21 results about "BASIC CUPRIC CARBONATE" patented technology

The invention provides a method for preparing active copper oxide by recycling ammonia and carbon. The method comprises the following steps: step 1, preparing a copper dissolving reagent from ammonia water and carbon dioxide; 2, the copper raw material and a copper dissolving reagent are mixed, oxygen or air is introduced, heating and pressurizing are carried out for an ammonia leaching complexing reaction, and a copper ammonia complex is obtained; step 3, after the copper ammonia complex is filtered, rectifying to remove ammonia and carbon, producing ammonia gas and carbon dioxide at the tower top, and producing basic cupric carbonate slurry at the tower kettle; 4, centrifuging and drying the basic cupric carbonate slurry to obtain a basic cupric carbonate solid; and 5, calcining the basic cupric carbonate solid at high temperature to produce active copper oxide. According to the active copper oxide preparation method capable of recycling ammonia and carbon, the active copper oxide with high purity and uniform particle size can be directly prepared.

The invention provides a novel mineral separation activating agent for sulphide ores and a preparation method of the novel mineral separation activating agent. The cleaning agent comprises 1-2 parts of basic cupric carbonate, 2-4 parts of ammonium chloride, 2-4 parts of nanometer jade powder, 2-3 parts of alginic acid, 1-2 parts of allyl glycidyl ether, 2-3 parts of peregal O, 2-3 parts of sodium di-sec-octyl maleate sulfonate, 2-3 parts of vinyl acetate, 4-7 parts of hydrogen peroxide, 4-6 parts of disodium hydrogen phosphate and 40-50 parts of water. The preparation method comprises the following steps: firstly mixing basic cupric carbonate and ammonium chloride to obtain a first mixture, then mixing the rest components, heating and stirring to obtain a second mixture, and finally uniformly mixing the first mixture and the second mixture. The activating agent overcomes the defects of a traditional activating agent, has efficient activating performance, can improve the beneficiation efficiency of low-grade, complex and refractory sulfide ore, is environmentally friendly, good in stability and high in adaptability, and provides technical support for efficient development of sulfide ore resources.

The invention discloses an analysis method for determining the content of water-soluble chlorine in basic cupric carbonate. Compared with the prior art, the method has the advantages that by optimizing sample treatment and determination conditions, the determination accuracy and precision are remarkably improved, and meanwhile, the analysis time is shortened. Specifically, a set of sample pretreatment process is customized according to different contents of water-soluble chlorine in a sample, and rapid and accurate chlorine content determination is realized through an improved potentiometric titration technology. According to the method, the detection efficiency is improved, and the reliability of the result is ensured by reducing personal errors. In addition, the analysis speed of the method is 1.5 times higher than that of a traditional method, the accuracy is improved by 30%, and the precision error range is reduced to 5%.

The invention belongs to the technical field of composite coatings, and particularly relates to a copper-tin electroplating solution and a preparation method and application thereof.The preparation method of the electroplating solution comprises the steps that citric acid is dispersed in water, potassium hydroxide is added, and a reaction solution 1 is obtained; basic cupric carbonate is added into the reaction solution until the solution becomes clear and does not generate bubbles, the solution is cooled, monopotassium phosphate is added, and a reaction solution 2 is obtained; dissolving potassium stannate in a dilute alkali hot solution, and after the potassium stannate is completely dissolved, adding hydrogen peroxide to obtain a reaction solution 3; and adding the cooled reaction liquid 3 into the reaction liquid 2 to obtain the electroplating liquid. The preparation method of the electroplating solution is simple and almost free of pollution, the electroplating solution is used for electroplating a metal test piece, and an obtained plating layer has high corrosion resistance.

The invention relates to the field of spectral absorption analysis, and provides an analysis method for determining mercury in basic cupric carbonate through hydrochloric acid dissolution, which comprises the following steps: dissolving basic cupric carbonate at low temperature by using hydrochloric acid without reducibility, steaming to 2-3mL, oxidizing mercury in a sample into high-valence mercury by using potassium permanganate, and determining the mercury content in the sample by using hydrochloric acid without reducibility. And completely reducing mercury in the sample into mercury vapor by using stannous chloride, and measuring the mercury content on a cold atomic absorption spectrometer. At present, a standard analysis method for mercury elements in materials such as basic cupric carbonate is lacked in China. Mercury is a harmful substance in the nature, and it is particularly important to analyze whether mercury can be accurately analyzed. The method is improved on the basis of a conventional analysis processing method, adopts single hydrochloric acid to dissolve the sample, and has the characteristics of high measurement precision, wide range, high accuracy, strong practicability and the like.

The invention discloses a preparation method and application of high-purity copper sulfate, and the preparation method comprises the following steps: reacting ammonia water with a copper chloride solution to obtain basic copper chloride; adding sulfuric acid into the basic copper chloride for dissolving, and removing impurities to obtain an acidic impurity-removed solution; reacting the acidic impurity removal liquid with the alkaline impurity removal liquid to obtain basic cupric carbonate and / or copper oxide; and adding sulfuric acid into the basic cupric carbonate and / or copper oxide for reaction, and cooling and crystallizing to obtain the high-purity copper sulfate. According to the preparation method of the high-purity copper sulfate, metal, nonmetal and other impurities in the raw materials can be removed, the impurity removal effect on trace impurities is obvious, new impurities are not introduced in the preparation process, the process is simple, industrial production can be achieved, and the obtained high-quality copper sulfate can be applied to the electroplating liquid and has good application prospects. Especially in the fields of electroplating of precision elements sensitive to impurities and semiconductors.

The invention relates to a method for preparing a nano needle-shaped basic cupric carbonate-nickel supercapacitor electrode material at an ultra-fast speed. A water-soluble copper compound and urea are used as basic raw materials, and a water-soluble nickel compound is used as an accelerant; the preparation method comprises the following steps: firstly, preparing a solution containing 0.01 to 0.50 mol / L of Cu < 2 + >, 0.01 to 0.50 mol / L of Ni < 2 + > and 0.2 to 0.5 mol / L of urea at the same time; then transferring the solution into a reaction kettle; and keeping the temperature of the reaction kettle at 105-135 DEG C for 30-60 minutes to obtain the single-crystal needle-shaped basic copper carbonate-nickel with the specific capacitance of more than 2300F / g. The method has the advantages that the hydrothermal reaction speed is high, the period is short and is not longer than 1 h, and the prepared nanometer needle-shaped basic copper carbonate-nickel has ultrahigh specific capacitance.

The invention discloses a preparation method of a broad-spectrum protective zirconium-based adsorbing material, and belongs to the technical field of adsorbents, the preparation method comprises the following steps: adding a dispersing agent into a zirconium oxychloride aqueous solution, and stirring at normal temperature to obtain a suspended emulsion to obtain zirconium oxychloride suspension slurry; adding a composite surfactant into the zirconium oxychloride suspension slurry, and stirring at a high speed to obtain a suspension; dropwise adding a sodium hydroxide solution in a stirring state, hydrolyzing to generate a precipitate, standing the precipitate, filtering, washing, drying, and crushing to obtain a surface modified zirconium hydroxide particle sample; preparing an impregnation liquid: adding sodium bicarbonate, basic cupric carbonate, potassium carbonate, silver nitrate and ammonium molybdate into pure water, stirring and dissolving to obtain the impregnation liquid; and adding the obtained impregnation liquid into a modified zirconium hydroxide particle sample. After a substrate material is loaded with metal active components, ammonia gas and a copper reaction center are complexed, a coordination compound is formed through weak chemical adsorption, and the purpose of ammonia gas protection is achieved.

The present invention relates to a method for preparing a polyether amine catalyst, and polyether amine. A polyether amine catalyst is a supported metal catalyst; γ-Al2O3 is used as a carrier; basic cupric carbonate, basic nickel carbonate and basic cobalt carbonate are used as precursors of supported metals; and the polyether amine catalyst is prepared by performing twice adsorption roasting and once reduction by means of an equivalent-volumetic impregnation method. Easier decomposition is achieved by using basic carbonate, and only water and carbon dioxide are generated, such that processes and costs for treating waste gases can be saved. By using the polyether amine catalyst to prepare polyether amine, a conversion rate and primary amine selectivity can be improved, and the color of products can be reduced. Therefore, the obtained polyether amine can have higher activity and wider application.

The invention relates to the technical field of production of basic cupric carbonate, in particular to an environment-friendly preparation process of high-purity heavy basic cupric carbonate. Comprising the following steps: S1, fully and uniformly mixing the acidic copper-containing etching waste liquid and an ethanol water solution in stirring equipment to obtain diluted waste liquid; s2, adding a composite precipitator and an auxiliary agent into the obtained diluted waste liquid, and carrying out precipitation treatment at 22-26 DEG C until the pH value is 6.5-7.5; wherein the addition amount of the composite precipitant is 40-60% of the mass of the diluted waste liquid, and the addition amount of the auxiliary agent is 8-12% of the mass of the diluted waste liquid; s3, washing the obtained precipitation product with deionized water for 2-4 times, and drying to obtain a high-purity heavy basic cupric carbonate finished product; the high-purity heavy basic cupric carbonate prepared by the method disclosed by the invention not only has better purity, but also can realize recycling of the acidic copper-containing etching waste liquid.

The invention relates to the technical field of basic cupric carbonate production, in particular to a filtering and deslagging device for basic cupric carbonate production, which comprises a bottom frame, a filtering frame, filtering cloth, a flushing unit, a power unit, a push plate and the like, a filtering frame is fixedly connected to the bottom frame, and a plurality of filtering holes are formed in the filtering frame; filter cloth is connected to the filter frame; a flushing unit is connected to the underframe and is used for flushing basic cupric carbonate; the underframe is connected with a power unit; the power unit is connected with two push plates and is used for driving the push plates to move left and right; and the push plate is in sliding connection with the filter frame. According to the method, the basic copper carbonate is flatly laid for multiple times to be sequentially flushed, and compared with flushing of all basic copper carbonate at a time, it can be ensured that water flow can fully permeate into basic copper carbonate powder, waste liquid is effectively loosened and taken away, and cleaning is more thorough.

The invention provides a method for removing a surface coating of a waste tire cord steel wire, and belongs to the technical field of high-value recycling of the waste tire cord steel wire. According to the method, separation of copper and zinc in coating components is achieved through a sodium benzoate / auxiliary leaching agent system in the first step, zinc precipitation treatment is conducted on first filtrate to obtain zinc hydroxide, a zinc oxide product can be further prepared, high commercial value is achieved, and cyclic utilization of the zinc element in tires is achieved; and 2, carrying out copper deposition treatment on the third filtrate to obtain a byproduct basic cupric carbonate. Through the two successive steps, the waste tire cord steel wire and the surface coating component are effectively separated, echelon separation of zinc and copper valuable elements in the coating component and high-value utilization of the cord steel wire are achieved, and the method has good application prospects and social and ecological benefits.

The invention belongs to the technical field of tungsten-copper alloys, and particularly relates to a high-thermal-conductivity tungsten-copper alloy and a preparation method thereof.The preparation method comprises the following steps that S1, ammonium paratungstate, copper oxide, copper tungstate, basic cupric carbonate, a silver-containing compound, an organic coordination agent, rare earth oxide and copper powder are obtained to serve as raw materials; s2, the raw materials except the copper powder are subjected to ball milling to obtain composite sol, the composite sol is dried to obtain precursor powder, and the precursor powder is subjected to heat treatment to obtain composite powder; and S3, the composite powder and the copper powder are laid according to the structure of bottom layer copper powder-composite powder-top layer copper powder, a composite pressed blank is obtained through pressing, infiltration sintering is conducted on the composite pressed blank, and the tungsten-copper alloy is obtained. By forming the three-stage core-shell structure of tungsten core-copper silver solid solution shell-rare earth transition layer, the comprehensive performance is superior to that of an existing silver nitrate / silver powder system, no harmful gas is discharged, and the green manufacturing requirement is met.

The invention provides a preparation method of a copper oxide material rich in oxygen vacancies, the copper oxide material and application, and belongs to the technical field of material preparation. According to the preparation method of the copper oxide material rich in oxygen vacancies provided by the invention, a solution combustion method based on basic cupric carbonate and an external oxidant is adopted, and the accurately controlled protective atmosphere and calcination conditions are combined, so that the copper oxide material rich in oxygen vacancies with a specific electronic structure can be simply and efficiently constructed; the oxygen vacancy content and the specific surface area of the copper oxide material are remarkably improved, so that a large number of oxygen vacancies exist in the material and can be in full contact with oxygen molecules. Therefore, the copper oxide material prepared by the method has excellent oxygen molecule activation performance, oxygen molecules in the environment can be continuously activated through oxygen vacancies even under the dark condition, sufficient reactive oxygen species (ROS) can be generated, and efficient antibiosis in dual modes of illumination and darkness can be realized.

The invention relates to the technical field of basic cupric carbonate drying, and discloses low-temperature drying equipment for preparing large-particle high-specific-gravity basic cupric carbonate through a wet method.The low-temperature drying equipment comprises a drying device, the top of the drying device is communicated with a feeding frame, a discharging hole is formed in the lower surface of the drying device, and the inner wall of the drying device is fixedly connected with a slope frame; a tiling part is arranged below the inclined plane frame; and the tiling part comprises two bottom plates, the ends, away from each other, of the two bottom plates are fixedly connected with a power device and a rotating rod correspondingly, and the end, away from the bottom plate, of the rotating rod is rotationally connected with the inner wall of the drying device. When a screw rod rotates, a moving frame is pushed to slide on the surface of a limiting plate, when the moving frame moves, a center rod is pushed to move through a bent plate, when the center rod moves, an inclined plate is pushed to move at the bottom of the inner wall of a drying frame, and when the inclined plate moves, basic cupric carbonate is pushed to move in the drying frame; and non-uniform drying caused by accumulation of basic cupric carbonate in the drying rack is avoided.

The invention provides a method for recovering high-activity copper oxide from alkaline etching waste liquid based on an ammonia distillation method, and belongs to the field of resourceful treatment of copper-containing waste liquid. The method comprises the following steps: filtering the alkaline etching waste liquid to remove suspended matters; carrying out adsorption coupling on dimethyl glyoxime and diatomite to remove impurities; carrying out gradient ammonia distillation treatment combining normal-pressure ammonia distillation and negative-pressure ammonia distillation on the impurity-removed etching waste liquid to obtain a basic cupric carbonate crude product; dissolving the basic cupric carbonate crude product in a urea solution to obtain a copper tetraammine carbonate solution; carrying out secondary negative pressure ammonia distillation treatment to obtain a basic cupric carbonate fine product with a spherical honeycomb structure; and carrying out graded calcination and water vapor activation co-treatment to obtain high-activity copper oxide. According to the method, the dimethyl glyoxime-diatomite coupling impurity removal, gradient ammonia distillation, urea dissolution, secondary ammonia distillation, graded calcination and water vapor activation treatment processes are combined, the quality and performance of a copper oxide product are improved, the high-activity copper oxide powder for PCB electroplating is obtained, and efficient cyclic utilization of copper resources is achieved.

The invention relates to the technical field of wastewater treatment, in particular to a wastewater treatment device for basic cupric carbonate manufacturing and a treatment method.The wastewater treatment device comprises a sedimentation tank and an annular flow baffle coaxially and fixedly installed at the top of the sedimentation tank, and a top assembly frame is fixedly installed at the top of the annular flow baffle; an output shaft of a first servo motor drives an outer stirring blade and an inner stirring blade to rotate, the inner stirring blade scrapes precipitates on an impurity precipitation plate, the precipitates are scraped in an impurity gathering groove, a second servo motor drives a driving wheel to rotate through a connecting belt, and the driving wheel drives an impurity push plate to scrape impurities in the impurity gathering groove. Through the operations of gathering and discharging, impurities can be effectively removed from the tank, the possibility that the impurities enter a water body again is reduced, water flowing out of the sedimentation tank is clearer, the content of pollutants such as suspended solids and heavy metals in the water is reduced, and effluent can better meet the water inlet requirement of a subsequent treatment unit or directly reach the discharge standard.

The utility model discloses a ruin area planting structure with a barrier function. The ruin area planting structure comprises a ruin main body, a gravel layer, a rammed earth layer, a waterproof layer, a barrier layer, a basic cupric carbonate layer and a soil planting layer, the rubble layer is arranged on the ruins body, the rammed earth layer is arranged on the rubble layer, the waterproof layer is arranged on the rammed earth layer, the blocking layer is arranged on the waterproof layer, the basic copper carbonate layer is arranged on the blocking layer, and the soil planting layer is arranged on the basic copper carbonate layer. Wherein the blocking layer comprises a root blocking layer and a blocking net arranged in the root blocking layer, and a plurality of positioning raised lines are arranged on the surface of the root blocking layer. The utility model can solve the problem that the ruin body is damaged by the root system of the plant in the ruin area.

The invention discloses a preparation method of amorphous basic cupric carbonate. The method comprises the following steps: (1) respectively preparing a soluble copper salt solution and a precipitant solution; (2) adding bottom water and a stabilizer into a reactor, adding the soluble copper salt solution and the precipitant solution obtained in the step (1) into the reactor in a parallel flow manner, and reacting while stirring to obtain slurry; the stabilizer is a solution containing isopropylamine chain dodecyl benzene sulfonate; (3) carrying out suction filtration and first washing on the slurry obtained in the step (2); (4) adding the material obtained in the step (3) into a solvent, and freezing; and (5) sequentially carrying out second washing, third washing and fourth washing on the material obtained in the step (4), and carrying out freeze drying on the washed material to obtain the amorphous basic cupric carbonate. According to the method, crystal structure transformation of amorphous basic cupric carbonate in the preparation process can be avoided, and the method is simple and easy to operate and does not need expensive instruments.

The invention discloses a preparation method and application of a copper tannate bactericide. The method comprises the following steps: dissolving refined basic cupric carbonate in a hot concentrated sodium bicarbonate solution, slowly dropwise adding a tannic acid solution into the basic cupric carbonate solution to carry out liquid-liquid reaction, and carrying out acid-base neutralization after the tannic acid solution is added because the sodium bicarbonate solution of the basic cupric carbonate is alkaline; a microenvironment with the pH value of 4-5 required by a coordination reaction is formed, and meanwhile, due to excessive copper ions, sufficient coordination combination of the copper ions and tannic acid is promoted, so that the product yield is increased. The whole preparation process is carried out under mild conditions, does not involve highly toxic and high-pollution substances, and is environment-friendly and high in safety. The prepared copper tannate can be applied to prevention and treatment of pathogenic microorganisms in agriculture, has multiple effects of resisting bacteria and viruses, promoting plant growth, enhancing crop stress resistance and the like, can remarkably improve the yield and quality of crops, does not generate drug resistance, and can solve the harm of the pathogenic microorganisms in a short time.

The invention discloses a process for efficiently recovering camphor residues, which belongs to the technical field of chemical preparation, copper oxide, copper simple substance and basic cupric carbonate in the camphor residues can be complexed and then settled and removed by using a solvent, and camphor and carbonized polymer oil are fully dissolved, so that the substances are classified and recovered. The method has the characteristics of less pollution, high repeated utilization rate and good economic benefit; the copper treatment agent is formed by mixing a co-dissolving solvent and a copper treatment agent, the co-dissolving solvent comprises xylene and a combined solvent, the combined solvent is formed by combining one or more of ethyl acetate, ethyl alcohol, acetic acid and alpha-terpilenol, and the copper treatment agent comprises oxalic acid and a second copper treatment agent. And the second copper treating agent is formed by combining one or more of chromic acid, carbonic acid and sodium oxalate. The invention also discloses a process for realizing efficient recovery of camphor residues by using the solvent.