17 results about "Bismuth carbonate" patented technology

The invention discloses a modified bismuth-based catalyst as well as a preparation method and application thereof, and belongs to the field of electrochemical reduction CO2 catalysis. By hybridizing boron-doped oxidized carbon black and bismuth oxide, in-situ synthesis of the bismuth oxide and advanced construction of a BiOC structure are realized. Particularly, in the electroreduction process of carbon dioxide, the bismuth oxide can be partially, spontaneously and irreversibly reconstructed into basic bismuth carbonate (Bi2O2CO3), and basic bismuth carbonate composite bismuth oxide (Bi2O2CO3 / Bi2O3) is formed. Due to the structure, the application performance of the catalyst in carbon dioxide electroreduction is remarkably improved, and the catalyst has high formic acid selectivity, high catalytic efficiency, excellent stability and large working current capacity.

Methods for preparing catalysts for oxidative dehydrogenation (ODH) of alkanes such as ethane are provided. An exemplary method includes forming a slurry including metal oxides; one or more of a bismuth compound, an antimony compound, and a tellurium compound; a reducing agent; and water; and heating the slurry to form the catalyst. The metal oxides include an oxide of molybdenum and an oxide of vanadium. The bismuth compound includes bismuth oxide, bismuth hydroxide, or a bismuth carbonate. The antimony compound includes an oxide of antimony, an antimony acetate, or an antimony ethoxide. The tellurium compound includes tellurium dioxide. The reducing agent includes molybdenum dioxide and may further include vanadium dioxide. The methods use all inorganic reagents, with no build up COx pressure observed during the hydrothermal synthesis.

The invention relates to a preparation method and application of a monolayer assembled bismuth subcarbonate nanosheet catalyst precursor. The preparation method comprises the following steps: 1) dissolving bismuth salt in water, adding triethanolamine, and stirring and mixing to form a uniform white solution; 2) adding an alkaline substance into the solution obtained in the step 1), and adjusting the solution to be alkaline; 3) heating and reacting the solution obtained in the step 2) to obtain a suspension containing white bismuth subcarbonate nanosheets; 4) carrying out solid-liquid separation on the suspension obtained in the step 3), collecting a white solid product, washing and drying to obtain a monolayer assembled bismuth subcarbonate nanosheet precursor; the morphology is formed by orderly assembling small-size nanosheets in a single layer in the two-dimensional plane direction, stacking and gathering of the nanosheets can be effectively inhibited, and exposure and structural stability of effective active sites are remarkably improved. When applied to the field of electrochemical carbon dioxide reduction, the catalyst can continuously run for 300 hours at the current density of 100 mA. Cm <-2 >, and the average formic acid Faraday efficiency reaches 82.6%.

The application discloses a modified bismuth-based catalyst, a preparation method and application thereof, and belongs to the field of electrochemical reduction of CO2 catalysis. The application realizes in-situ synthesis of bismuth oxide and early construction of a Bi-O-C structure by hybridizing boron-doped carbon black and bismuth oxide. In particular, during the process of electrochemical reduction of carbon dioxide, the bismuth oxide is partially and spontaneously irreversibly restructured into bismuth subcarbonate (Bi2O2CO3), forming bismuth subcarbonate composite bismuth oxide (Bi2O2CO3 / Bi2O3). The existence of the structure significantly improves the application performance of the catalyst in the electrochemical reduction of carbon dioxide, and the catalyst has high formic acid selectivity, high catalytic efficiency, excellent stability and large working current capacity.

The invention discloses application of a bismuth-based compound in photocatalytic degradation of sulfur hexafluoride and a method for photocatalytic degradation of sulfur hexafluoride. The bismuth-based compound is one of bismuthyl carbonate, bismuth tungstate, a bismuthyl carbonate mixture and a bismuth-based heterojunction. The bismuthyl carbonate mixture is a mixture of one or more of Na2S, Na2SO3, Na2S2O3 and NaI and bismuthyl carbonate; the bismuth-based heterojunction is formed by mixing and stirring a solution containing one or more of sodium sulfide, NaI, Na2SO3 and Na2S2O3 and bismuth subcarbonate, and then drying. The compound disclosed by the invention takes a metal bismuth atom as an active site center, so that adsorption of sulfur hexafluoride can be promoted; and the substance formed in situ and the bulk material form a heterojunction to improve the photodegradation activity. Compared with a traditional technology needing vacuum, the method better conforms to the actual situation and has huge practical potential, materials used in the method do not need to be sintered, the process is simple, and the machining cost is low.

The invention relates to the technical field of packaging materials, and discloses a packaging carton coating material capable of absorbing sulfides, the coating material is composed of an active absorption component, a functional adhesive matrix, a functional auxiliary agent and water; wherein the active absorption component is a compound of nanoscale zinc oxide and bismuth subcarbonate; the functional adhesive matrix is a combination of polyvinyl alcohol and sodium carboxymethyl cellulose with specific parameters, and the preparation method comprises the following steps: accurately controlling the pH value to be alkalescent when the active slurry is prepared, and then mixing the active slurry with the functional glue solution. Through the synergistic effect of the active components and a reaction microenvironment constructed by the functional adhesive, the sulfide absorption efficiency is remarkably improved; a porous network structure is formed by optimizing the component proportion, so that the high utilization rate of active sites is ensured; the preparation process inhibits agglomeration of nanoparticles, and ensures uniformity and stability of the performance of the final product.

The invention discloses an ultraviolet-resistant nylon composite material which comprises nylon resin and a modified bismuth compound, and the modified bismuth compound enables the composite material to have an X-ray developing function and also has improved ultraviolet aging resistance, mechanical properties and precipitation resistance. Wherein the bismuth compound is selected from bismuth carbonate, bismuth oxychloride and bismuth trioxide. The ultraviolet-resistant nylon composite material disclosed by the invention can be used for preparing an interventional catheter, and compared with the prior art, the preparation method disclosed by the invention is simple, and the problem of ultraviolet radiation discoloration of the interventional catheter is solved.

The application relates to the technical field of electrode materials, in particular to a bismuth-based alloy composite electrode material based on biomass charcoal and a preparation method thereof, which comprises the following steps: after pretreatment of waste biomass materials, KOH is used for activation and pore making, and porous biomass charcoal is obtained after acid pickling and drying; the porous biomass charcoal, basic bismuth carbonate, tin oxalate, copper oxalate and magnesium powder are mixed to obtain mixed powder, anhydrous ethanol is added to the mixed powder for grinding to a paste, and a precursor mixture is obtained after vacuum drying; the precursor mixture is subjected to a magnesium thermal reduction reaction in an argon atmosphere, the reaction product is cooled to room temperature, and acid pickling and drying are carried out to obtain the bismuth-based alloy composite electrode material based on biomass charcoal. The application solves the problems of large volume expansion and poor conductive stability of the existing bismuth-based alloy electrode, and realizes resource utilization of waste biomass.

Methods for preparing catalysts for oxidative dehydrogenation (ODH) of alkanes such as ethane are provided An exemplary method includes providing a first mixture including metal oxides; a reducing agent; and one or more of a bismuth compound, an antimony compound, and a tellurium compound; and heating the first mixture to form the catalyst. The first mixture is essentially free of water. The metal oxides include an oxide of molybdenum and an oxide of vanadium. The bismuth compound includes bismuth oxide, bismuth hydroxide, or a bismuth carbonate. The antimony compound includes an oxide of antimony, antimony acetate, or antimony ethoxide. The tellurium compound includes tellurium dioxide.

The invention provides flame-retardant rubber containing a bismuth-based flame retardant and a preparation method of the flame-retardant rubber, and belongs to the technical field of flame-retardant rubber. Natural rubber, nitrile rubber, butadiene styrene rubber and chloroprene rubber are adopted as main base materials, and at least one of bismuth oxide, bismuth oxychloride, bismuth hydroxide and bismuth subcarbonate is introduced as an environment-friendly flame retardant, so that the flame-retardant effect of the product is ensured; meanwhile, the use of complex solvents and the discharge of potential byproducts are reduced, and the method is an important way for realizing ideal green life. Carbon black, stearic acid, zinc oxide, decabromodiphenyl ethane, aluminum diethylphosphinate, diethyl phthalate, paraffin oil, a coupling agent, insoluble sulfur, an accelerant, an anti-aging agent and other substances are also added, and through multiple times of mixing and banburying, the tensile property of the product is guaranteed, meanwhile, the fireproof performance of the product is effectively improved, ignition is delayed, and the flame propagation speed is reduced; and the use safety of the product is improved.

The invention relates to a composite material of bismuthyl carbonate and a carboxyl group-containing organic compound for filtering ultraviolet radiation. The present invention relates to particles and solvates thereof, such as hydrates thereof, comprising at least one bismuth subcarbonate of the empirical formula (BiO) 2-x (CO3), where-0.4 lt; xlt; 0.6, the maximum average size of the particles being less than 400 nm; and one of at least one carboxyl group-containing organic compound and / or a salt thereof, to a process for their preparation, and also to cosmetic compositions and uses using said composite.

A composite of bismuthyl carbonate and a polymer for filtering ultraviolet radiation. The present invention relates to a composite material comprising at least one bismuthyl carbonate particle of formula (I) (BiO) 2-x (CO3) and solvates thereof (e.g. Hydrates thereof), where-0.4 lt; xlt; 0.6, the maximum average size of said particles being less than 400 nm, and at least one polymer; relates to processes for their preparation, and also to cosmetic compositions and uses of said composites.

The present application relates to the technical field of glass microsphere preparation, and particularly relates to high-refractive large-diameter glass microspheres for road marking and a preparation method thereof, the preparation method comprising the following steps: mixing raw materials such as quartz sand and bismuth carbonate with a nano-domain inducing modifier and performing wet ball milling to obtain mixed fine powder; sequentially performing high-temperature melting, temperature control and phase separation treatment and temperature rising and homogenization treatment on the mixed fine powder to obtain a glass melt, and performing drop shrinkage and ball formation through a porous bushing and performing step cooling and solidification to obtain large-diameter glass microsphere primary products; stirring and reacting the large-diameter glass microsphere primary products with a modified nano-hybrid surface treatment agent under heating, and performing vacuum drying and cooling to obtain high-refractive large-diameter glass microspheres. Through the synergistic effect of the nano-domain inducing modifier and the modified nano-hybrid surface treatment agent, the prepared glass microspheres have internal optical uniformity, high mechanical strength, excellent hydrophobicity and interfacial bonding force on the surface, and the long-term effective reflective life and weather resistance of the road marking are significantly improved.

The application relates to a corrosion-resistant coating for enhancing the corrosion resistance of a steel port terminal near the sea and a preparation method, and belongs to the technical field of corrosion-resistant coatings. The preparation method comprises the following steps: mixing bisphenol A type epoxy resin, an active diluent, a dispersing agent, a leveling agent, an anti-settling agent, alkaline bismuth carbonate, bismuth oxide and zinc phosphate to obtain component A; mixing component A with a curing agent, applying the mixture to the surface of a steel base material, and performing pre-curing to obtain a pre-cured coating; performing humidity activation treatment on the pre-cured coating to obtain a humidity-activated coating; and finally curing the humidity-activated coating to obtain the corrosion-resistant coating for enhancing the corrosion resistance of the steel port terminal near the sea. Through the specific humidity activation treatment step and the alkaline bismuth carbonate, bismuth oxide and zinc phosphate filler system, the coating has the ability to actively respond to the invasion of chloride ions, effectively blocks micro-penetration channels, and overcomes the technical difficulties that the coating performance is irreversibly attenuated and the activity of the filler is difficult to effectively stimulate.

This invention provides a flame-retardant rubber containing a bismuth-based flame retardant and its preparation method, belonging to the field of flame-retardant rubber technology. This invention uses natural rubber, nitrile rubber, styrene-butadiene rubber, and chloroprene rubber as the main base materials, while introducing at least one of bismuth oxide, bismuth oxychloride, bismuth hydroxide, and bismuth subcarbonate as an environmentally friendly flame retardant, ensuring the product's flame-retardant effect; it also reduces the use of complex solvents and potential by-product emissions, which is an important way to achieve an ideal green lifestyle. Carbon black, stearic acid, zinc oxide, decabromodiphenyl ethane, aluminum diethylphosphinate, diethyl phthalate, paraffin oil, coupling agents, insoluble sulfur, accelerators, antioxidants, and other substances are also added. Through multiple mixing and intensive kneading processes, the product's tensile properties are guaranteed while effectively improving its fire resistance, delaying ignition, reducing flame propagation speed, and enhancing the safety of product use.

This invention discloses a sulfur-iodine co-modified bismuth subcarbonate catalyst, its preparation method, and its application, belonging to the field of electrocatalytic reduction technology. The sulfur-iodine co-modified bismuth subcarbonate catalyst is a Bi₂O₂CO₃ phase, composed of Bi... 13 S 18 The I2 nanosheet precursor was reconstructed in situ into a sulfur- and iodine-modified bismuth subcarbonate nanosheet structure under near-neutral CO2 electroreduction conditions, while retaining S on its surface and / or between layers. 2‑ and I ‑ Thus retaining Bi 3+ Simultaneous oxidation of the bismuth subcarbonate catalyst enables synergistic regulation of surface anions, constructing an active interface with abundant nanoscale pits and a high specific surface area. This invention employs a simple and mild process, and the resulting sulfur-iodine co-modified bismuth subcarbonate catalyst exhibits excellent performance in the electrocatalytic reduction of carbon dioxide to formate, achieving up to 1000 mA cm⁻¹. ‑2 It maintains high formate Faraday efficiency over a wide current density range and achieves long-term stable operation in membrane electrode systems, demonstrating good prospects for practical applications.

The invention relates to the field of hydrometallurgy, in particular to a method for enhancing bismuth analysis and antimony and bismuth element resource utilization in an antimony-based adsorbent. The method specifically comprises the following steps: fully and uniformly mixing dilute nitric acid serving as a leaching agent with an inactivated antimony-based adsorbent, stirring, and then carrying out solid-liquid separation to obtain leaching residues, namely the regenerated antimony-based adsorbent, which can be directly returned to an adsorption unit for purification and impurity removal. And adding sodium carbonate into the leachate, depositing bismuth ions in the leachate, carrying out solid-liquid separation after reaction to obtain bismuth-containing carbonate precipitate, washing and drying the material, and carrying out oxidizing roasting to obtain the roasted product, namely the high-purity bismuth trioxide. According to the method for selectively separating antimony and bismuth and simply regenerating the adsorbent, after bismuth is selectively removed through the antimony salt adsorbent, the obtained regenerated antimony salt adsorbent can directly return to an adsorption purification unit, and the impurity removal effect is equivalent to that of an initial adsorbent; and the bismuth-containing solution is treated to obtain high-purity bismuth trioxide, so that recycling and high-value utilization of the bismuth element are realized.