The invention relates to a synergistic spray charging and electrostatic dust collecting method by which a 
water spray charging device is combined with an electrostatic 
dust collector, 
flue gas is conditioned by using 
water spray, agglomeration of 
dust particles is promoted and the charging characteristic of the 
dust particles is improved through charging drops containing an agglomerating agent, thus the dust collection efficiency of the electrostatic 
dust collector is increased, the fine dust collecting efficiency is higher than 90 percent, and the concentration of 
smoke dust at an outlet is lower than 50 milligrams per cubic meter. The invention also discloses a synergistic spray charging and electrostatic dust collecting device which comprises the electrostatic 
dust collector and the 
water spray charging device, wherein the electrostatic dust collector is arranged on a 
flue; and the water spray charging device is arranged on a 
flue in front of an inlet of the electrostatic dust collector, or on a gradually expanded section of the inlet or on a position of a bottom second-stage or third-stage 
electric field in the electrostatic dust collector. The water spray charging device comprises a dual-fluid atomizing 
nozzle and a 
corona ring, wherein the dual-fluid atomizing 
nozzle is arranged at the front part of the 
corona ring, an insulator is arranged outside the upper end of the 
corona ring, and the 
corona ring is connected with a high-
voltage power supply through a wire. The synergistic spray charging and electrostatic dust collecting device has a simple structure, low cost and high dust collecting efficiency.