The invention relates to the technical field of
bridge engineering materials, in particular to an
epoxy resin self-repairing material with dynamic covalent bonds for a large-span steel
bridge deck and a preparation method of the
epoxy resin self-repairing material. According to modified
bisphenol A
epoxy resin, flexible chain segments and rigid groups are introduced into an epoxy resin molecular chain, so that the
toughness and
heat resistance of the material are improved; the modified
aliphatic amine curing agent and the modified epoxy
resin matrix have good compatibility, the formed
network structure is more compact, the
hardness and the
heat resistance of the material are improved, the dynamic
covalent bond cross-linking agent adopts a
furan-
maleimide system containing Diels-
Alder reaction, and the dynamic
covalent bond cross-linking agent has good mechanical properties and mechanical properties. Wherein a
furan group and a
maleimide group can be subjected to reversible
addition reaction under a mild condition to form a dynamic
covalent bond, so that rapid and effective self-repairing of the material when the material is damaged is realized, the self-repairing material adopting the technical scheme has an excellent self-repairing function, a repairing process can be triggered without external stimulation, and the self-repairing material has a good application prospect. And the applicability is higher.