462 results about "Copper hydroxide" patented technology

A method of preserving wood includes injecting into the wood an effective amount of a aqueous wood-injectable biocidal slurry, said a wood-injectable biocidal slurry containing dispersants and sub-micron biocidal particles selected from at least one of the following classes: 1) a plurality of particles containing at least 25% by weight of a solid phase of sparingly soluble salts selected from copper salts, nickel salts, tin salts, and/or zinc salts; 2) a plurality of particles containing at least 25% by weight of a solid phase of sparingly soluble metal hydroxides selected from copper hydroxide, nickel hydroxide, tin hydroxide, and/or zinc hydroxide; 3) a plurality of particles containing at least 25% by weight of a solid phase comprising a substantially-insoluble organic biocide selected from triazoles, chlorothalonil, iodo-propynyl butyl carbamate, copper-8-quinolate, fipronil, imidacloprid, bifenthrin, carbaryl, strobulurins, and indoxacarb; 4) a plurality of particles containing on the outer surface thereof a substantially-insoluble organic biocide; 5) a plurality of particles containing a solid phase of a biocidal, partially or fully glassified composition comprising at least one of Zn, B, Cu, and P. The particles may advantageously contain metallic copper, a leachability barrier, pigments, dyes, or other adjuvants disposed on the outer surface thereof.

A method for preserving wood by injecting into the wood a slurry having: particles of a sparingly soluble copper salt, copper hydroxide, or both, wherein the weight average diameter d₅₀ of the particles in the slurry is between 0.1 microns and 0.7 microns and the d₉₈ of the particles in the slurry is less than about 1 micron; a dispersant; and water. The dispersant is anionic or a mix of anionic and non-ionic. Advantageously, less than 20% by weight of the particles have a diameter less than 20 nanometers. Useful copper salts include basic copper carbonate, tri-basic copper sulfate, copper oxychloride, basic copper nitrate, basic copper borate, copper borate, basic copper phosphate, or copper silicate. The slurry most preferably includes copper hydroxide particles. The slurry further advantageously includes at least one organic biocide, wherein at least a portion of the organic biocide is coated on the particles.

The invention provides an electrode material in a hollow tubular structure, and the electrode material is in the hollow tubular structure which consists of a composite hydroxide/copper hydroxide/copper-contained metal substrate. The chemical formulation of the composite hydroxide is MxM'y(OH)2, wherein M is Ni2+ or Co2+, M' is Co2+, Al3+, or Fe3+. According to the invention, a method of solution dipping and constant potential deposition, and a copper hydroxide nanowire array grows on the copper-contained metal substrate in an in-situ manner. The composite hydroxide is deposited on a copper hydroxide nanorod in electrolyte containing mixed metal salt solution in a manner of electro-deposition through employing the method of constant potential deposition. Meanwhile, electrochemical corrosion enables the copper hydroxide nanorod to be dissolved in a process of electro-deposition, thereby obtaining the hollow tubular structure of the composite hydroxide/copper hydroxide/copper-contained metal substrate. The electrode material is good in super-capacitance performance, and can be used for a super-capacitor.

The invention belongs to the field of preparation of inorganic nonmetallic materials and in particular relates to a method for preparing copper hydroxide phosphate micro-crystals with different shapes. The method comprises the following steps of: uniformly dissolving a soluble bivalent copper salt and soluble phosphate in an alcohol and water mixed solution in certain ratio; fully stirring to perform a reaction; performing a hydrothermal reaction on the alcohol and water mixed solution continuously; filtering; cleaning; and drying to obtain an objective product. According to the method for preparing the copper hydroxide phosphate micro-crystals with different shapes, the process is simple and easy to operate, the product purity is high, the preparation cost of the product is low, the obtained product comprises micron-sized micro-crystals with different shapes and can be used as a visible-light response photocatalyst. The prepared copper hydroxide phosphate micro-crystals with different shapes can be used as the visible-light response photocatalyst and has wide application prospect in the field of degradation of dye wastewater and indoor harmful gas, photo-catalytic disinfection and the like.

A process for preparing the array of copper oxide nanotubes includes such steps as reaction between sodium hydroxide, ammonium persulfate and copper foil in water at 0-30 deg.C to generate the array of copper hydroxide nanotube, and heating in inertial gas or vacuum.

The invention discloses a preparation method of a metal net membrane with self-cleaning and underwater super-oleophobic characteristics. The metal net membrane can achieve efficient oil-water separation and self cleaning. A traditional oil-water separation membrane has the defects that a preparation technology is complex, regeneration is difficult, and repeated using can not be achieved. With a copper net being a substrate, an anodic oxidation method is adopted for generating a copper hydroxide nanowire array, multiple layers of titanium dioxide are deposited on the nanowire array through layer-by-layer self-assembly, and the copper net membrane covered by a copper oxide/titanium dioxide composite membrane layer is generated through roasting. The net membrane is high in mechanical performance and resistant to high heat, has the super-hydrophilic and underwater super-oleophobic characteristics, can efficiently separate an oil-water mixture and meanwhile can perform self cleaning under photocatalysis active illumination of the titanium dioxide layer to achieve regeneration and repeated using. Compared with the preparation technology of the existing oil-water separation membrane, the method facilitates scale expansion, preparation is easy, raw materials are environmentally friendly, the cost is low, cyclic reuse can be achieved, and the net membrane is a novel oil-water separation net membrane which is more environmentally friendly and affordable.

The invention relates to an environmentally-friendly treatment method and an environmentally-friendly treatment device for slurry produced in an organosilicon monomer synthesis process. The method comprises the following steps of: cooling organosilicon slurry and then introducing into a closed hydrolysis tank filled with alkaline solution; reacting high boiling residue with alkaline water in the slurry through stirring to generate neutral or alkaline granular hydrolyzate; collecting to the bottom of the hydrolysis tank and recovering; and flowing copper hydroxide flocculent precipitate produced by the reaction from an upper overflow port of the closed hydrolysis tank along with aqueous solution. The invention also provides the closed hydrolysis tank. By adopting the environmentally-friendly treatment method for the organosilicon slurry, the defects of incomplete hydrolysis of organosilicon high boiling residue and high probability of forming acid mist in the prior art are overcome; and the hydrolyzate is recovered under the condition of guaranteeing full hydrolysis of the slurry. Copper in the slurry is converted into the copper hydroxide precipitate for recycling. The problems ofenvironmental friendliness and safety are solved; and the slurry treatment cost is saved.

An alkaline cell having an anode comprising zinc, an aqueous alkaline electrolyte, a cathode mixture comprising cathode active material comprising copper oxide or copper hydroxide. Graphitic carbon, preferably expanded graphite or graphitic carbon nanofibers are added to the cathode mixture thereby resulting in a sharp drop in cathode resistivity. The cathode active material preferably comprises between about 80 and 92 percent by weight of the cathode. The sharp drop in cathode resistivity resulting from the addition of expanded graphite or graphitic carbon nanofibers makes the cell suitable for use as a primary alkaline cell having good capacity. The graphitic carbon, preferably graphitic nanofibers comprise preferably between about 4 and 10 percent by weight of the cathode. The carbon nanofibers have an average diameter desirably less than 500 nanometers, preferably between about 50 and 300 nanometers.

The invention discloses a cuprous oxide nanocrystalline with adjustable morphology and dimension as well as a preparation method and an application thereof. The preparation method comprises the following steps: copper hydroxide which is used as a precursor is synthesized; the pH value of the system is regulated; the system whose pH value is regulated is reduced in order to obtain cuprous oxide nanocrystalline. A surfactant is not needed to add, the cuprous oxide nanocrystalline with specific morphology and dimension can be obtained by adjusting the pH value of the reaction system, and the nanocrystalline can be used for photocatalytic degradation of organic pollutants, and the method is a rapid, simple and green preparation method of cuprous oxide nanocrystalline.

The invention discloses a preparation method of a cubic cuprous oxide/graphene nanocomposite with efficient photocatalysis capability. According to the method, the composite can be prepared with a simple one-pot reduction method. Firstly, graphene oxide is prepared with an improved Hummers method, copper sulfate pentahydrate and graphene oxide are ultrasonically dispersed in water and mechanically stirred in a water bath at the temperature of 50-60 DEG C to be uniformly mixed, a sodium hydroxide solution is dropwise added to the mixture, copper hydroxide precipitates are formed, then, a glucose solution is added, the mixture reacts for 2-3 h, sufficient reduction is performed, centrifugation, washing and drying are performed, and a cubic cuprous oxide/graphene photocatalyst with the efficient photocatalysis capability is obtained. The process is simple, the cost is low, the product has uniform morphology, and the cubic cuprous oxide/graphene nanocomposite has excellent capability of photocatalytic degradation of organic dye under the visible light and has great application potential in environmental governance and solar energy utilization.

The invention provides a copper-based Cu-Cu2O-CuO catalyst for an organic silicon monomer synthesis reaction as well as a preparation method and an application of the copper-based Cu-Cu2O-CuO catalyst. The catalyst comprises components in percentage by mass as follows: 0-40% of elementary Cu, 40%-90% of Cu2O and 0-40% of CuO, and the sum of mass percentages of all the components is 100%. The method comprises steps as follows: a copper salt is dissolved to form a copper salt solution; an alkaline solution is dropwise added to the copper salt solution, and copper hydroxide precipitate is obtained and then converted into CuO precipitate; then a certain quantity of reducing agent is dropwise added to a CuO suspension for a controllable reduction reaction; obtained reaction products are filtered, washed and subjected to vacuum drying, and then the multicomponent copper-based catalyst is obtained. The experimental process route is simple, the controllability is high, and the prepared multicomponent copper-based catalyst is smaller in particle size and evener in particle size distribution, contains controllable components and shows the higher M2 selectivity and the higher silicon powder raw material conversion ratio.

The invention belongs to the technical field of novel function nanometer material preparation, and discloses a preparation method for a copper nanowire. Reducing agent is added to copper source on the premise that morphology control agent and chemical potential control agent are exist in water solution, and the copper nanowire are obtained after separation and under the condition that reaction is carried out for at least one hour in temperature of 25 DEG C to 100 DEG C, wherein the copper source is one or combination of copper hydroxide and copper oxide, the morphology control agent is one kind or combination of more than two kinds of polyethylene polyamine, the chemical potential control agent is one or combination of sodium hydroxide and potassium hydroxide, and the reducing agent is one or combination of hydrazine hydrate and hydroxylamine. The preparation method for the copper nanowire has the advantages of being simple in technology and device, cheap and easy-getting in raw materials, low in cost, high in productivity, suitable for large-scale industrial production, and the like. Prepared copper nanometers are uniform in diameter, diameters and lengths of the copper nanometers can be controlled through changing concentration of the morphology control agent and concentration and reaction temperature of the copper resource.

The invention discloses a preparation method for a copper/cuprous oxide/cyclized polyacrylonitrile visible-light-driven photocatalyst, and belongs to the technical field of environmental cleaning photocatalyst new materials. The preparation method includes the steps of firstly, preparing a nanometer copper hydroxide/photocatalyst compound by synchronously conducting solvent conversion and in-situ ion exchange reaction with photocatalyst, cupric nitrate and sodium hydroxide as raw materials; secondly, reducing copper hydroxide into cuprous oxide in situ through ascorbic acid; thirdly, conducting thermal treatment under the nitrogen atmosphere, reducing a small amount of cuprous oxide into elementary substance copper while cyclization and dehydrogenation are conducted on polyacrylonitrile to form a conjugated structure, and obtaining the copper/cuprous oxide/cyclized polyacrylonitrile visible-light-driven photocatalyst. The raw materials are wide in source, cost is low, the preparation method is simple and suitable for large-scale production, cyclized polyacrylonitrile can improve the separation efficiency of photoproduction electron holes and absorption of the visible light areas and can have a protection and optical corrosion reduction effect on copper/cuprous oxide, and the obtained catalyst is remarkable in adsorption and photocatalytic effect.

The invention relates to a method for recycling copper, indium and gallium from a waste copper-indium-gallium target. The method comprises the following steps that copper, indium and gallium are dissolved in acid to be in corresponding ionic states; then neutralization and sedimentation are performed to form corresponding hydroxides; then, a concentrated NaOH solution is used for separation to remove gallium, a simple substance of gallium is electrolyzed and recycled, and a water electrolyte containing NaOH generated in the electrolytic process is used for secondary gallium separation; the copper hydroxide and the indium hydroxide are dissolved in acid again, a kerosene solution of di(2-ethylhexyl phosphoric acid) is used for extracting In3+ into an organic phase, and Cu2+ is still in the water phase; iron power is used for replacing a simple substance of copper from the water phase containing Cu2+; and concentrated hydrochloric acid is used for reversely extracting In3+ into the water phase, and then aluminum powder is used for replacement to obtain a simple substance of indium. According to the method, the copper recycling rate is not smaller than 97.1%, the indium recycling rate is not smaller than 97.3%, and the gallium recycling rate is not smaller than 97.9%, so that operation is easy and convenient, and the cost is low.

The invention discloses a preparation method of a metal organic framework material film, wherein the preparation method comprises the following steps: mixing 1-1.5mM ethanol amine aqueous solution with a same volume of 2-5mM copper nitrate aqueous solution by stirring magnetically, carrying out sealed reaction to obtain a copper hydroxide nanowire solution; then mixing 30-60ml of the copper hydroxide nanowire solution with 1-2ml of gold nanoparticle modified by citric acid root, filtering through a filtering film, and then depositing on the filtering film to obtain a gold-copper hydroxide nanowire layer; finally mixing the gold-copper hydroxide nanowire layer with 10-20ml of 4-10mM trimesic acid/ethanol aqueous solution to react for 1-5 hours, thus obtaining the metal organic framework material film. The invention also discloses application of the metal organic framework material film prepared by the preparation method and application of the metal organic framework material film in gas separation. The metal organic framework material film is formed by stacking cubic crystals; an exposed crystal plane is a {100} family of crystal plane.

The invention discloses a catalyst for preparing a multi-carbon product by electro-reduction of carbon dioxide and carbon monoxide as well as a preparation method and application thereof, and belongsto the field of electro-catalysis. The catalyst is a halogen-modified copper electro-catalyst, and halogen comprises at least one of fluorine, chlorine, bromine and iodine. The preparation method of the catalyst comprises the following steps: loading a copper halide precursor on a gas diffusion layer, and carrying out electric reduction to obtain the halogen-modified copper electro-catalyst, wherein the copper halide precursor comprises at least one of a fluorine copper hydroxide precursor and other copper halide precursors except the fluorine copper hydroxide precursor. The catalyst is applied to a reaction for preparing a multi-carbon product by electrically reducing carbon dioxide and carbon monoxide, is high in reaction activity, high in selectivity and stable in catalytic performance,and maintains very high multi-carbon product selectivity in a very wide current range.

The invention provides an iron-copper oxide/copper base electrode material and a preparation method thereof. The iron-copper oxide/copper base electrode material is expressed as Fe3O4/CuO/copper base.A copper hydroxide nanowire array, i.e. Cu(OH)2/copper base, is grown on the copper base in an in-situ way; then ferric hydroxide is electrodeposited on the Cu(OH)2/copper base in the electrolyte solution containing iron ions by using the method of potentiostatic electro-deposition so as to form the hollow tubular structure Fe(OH)3/Cu(OH)2/copper base; and then the ferric hydroxide is transformedinto ferric oxide and the copper hydroxide is transformed into copper oxide through high temperature roasting, and the hollow tubular structure is maintained so that the hollow tubular structure Fe3O4/CuO/copper base material is obtained. The material has great super capacitance performance and is suitable for being used as the supercapacitor electrode material.

The invention provides a preparation method for durable antibacterial cellulose fibres. The preparation method comprises the following steps: S1, removing impurities from cellulose fibres in a physical mechanical mode to obtain impurity-removed fibres; S2, performing pre-treatment on the impurity-removed fibres, and dewatering to obtain dewatered fibres, wherein the pre-treatment comprises a cleaning process and/or a refining and bleaching process; S3, performing antibacterial finishing on the dewatered fibres with an antibacterial working liquid to obtain durable antibacterial cellulose fibres, wherein the antibacterial working liquid comprises an antibacterial agent, an alkaline auxiliary agent and a penetrating agent; the antibacterial agent is one or more of magnesium carbonate, coppernitrate, copper chloride, copper hydroxide, copper carbonate, basic cupric carbonate, zinc chloride, zinc sulphate, zinc hydroxide and zinc carbonate; and the alkaline auxiliary agent is one or moreof sodium hydroxide, potassium hydroxide, sodium bicarbonate, ammonium carbonate, ammonia water, sodium phosphate and sodium carbonate. The prepared cellulose fibres have a durable antibacterial effect; and the whiteness value of the fibres is high.

The invention provides a preparation method of zinc oxide normal-temperature desulfurizing agent. The method comprises the following steps: firstly forming respective unstable precipitate of partial zinc salt and copper salt; and then completely translating residual zinc salt and copper salt not participating the precipitation in a bipyramid rotary vacuum reaction kettle and above unstable precipitates into stable zinc hydroxide and copper hydroxide, roasting to obtain compound powder of zinc oxide and copper oxide, and then preparing the zinc oxide normal temperature desulfurizing agent. The preparation method of the zinc oxide normal temperature desulfurizing agent provided by the invention has a simple process step, and less requirements on condition control and equipment operation, and the sulfur capacity of the prepared zinc oxide normal temperature desulfurizing agent at normal temperature reaches up to 20.3% and more; and therefore, the preparation method provided by the invention is suitable for large-scale production, and has high actual application value.

The present invention discloses algae killing and inhibiting method for water body. Electrolysis equipment is set on vehicle, boat, floated apparatus, cooling tower system or other apparatus near thewater body, and the electrodes are contacted with water body. The anode is made of copper material, and the cathode material is copper, iron, aluminium, graphite or other conductive material. The copper density in the water body is 0.4-4 mg/L for inhibiting algae and 3-8 mg/L for killing algae. Produced copper hydroxide is exhausted to water body continuously or intermittently to kill or inhibit algae. The said method can be used for killing and inhibit algae and bacteria without producing environmental pollution.

The invention discloses a preparation method and application of a metal organic framework thin film on the surface of a macroporous high polymer hollow fiber pipe. The method comprises the following steps of (1) adding an aqueous solution of ethanolamine into an aqueous solution of copper nitrate, zinc nitrate or cadmium nitrate with the same volume while magnetic stirring, reducing stirring speed, obtaining a corresponding solution of copper hydroxide, zinc hydroxide or cadmium hydroxide nanowires, impregnating a macroporous high polymer hollow fiber film of which one end is sealed and the other end is connected with a suction filtration pump into the solution containing the nanowires, and performing suction filtration for 30 minutes to form a nanowire layer on the surface of the macroporous high polymer hollow fiber film; (2) impregnating the macroporous high polymer hollow fiber film with the nanowire layer on the surface into an organic ligand solution, and performing reaction for 30 minutes at normal temperature. According to the method and the application, a dense organic framework thin film can be directly prepared on the surface of the macroporous high polymer hollow fiber pipe, and can be used for gas separation, the method comprises simple operating steps, and is environment-friendly, and reaction residuals can be easily recovered.