883 results about "Copper salt" patented technology

The invention discloses a composite electrode material for removing uranium through photoelectrocatalysis and a preparation method and application of the composite electrode material, and belongs to the technical field of catalytic materials and wastewater treatment.The preparation method of the composite electrode material comprises the following steps that a ZIF-8 material, copper salt and ferric salt are mixed, and a first metal composite material is prepared; reacting the first metal composite material with a KOH solution to prepare a second metal composite material; carrying out carbonization treatment on the second metal composite material, and then carrying out acid treatment by using acid to obtain a bimetallic atom catalytic material; the preparation method comprises the following steps: dispersing a bimetallic atom catalytic material and a g-C3N4 material in a mixed solution containing phytic acid and a Nafion solution to obtain catalyst ink; and coating the catalyst ink on a substrate, and carrying out illumination drying to obtain the composite electrode material. According to the composite electrode material, under the synergistic effect of the bimetallic single atomic cluster catalyst and g-C3N4, respective advantages are fully exerted, and efficient deposition removal of uranium is achieved.

The invention relates to the technical field of catalysts, and discloses a preparation method and application of a copper-based metal-organic framework catalytic material.The preparation method comprises the following steps that S1, cuprous salt, N, N '-bis (5-aminonicotinyl) naphthalimide and a solvent are mixed, and a mixture is obtained; s2, heating the mixture to a reaction temperature, carrying out a constant-temperature reaction, and cooling to obtain a crystal; and S3, washing and drying the crystal to obtain the copper-based metal-organic framework catalytic material. According to the preparation method of the copper-based metal-organic framework catalytic material provided by the invention, N, N '-bis (5-aminonicotinyl) naphthalimide is used as an organic ligand to prepare the copper-based metal framework Cu-PTD with N / O co-coordination, and the copper-based metal framework Cu-PTD has relatively strong electrocatalytic carbon dioxide reduction and electron transfer capabilities; and the catalyst has relatively high selectivity on electrocatalytic carbon dioxide reduction products.

The invention belongs to the technical field of lithium ion battery negative electrode materials, and particularly relates to a spinel type metal oxide coated hard carbon composite material based on a lattice matching mechanism, and a gradient doping preparation method of the spinel type metal oxide coated hard carbon composite material can overcome the defects that a hard carbon material is low in initial coulombic efficiency (about 50%), low in lithium ion transmission rate and poor in rate capability. According to the invention, magnesium salt, aluminum salt, copper salt and other metal salts are mixed with hard carbon, a precipitant is added, and a hydrothermal method is combined with a calcination process to obtain the core-shell structure composite material with hard carbon coated with a spinel structure. The technology has the following three obvious advantages: (1) lattice adaptive design of the spar type metal oxide and the hard carbon, (2) molybdenum-copper gradient doping repair of the SEI film, and (3) stable circulation of more than 5000 times at the capacity of 350mAh / g.

The invention relates to the technical field of new material detection, in particular to a copper foil coating content detection method. The method comprises the following steps: preparing a plurality of mixed standard solutions; the mixed standard solution comprises copper ions and at least one to-be-detected element ion; in the plurality of mixed standard solutions, the copper ion concentrations are the same and are first preset concentration values; measuring a plurality of mixed standard solutions, and establishing a standard curve between a theoretical value and a measured value of the ion concentration of each to-be-measured element; dissolving a plating layer on the surface of the to-be-detected copper foil by using nitric acid, and filtering to obtain a to-be-detected sample solution; adding copper salt into the to-be-detected sample solution to obtain a to-be-detected analysis solution; measuring the to-be-measured analysis solution to obtain the measurement concentration of each to-be-measured element ion; according to the measured concentration of each to-be-measured element ion and the corresponding standard curve, the corrected content of each to-be-measured element ion is obtained. The problem that an existing copper foil coating content detection method is low in detection accuracy is solved.

The invention discloses a lanthanum-doped CuMgAl catalyst as well as a preparation method and application thereof, and belongs to the technical field of catalysts. The preparation method of the lanthanum-doped CuMgAl catalyst comprises the following steps: adding a copper salt, a magnesium salt, an aluminum salt and a lanthanum salt into water to obtain a first solution; adding a precipitator into water to obtain a second solution; adding the second solution into the first solution to adjust the pH value to 10.5 to obtain a mixed solution, stirring the mixed solution to generate a co-precipitation reaction, after the reaction is completed, carrying out aging treatment to promote growth and structure ordering of layered double hydroxide crystals, and then carrying out calcination treatment to convert a layered double hydroxide precursor into an oxide, thereby obtaining the layered double hydroxide. And the lanthanum-doped CuMgAl catalyst is obtained. The lanthanum-doped CuMgAl catalyst prepared by the preparation method disclosed by the invention has excellent activity and stability.

This invention belongs to the field of wastewater treatment technology, specifically relating to a method for removing metallic impurities from acidic copper-containing etching wastewater at room temperature and pressure. The method includes the following steps: S1, adding an oxidant to the acidic copper-containing etching wastewater to conduct an oxidation-reduction reaction, obtaining a pretreatment solution; S2, adding phosphoric acid or soluble phosphate to the pretreatment solution, adjusting the pH to 1.3-1.7 using a pH adjuster, stirring, and filtering to obtain a purified copper-containing solution. The method provided by this invention achieves high removal rates for Fe, Ni, Zn, Ca, and Mg, while maintaining a high copper ion content. It can recycle and regenerate high-purity copper salt products for application in food, cosmetics, medical, electroplating, and other fields, while also reducing hazardous waste generation, improving economic efficiency, and significantly reducing costs.

The invention discloses a composite adsorbent for removing tetracycline in wastewater and a preparation method thereof, and relates to the field of wastewater treatment.The preparation method comprises the following steps that gasified slag and corn roots are pretreated and then mixed and pyrolyzed to prepare a magnetic biochar substrate, the magnetic biochar substrate is dispersed in a solvent, copper salt and organic ligands are added, and the magnetic biochar substrate is obtained; and collecting products through an external magnetic field to obtain the composite adsorbent for removing tetracycline in wastewater. A copper-based metal organic framework material grows in situ on a gasified slag / corn root biochar substrate, and the specific surface area of the material is increased by using a highly ordered porous structure of MOF; through the combined action of various mechanisms, the adsorbent shows extremely high adsorption capacity and good selectivity on tetracycline molecules.

The invention belongs to the technical field of wastewater treatment, and particularly relates to a method for removing metal impurities from acidic copper-containing etching wastewater at normal temperature and pressure. The method for removing the metal impurities from the acidic copper-containing etching wastewater at normal temperature and pressure comprises the following steps: S1, adding an oxidizing agent into the acidic copper-containing etching wastewater to carry out oxidation-reduction reaction to obtain a pretreatment solution; and S2, phosphoric acid or soluble phosphate is added into the pretreatment solution, the pH is adjusted to 1.3-1.7 through a pH adjusting agent, stirring and filtering are conducted, and the purified copper-containing solution is obtained. According to the method, the removal rate of Fe, Ni, Zn, Ca and Mg is high, high-content copper ions can be kept, a high-purity copper salt product can be recycled and regenerated to be applied to the fields of food, cosmetics, medical treatment, electroplating and the like, hazardous waste can be reduced, economic benefits are improved, and cost is greatly reduced.

The application belongs to the technical field of photo-thermal catalysts, and particularly relates to a molecular sieve photo-thermal catalyst for methane oxidation to prepare methanol and a preparation method thereof, the catalyst has a structural formula of Cu / M-ZSM-5, and the preparation method comprises the following steps: S1: uniformly mixing a silicon source, an aluminum source, a metal source, a template agent and water to form a starting gel; S2: performing hydrothermal crystallization, centrifugal separation, washing until neutral, and drying to obtain a molecular sieve raw powder; S3: performing calcination to obtain M-ZSM-5 molecular sieve; and S4: under ultrasonic wave conditions, ion exchanging M-ZSM-5 with a copper salt solution, and performing rotary evaporation and drying to obtain the Cu / M-ZSM-5 photo-thermal catalyst. The catalyst is filled into a fixed bed reactor, helium is introduced, the temperature is raised to an activation temperature, the catalyst is activated, and a mixed gas of methane, oxygen and water is introduced; when the doped metal is Zn, the methanol yield of the Cu / Zn-ZSM-5 photo-thermal catalytic methane is 100.05 micromoles g cat ‑1 h ‑1 , which is increased by 91% compared to the methanol yield of Cu / ZSM-5. The catalyst exhibits excellent catalytic performance and stability in the reaction of preparing methanol by photo-thermal catalysis of methane.

The invention relates to an enzyme response antibacterial carbon dot and a preparation method and application thereof.The carbon dot takes a copper-doped carbon dot as a core and is covalently grafted with a hyaluronic acid shell layer through amidation reaction to form a composite nano material Cu-CDs (at) HA, specifically, soluble copper salt and folic acid are subjected to a hydrothermal reaction to obtain the copper-doped carbon dot, carboxyl is activated through EDC / NHS in a buffer system, and the carbon dot is prepared. And performing grafting reaction with hyaluronic acid to obtain a target product. The hyaluronidase-containing antibacterial composition can be specifically degraded and release antibacterial components under the action of hyaluronidase, shows good bacterial responsive bactericidal performance, has the minimum inhibitory concentrations of 8 g / mL and 16 g / mL for staphylococcus aureus and escherichia coli respectively, and has peroxidase-like activity and free radical scavenging capacity. The antibacterial carbon dots can be used for preparing intelligent wound dressings, antibacterial coatings and other biomedical materials, and have the advantages of responsive drug release, efficient antibacterial property and promotion of wound repair.

The invention discloses a copper-based catalyst for preparing acetaldehyde through ethanol dehydrogenation as well as a preparation method and application of the copper-based catalyst. The preparation method comprises the following steps: S1, carrying out alkalization treatment on protic mordenite in a strong alkali solution to increase the number of surface hydroxyl groups of the protic mordenite; and S2, adding the mordenite obtained in the step S1 into a copper salt solution to load copper ions, and then sequentially carrying out low-temperature drying shaping and medium-temperature activation stages to obtain the copper-based catalyst with networked Cu-OH-Si-O bonds on the surface. Through the synergistic effect of alkali liquor regulation and control and staged oxygen roasting, the dispersity and stability of a Cu active center in the catalyst are improved, the acetaldehyde selectivity of the reaction of preparing acetaldehyde through ethanol dehydrogenation is also improved, and side reactions are inhibited. Carrying out heat treatment regeneration on the inactivated copper-based catalyst in an oxygen-containing atmosphere; and after regeneration, the networked Cu-OH-Si-O bond on the surface of the copper-based catalyst is reconstructed.

The invention discloses a preparation method of a biomass hard carbon negative electrode material, which is characterized by comprising the following steps: carrying out primary carbonization on a biomass material, sequentially introducing a phosphorus element, a boron element and a copper element, carrying out secondary carbonization on a modified hard carbon raw material, and introducing carbonyl to obtain the hard carbon negative electrode material. Preliminary carbonized powder, boric acid and phosphoric acid are added into a reaction kettle together for a low-temperature graphitization reaction, phosphorus and boron are introduced for a hard carbon raw material, the phosphorus can widen the spacing of a graphite layer, the boron can catalyze rearrangement of a graphitized carbon layer, then the hard carbon raw material and organic copper salt are mixed and ground in cooperation, secondary carbonization is conducted, and the hard carbon material is obtained. By introducing the copper element, graphitization of the product can be promoted, and meanwhile, copper atoms can also improve the conductivity; and glyoxylic acid is added to introduce carbonyl into the product, and the carbonyl can preferentially catalyze decomposition of the inorganic salt, so that decomposition of an organic solvent is inhibited, and then a uniformly distributed inorganic salt-rich SEI film is formed.

The invention provides a preparation method of ultrahigh-purity copper. The preparation method comprises the following steps: providing a first anode, a first cathode and an electrolyte; the electrolyte comprises the following components: a purified copper salt solution, inorganic acid, an oxidizing agent and an additive, the purified copper salt solution comprises purified copper salt and water, the purified copper salt comprises copper sulfate and copper nitrate, and the molar ratio of nitrate to sulfate in the purified copper salt solution is (1.5-9): 1; the additive comprises any one or a combination of at least two of an alcohol compound, polyacrylamide or a tetrazole compound; and the first cathode and the first anode are immersed in the electrolyte for electrochemical deposition, and the ultra-high-purity copper is obtained. The electrolyte composed of the purified copper salt solution, the inorganic acid, the oxidizing agent and the additive is adopted, the proportion of nitrate radicals to sulfate radicals in the purified copper salt solution is controlled, the impurity content of the sulfur element and the silver element in the electrolyte can be controlled, and preparation of the ultra-pure electrolytic copper is achieved.

The invention discloses superfine copper powder and a preparation method and application thereof, and belongs to the technical field of copper powder.The preparation method of the superfine copper powder comprises the following steps that a micro-channel reactor is provided, and the micro-channel reactor comprises a micro-mixer and a micro-reactor which are connected with each other; a copper salt solution, a reducing agent solution and a sodium hydroxide solution are injected into a micro-channel reactor to be evenly mixed, a mixed solution is obtained and then enters the micro-channel reactor to be subjected to a reaction, discharging is conducted, and the superfine copper powder is obtained. The injection flow rate ratio of the sodium hydroxide solution to the copper salt solution to the reducing agent solution is (0.5-2): (0.8-1.2): (0.8-1.2). According to the method, the uniformity and the preparation efficiency of the superfine copper powder are remarkably improved, meanwhile, the reaction time is greatly shortened, the yield and the purity of the superfine copper powder are remarkably improved, continuous and efficient preparation of the superfine copper powder is achieved, and the method has wide application prospects.

The invention discloses a biological patch material with dry-state adhesion and wet-state easy stripping characteristics and application thereof, and belongs to the field of biological medicine. The biological patch material is prepared according to the following steps: by taking water-soluble protein as a template and copper ions in water-soluble copper salt as a metal coordination center, carrying out self-assembly on the template and drug molecules with phenolic hydroxyl structures to form nanoflowers; mixing the acrylamide, the sodium alginate, the water-soluble calcium salt and the nano-flowers to obtain the water-soluble calcium-based water-soluble nano-flower fertilizer. The biological patch material is adhered to the skin through electrostatic interaction, covalent bonds, physical interpenetration and topological tissues. The patch has skin adhesion in a dry state, so that the patch is convenient to fix; after the patch is in contact with burnt skin, the patch absorbs water and swells, the adhesive force is obviously reduced, and painless, easy and non-invasive stripping is realized. In addition, the patch has immunoregulation performance, can prevent stimulation and anaphylaxis caused by long-term contact with the skin, and promotes burn repair.

The invention discloses a high-chlorine industrial wastewater treatment and chlorine recovery method, which comprises the following steps: sequentially adding copper sulfate and a carbon-sulfur reducing agent into to-be-treated high-chlorine wastewater according to a ratio, adjusting the pH value, generating chlorine-containing residues, precipitating and separating out the chlorine-containing residues from a water body, and carrying out decoloration treatment on dechlorinated tail water by adopting an electrolytic bath, copper sponge deposited at the cathode is subjected to impurity removal treatment and then is merged into a copper salt circulating system; chlorine-containing residues are subjected to dissolution and quality-divided treatment, an obtained solution phase is concentrated / crystallized, KCl is recycled, an obtained copper-containing precipitate and the sponge copper are combined and collected, the mixture is dissolved by means of dilute sulfuric acid in the oxidizing atmosphere, and the whole mixture returns to a wastewater dechlorination treatment system. CuSO4 is reduced to generate Cu < + > ions to precipitate and remove chloride ions in the wastewater, the obtained KCl product is used at a high value, and the cuprous precipitate is subjected to conversion treatment and is completely reused in the dechlorination process, so that the wastewater treatment cost is remarkably reduced, and the method has the obvious advantages of high dechlorination efficiency, no generation of solid wastes and the like, and is suitable for industrial production. And the method has wide adaptability to industrial circulating water containing 2.5-8.5 g / L of chlorine, membrane-process strong brine and the like.

The invention discloses a catalytic system for preparing amine compounds through nitro reduction and application of the catalytic system. The catalytic system comprises an alkaline aqueous solution, a reducing agent and a catalyst, the alkaline aqueous solution is an alkali metal hydroxide aqueous solution; the reducing agent is alkali metal hydroboron and / or alkaline earth metal hydroboron; the catalyst is copper salt lewis acid and / or other lewis acid; the other Lewis acid is selected from one or a combination of more of cobalt salt, ferric salt, zinc salt, manganese salt and palladium salt. When the catalytic system is used for reducing the aromatic nitro-compound, the using amount of a reducing agent is small, meanwhile, the using amount of an organic solvent is reduced, the reaction yield is high, the reaction is milder, and amplified production of the process is facilitated.

The invention relates to the field of electroplating sludge, and particularly discloses a selective separation and resource recycling method for copper in electroplating sludge. The method comprises the following steps: mixing and roasting electroplating sludge and sodium salt, and washing with water to obtain filter residues; then carrying out acid leaching on the filter residues to obtain an acid leaching solution containing iron, copper, nickel and zinc; then enabling the pickle liquor to sequentially pass through a first ion exchange column filled with monophosphate group chelating resin and a second ion exchange column filled with copper selective functionalized resin to selectively adsorb iron ions and copper ions respectively; then desorbing the resin adsorbing the copper by using an acid solution to obtain a copper-containing eluent; and finally, carrying out evaporation concentration and recrystallization treatment to obtain a high-purity copper salt product. According to the method, the separation selectivity and the recovery efficiency of copper in the electroplating sludge are fundamentally improved by adopting a chelating resin combination with specific functional groups and an optimized acid leaching-adsorption series process.

The present application belongs to the technical field of the synthesis of chiral boron compounds, and in particular relates to an MOF-Cu(II) / CMC composite material, and a preparation method therefor and the use thereof. The preparation method for an MOF-Cu(II) / CMC composite material of the present application comprises: dropwise adding an aqueous solution of sodium carboxymethyl cellulose to an aqueous solution of a bivalent copper salt, performing solid-liquid separation, mixing obtained composite microspheres with an organic solution of trimesic acid, heating the resulting mixture, and subjecting same to solid-liquid separation, so as to obtain an MOF-Cu(II) / CMC composite material. The MOF-Cu(II) / CMC composite material is used in an asymmetric chiral boron addition reaction. The reaction is performed at room temperature, involves mild conditions, is applicable to a wide range of substrates and has a high yield and enantioselectivity. Moreover, the method can achieve the synthesis of a chiral organic boride in a solvent having simple components, providing an efficient new method for the preparation of drug molecules and active intermediates, and also broadening the range of substrates used for the preparation of chiral organic borides.

The invention provides nanoscale superfine copper powder and a preparation method thereof, and belongs to the technical field of metal powder, the preparation method comprises the following steps: dispersing copper salt and a complexing agent in deionized water to obtain a copper salt solution; dispersing a reducing agent and a dispersing agent in deionized water to obtain a reducing solution; dispersing sodium hydroxide in deionized water to obtain a sodium hydroxide solution; the method comprises the following steps: heating a copper salt solution, a reduction solution and a sodium hydroxide solution to 45-80 DEG C, adding the reduction solution into the copper salt solution under a stirring condition, then adding the sodium hydroxide solution to obtain a mixed solution, and reacting for 2-3 hours; and after the reaction is finished, a suspension containing copper powder is obtained, and after solid-liquid separation, washing and drying are conducted, the nanoscale superfine copper powder is obtained. The method is simple in technological process, does not need special equipment and is suitable for industrial production. And the prepared nano copper powder is good in dispersing performance, uniform in particle size distribution, high in purity and suitable for being applied to the field of microelectronic components.

The invention discloses a three-dimensional graphene copper composite material based on in-situ interface chemical bonding and a preparation method and application of the three-dimensional graphene copper composite material, relates to the technical field of metal-based composite materials, and solves the problems of graphene dispersion and interface bonding. The preparation method of the three-dimensional graphene copper composite material comprises the following steps: dissolving soluble copper salt and an organic ligand in water to form a complex solution, adding copper powder into the complex solution, uniformly mixing, and drying to obtain precursor coated copper powder; and carrying out spark plasma sintering or vacuum hot pressed sintering on the precursor coated copper powder to obtain the copper powder. A three-dimensional interpenetrating continuous network formed by graphene is arranged in the prepared three-dimensional graphene copper composite material, the interface of the graphene and a copper matrix is a chemical bonding interface, the comprehensive performance is excellent, and the composite material has high conductivity (gt; 103% IACS) and a high strength (gt; the comprehensive performance of the composite material is far better than that of a composite material prepared by a traditional method, and the composite material is suitable for high-end electric conduction, heat conduction and structural function integrated components.

The invention relates to a high-entropy metal oxide catalyst and a preparation method and application thereof.The preparation method comprises the following steps that S1, ferric salt, cobalt salt, manganese salt, nickel salt, copper salt and organic alkaline matter are mixed to obtain a mixed solution, hydrothermal reaction is conducted, and a precursor is obtained; and S2, calcining the precursor at the temperature of 500-600 DEG C to obtain the high-entropy metal oxide catalyst. The high-entropy metal oxide catalyst uniformly doped with iron, cobalt, manganese, nickel and copper is prepared by adopting a hydrothermal reaction and calcination method, and the high-entropy metal oxide catalyst not only can efficiently catalyze ozone to remove antibiotics, but also can still keep an excellent antibiotic removal rate constant in a water body containing hetero ions and humic acid; and the anti-interference capability is excellent.

The invention discloses a method for detecting the content of elemental iron in a lithium iron phosphate material. The method comprises the following steps: separating magnetic foreign matters from the lithium iron phosphate material; the magnetic foreign matter is placed in the copper salt solution, a first solid matter is obtained through reaction, and the first solid matter comprises a copper element; and measuring the content of the copper element in the first solid substance to obtain the content of the elemental iron in the lithium iron phosphate material. According to the embodiment of the invention, the elemental iron and other iron-containing foreign matters in the magnetic foreign matters are subjected to differential treatment, and the content of the elemental iron in the lithium iron phosphate material is obtained according to the determination result of the content of the copper element obtained through the replacement reaction, so that the obtained detection result reduces the interference of non-elemental iron foreign matters on the content of the elemental iron, and the detection accuracy is improved. The detection accuracy of the content of the elemental iron in the lithium iron phosphate material is favorably improved.

The invention relates to the technical field of catalytic synthesis, in particular to a chloromethylation catalyst, a preparation method of the chloromethylation catalyst and a method for preparing high-purity ortho-position, meta-position and para-position chloromethyl styrene through the chloromethylation catalyst, and the chloromethylation catalyst is prepared by loading sulfonic acid compounds and (or) pyridine compounds and (or) copper salt on a molecular sieve. The method can improve the localization selectivity of chloromethylation. The method for preparing high-purity ortho-position, meta-position and para-position chloromethyl styrene comprises the following steps of: reacting beta-bromophenylethane, paraformaldehyde and lewis acid in the presence of the chloromethylation catalyst to generate chloromethyl beta-bromophenylethane, and then performing elimination reaction under an alkaline condition to generate a chloromethyl styrene crude product; the high-purity ortho-position, meta-position and para-position chloromethyl styrene is obtained after the crude product is rectified, the brand-new catalyst is adopted in the method, the reaction selectivity is enhanced, the process is simple, and industrial production is facilitated.

The invention relates to the technical field of metal-based-organic framework catalysts, in particular to a catalytic material, a preparation method and application in electro-catalysis of carbon dioxide reduction.The Cu-BIBT catalytic material is prepared by mixing bivalent copper salt and BIBT organic ligand in a solvent and then controlling the heating-constant temperature-cooling process, and the material can be used for catalyzing reduction of carbon dioxide under the strong alkali condition (pH = 14). The copper-based metal-organic framework material prepared by the preparation method disclosed by the invention has the advantages that the copper-based metal-organic framework material keeps a stable copper-based metal-organic framework structure, has relatively strong CO2RR electro-catalysis and electron transfer capabilities, has relatively high selectivity on C2 + products in the CO2RR electro-catalysis, and greatly reduces the generation difficulty of the C2 + products in the CO2RR electro-catalysis.

The invention relates to the technical field of photocatalysis and nano materials, in particular to ZnO / CuO multistage microspheres with atomic-scale heterogeneous interfaces and oxygen vacancies as well as a preparation method and application of the ZnO / CuO multistage microspheres. The preparation method comprises the following steps: jointly dissolving soluble zinc salt, soluble copper salt and 1, 3, 5-benzene tricarboxylic acid in a composite solvent composed of glycerol and absolute ethyl alcohol, and carrying out solvothermal synthesis reaction to obtain Zn / Cu-MOFs multistage microspheres; the Zn / Cu-MOFs multistage microspheres are used as a precursor, and the ZnO / CuO multistage microspheres with atomic-scale heterogeneous interfaces and oxygen vacancies are obtained through calcination treatment. According to the preparation method disclosed by the invention, a solvothermal method is combined with a calcining process, so that uniform compounding and tight combination of ZnO and CuO are realized, the oxygen vacancy concentration of the ZnO / CuO multistage microspheres with atomic-scale heterogeneous interfaces and oxygen vacancies is effectively regulated and controlled, and a novel functional material which is high in performance and easy to prepare is provided for the field of photocatalysis.

The invention discloses a circuit board line deposition method and a circuit board line, and belongs to the technical field of circuit board manufacturing, and the method comprises the steps: carrying out the pretreatment of a substrate, the surface of which does not contain a copper foil, and forming a through hole in the substrate; forming graphical printing ink on the surface of the pre-treated substrate; putting the patterned substrate into a chemical copper deposition tank containing a copper salt and a reducing agent, and enabling copper ions to be reduced and separated out to be attached to the hole walls of the through holes and the surface of the substrate which is not covered by the ink under the catalytic action, so as to obtain a copper layer with a target thickness and complete the manufacturing of a circuit layer; the thickness of the ink is greater than or equal to that of the copper layer. The thick copper is directly deposited on the surface of the substrate without the copper foil by combining the circuit deposition process and the thick copper deposition process aiming at the substrate without the copper foil on the surface, so that the cost can be continuously reduced, and the manufacturing cost is greatly reduced through new process development on the premise of meeting the product quality.

The invention discloses an aromatic polycarboxylic acid copper-based catalyst as well as a preparation method and application thereof. The method comprises the following steps: respectively dissolving a copper salt and an aromatic polycarboxylic acid ligand, slowly dropwise adding the obtained copper salt solution into an aromatic polycarboxylic acid ligand solution, uniformly mixing, and synthesizing a series of aromatic polycarboxylic acid copper-based catalysts by adopting a solvothermal method. The preparation method is simple in operation process, mild in reaction condition and easy to regulate and control. By regulating and controlling the solvent, the reaction temperature, the reaction time, the reactant variety and proportion and the like in the system, the copper-based catalyst which shows high selectivity of multi-carbon products in the electro-catalysis carbon dioxide reduction reaction can be synthesized, and the selectivity of C2 products such as ethylene and ethanol is up to 77%.

The application relates to the development and technical field of electrocatalysts, and discloses a benzothiadiazole modified single-atom zirconium-doped metal copper electrode material and a preparation method and application thereof. The preparation method comprises the following steps: dissolving inorganic copper salt and inorganic zirconium salt, adding the inorganic copper salt and the inorganic zirconium salt into an alkaline solution, and performing hydrothermal reaction to obtain a single-atom zirconium-doped copper oxide precursor; dissolving benzothiadiazole, adding the benzothiadiazole into a dispersion solution of the single-atom zirconium-doped copper oxide precursor to obtain a mixed solution; spraying the mixed solution on a polytetrafluoroethylene film substrate loaded with copper nanoparticles to obtain a benzothiadiazole modified single-atom zirconium-doped copper oxide precursor electrode material; and performing electrochemical reduction treatment on the benzothiadiazole modified single-atom zirconium-doped copper oxide precursor electrode material to obtain a benzothiadiazole modified single-atom zirconium-doped metal copper electrode material. The electrode material is applied to an electro-reduction carbon dioxide reaction as a working electrode, exhibits excellent electro-reduction CO2 performance in an acidic environment, and realizes high-value-added C 2+ product with high selectivity.

The invention discloses a copper ion mediated bivalirudin self-assembled nano-drug and a preparation method and application thereof, and belongs to the field of biological medicines.The preparation method comprises the following steps that bivalirudin and targeting peptide cRGD are dissolved in an organic solvent, copper salt is dissolved in deionized water, the organic solution and an aqueous solution are mixed, the pH is adjusted to be faintly acid or neutral, and the copper ion mediated bivalirudin self-assembled nano-drug is obtained; and fully stirring and reacting to obtain a suspension, centrifuging to remove supernate, and freeze-drying to obtain the freeze-dried powder. On the basis of a metal coordination polypeptide self-assembly strategy, metal ions are introduced on the basis of traditional polypeptide self-assembly, special reaction performance is introduced through coordination of polypeptide functional groups and the metal ions to participate in regulation and control of the polypeptide self-assembly process, and thrombus targeting peptide is introduced on the basis to achieve precise drug delivery at the thrombus part.