Wind-power class bi-component epoxy adhesive and preparation method thereof

An epoxy adhesive, two-component technology, used in the field of wind power grade two-component epoxy adhesive and its preparation, large-scale composite material structure bonding, and wind power blade clamping and bonding, which can solve the problems of poor flexibility and curing reaction. High temperature problems, to achieve the effect of high flexibility, smooth curing process and low heat release

Inactive Publication Date: 2009-10-07
YANTAI DARBOND TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] The purpose of the present invention is to overcome the deficiencies of the above-mentioned prior art, and provide a wind power grade two-component epoxy adhe

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0019] Example 1, accurately weigh the following raw materials, methacrylic acid modified epoxy resin 62g, fumed silicon 9g, organobentonite 9g, alumina 5g, BGE 8g, triphenylphosphine oxide 3g, resorcinol 2.5g , polyoxyethylene alkylphenol ether 1.5g, add the above-mentioned components into the double planetary power mixing mixer in turn, and mix evenly in time to form the A component of the two-component epoxy adhesive, which is packaged after naturally standing to room temperature. Preservation: Accurately weigh 20g of triethylenetetramine and 20g of polyetheramine, add them into a dual-planetary power mixing mixer, and mix them uniformly in time to form curing agent B component, which will be packaged after naturally standing to room temperature, and stored at room temperature; Can be mixed evenly.

Embodiment 2

[0021] Embodiment 2, accurately weigh the following various raw materials, acrylic modified epoxy resin 55g, organic bentonite 8g, fumed silicon 12g, boron nitride 8g, AGE 8g, benzotriazole 3g, hydroquinone 4g, polypropylene Amide 2g, add the above-mentioned components into the double planetary power mixing mixer in turn, and mix evenly in time to form the A component of the two-component epoxy adhesive, which will be packaged after naturally standing to room temperature, and stored at room temperature; Accurately weigh diethylene triethylene Add 25g of amine and 25g of N-aminoethylpiperazine into the double planetary power mixing mixer, pump out and mix evenly to form component B of the curing agent, leave it to room temperature naturally, pack it, and store it at room temperature; mix the two evenly before use. Can.

Embodiment 3

[0032] Embodiment 3, accurately weigh the following various raw materials, methacrylic acid modified epoxy resin 31g, acrylic acid modified epoxy resin 31g, fumed silicon 15g, organic bentonite 4.5g, zinc oxide 1g, silicon oxide 1g, AGE 6g, three Add 3g of phenylphosphine oxide, 2g of benzotriazole, 4g of hydroquinone, and 1.5g of polyacrylamide. Add the above components into a double planetary power mixer in turn, and mix evenly under vacuum to form a two-component epoxy adhesive. Component A of the product, let it stand at room temperature naturally, pack it, and store it at room temperature; Accurately weigh 22g of tetraethylenepentamine and 22g of isophoronediamine, add it to a double planetary power mixer, and mix it evenly to form a curing agent group B Divide, let it stand at room temperature naturally, pack it, and store it at room temperature; mix the two evenly when using.

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PUM

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Abstract

The invention discloses a wind-power class bi-component epoxy adhesive and a preparation method thereof. The epoxy adhesive is made from a main component A mainly consisting of epoxide resin and a filler and a curing agent component B and characterized in that the component A, according to percentage by weight, contains 50 percent to 68 percent of acrylic acid modified epoxide resin, 1 percent to 10 percent of high-property heat filler, 2 percent to 10 percent of epoxide diluter, 10 percent to 25 percent of thixotropic agent and 0.5 percent to 12.5 percent of additive, and the component B is divided into aliphatic amine, polyetheramine, alicyclic amine mixed-type general curing agent; and the mixing proportion of the component A and the component B is 100:30-100:50 according to portions by weight. The invention can improve exothermic peak temperature property during the curing reaction of epoxide resin adhesive and the toughness of the epoxy adhesive, thus being applicable to the cementation of large-scale composite material structural pieces, particularly meeting the requirements for low exothermic peak temperature in wind-power leaf pectization technology.

Description

Technical field: [0001] The invention relates to the technical field of polymer material adhesives, in particular to a wind power-grade two-component epoxy adhesive and a preparation method thereof, which are mainly used in the bonding of large-scale composite material structures, and are especially suitable for the mold-clamping bonding of wind power generation blades . Background technique: [0002] Wind energy is a kind of green energy sourced from nature, pollution-free, and the fastest growing in the world. At present, the wind power industry is in its infancy, and has the conditions for rapid development of the wind power industry, and a large number of enterprises manufacturing wind turbine blades have emerged, and epoxy resin adhesives are usually required to manufacture wind turbine blades with composite materials. [0003] In addition to the characteristics of high thixotropy, long pot life, and high mechanical strength of the cured product, epoxy resin adhesives ...

Claims

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Application Information

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IPC IPC(8): C09J163/10
Inventor 许愿王建斌解海华
Owner YANTAI DARBOND TECH
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