The invention relates to the field of carbon material preparation, in particular to a
nitrogen-doped graded double-shell hollow carbon
microsphere and a preparation method of a
noble metal-loaded catalyst of the
nitrogen-doped graded double-shell hollow carbon
microsphere. The preparation method comprises the following steps: adding
resorcinol and amines into a water /
alcohol /
ammonia water
system, then adding
formaldehyde to carry out
condensation reaction, and when the reaction time is 30-99% of the time required for turbid appearance, adding tetraethyl
silicate and continuously reacting to form a
polymer resin /
silicon dioxide first composite shell layer; and raising the temperature, continuing the reaction to form a second
polymer resin shell layer, and sequentially centrifuging, washing,
drying, carbonizing and removing
silicon dioxide to obtain the
nitrogen-doped graded double-shell hollow carbon microspheres. According to the nitrogen-doped graded double-shell hollow carbon
microsphere, the inner shell mainly comprises mesopores, the outer shell mainly comprises micropores, the main components of the inner shell are carbon and a very small amount of nitrogen, the main component of the outer shell is nitrogen-
doped carbon, the adsorption of ions on the surface of the carbon microsphere can be promoted, and the electrochemical performance of the carbon microsphere serving as a catalytic material and an
electrode material is effectively improved.