogel substrate generated by reaction of silk fibroin and polyethylene glycol diacrylate can adsorb water molecules in environments with different humidity to wet the substrate, and a saturated microscopic water environment is provided for colorimetric reaction on the surface of a pore wall, so that interference of environmental humidity on response is effectively relieved. The quantitative method established by using the response type aerogel can be used for high-sensitivity quantitative detection of hydrogen sulfide in livestock and poultry farms.

The invention discloses a coal mine safety information intelligent monitoring system applying an industrial internet, and relates to the technical field of intelligent monitoring. During operation of the system, multi-source data are collected from equipment and subjected to primary processing, and data from different sources are subjected to space-time matching and association by using a data fusion technology; and obtaining a coal mine safety information early warning index Yjzs after calculation, analyzing the stress change and risk of the underground rock stratum, and simulating and predicting the chemical risk in the mine by processing the hydrogen sulfide diffusion rate and nitrogen oxide concentration gradient data and adopting a computational fluid dynamics (CFD) chemical reaction rate model. And monitoring and evaluating behaviors of coal miners and operation conditions of equipment, comparing a coal mine safety information early warning index Yjzs with a preset warning threshold value M and a danger threshold value N, generating a corresponding strategy scheme according to a comparison result, and dynamically adjusting the threshold value to adapt to different mine conditions and safety standards.