The invention discloses a preparation method of a piece of titanium dioxide-graphene composite nano paper. The titanium dioxide-graphene composite nano paper mainly comprises a titanium dioxide nano zone and graphene, or a titanium dioxide nano zone, graphene and additives. The preparation method of the titanium dioxide-graphene composite nano paper mainly comprises the following procedures of synthesizing, compounding, dispersing, suction filtering, drying and the like. Compared with the ordinary nano granules or nano films, the titanium dioxide-graphene composite nano paper is more excellent in performance, simple in manufacturing method and lower in cost. Due to the introduction of the graphene, the nano paper has good conductivity, can effectively solve the problem that electrons are compounded with cavities when being excited, and improves the photocatalysis efficiency. The composite nano paper has important application prospects in high-tech fields of photocatalysis, sensors, electronic devices and the like. The composite nano paper has the advantages of reasonable design, simple process, non-toxicity, harmlessness, low price and the like, is easy to operate and can be directly cut.