1101 results about "Phenolic aldehyde" patented technology

The invention discloses a wear-resistant high-strength composite polyurethane sieve plate and a preparation method thereof, and belongs to the technical field of polyurethane sieve plate processing.The preparation method comprises the following steps that modified polyurethane is added into xylene, the temperature of a reaction system is increased to 90-100 DEG C, stirring is conducted till the system is dissolved and clarified, and a polyurethane sieve plate is obtained; the preparation method comprises the following steps: adding olefin double bond modified aluminum oxide powder and a catalyst into a reaction system, taking composite polyurethane prepared from modified aluminum powder reinforced modified polyurethane as a polyurethane sieve plate base material, and carrying out reinforced crosslinking on the composite polyurethane by using o-cresol formaldehyde epoxy resin and modified nylon fiber; the strong acid and alkali corrosion resistance of the composite polyurethane sieve plate is effectively improved, and the service life of the composite polyurethane sieve plate is effectively prolonged.

The invention provides a low-warpage underfill adhesive for FC-BGA packaging, a preparation method thereof and a flip chip. The underfill adhesive comprises the following components in percentage by mass: 50%-60% of silicon dioxide, 24%-29% of epoxy resin, 16%-20% of a curing agent, 0.1%-0.2% of carbon black and 0.1%-0.2% of an accelerant. Wherein the epoxy resin is composed of high-purity bisphenol A epoxy resin, polyurethane modified epoxy resin and phenolic aldehyde modified epoxy resin. By adjusting the proportion of the high-purity bisphenol A epoxy resin, the polyurethane modified epoxy resin and the phenolic aldehyde modified epoxy resin and combining the curing agent and the accelerant, the stress of the underfill adhesive is integrally reduced, and the underfill adhesive with good fluidity and low warpage is obtained; therefore, the packaging yield and the packaging efficiency of chip packaging are improved.

The invention relates to the technical field of new materials, and mainly relates to a double-component low-viscosity ultralow-temperature adhesive as well as a preparation method and a use method thereof. The double-component low-viscosity ultralow-temperature adhesive comprises a component A and a component B. The component A comprises the following components in percentage by mass: 20-40% of bisphenol A epoxy resin, 4-8% of aromatic epoxy resin, 6-10% of polyurethane modified epoxy resin, 1-2% of a rubber toughening agent, 5-20% of a diluent and the balance of an additive. And the component B comprises the following components in percentage by mass: 10-40% of a polyether amine curing agent, 10-40% of a fatty amine curing agent, 10-40% of an aromatic amine curing agent and 10-40% of a phenolic aldehyde amine curing agent. The adhesive provided by the invention has relatively strong compressive strength and excellent toughness, can keep good toughness in a low-temperature environment, is not easy to cause brittle rupture, can bear relatively large mechanical load, and is suitable for various industrial applications.

The invention discloses a phthalonitrile modified phenolic aerogel and a preparation method and application thereof. Linear phenolic aldehyde, 4-nitrophthalonitrile and a basic catalyst are dissolved in an organic solvent, a water bath reaction is conducted, powder is prepared, and phthalonitrile etherified phenolic resin is obtained; preparing a mixed solvent, and dissolving linear phenolic aldehyde and phthalonitrile etherified phenolic resin in the mixed solvent to obtain a mixed solution; adding a cross-linking agent into the mixed solution, carrying out sol-gel reaction to obtain wet gel, and aging, segmentally curing and drying the wet gel to obtain the phthalonitrile modified phenolic aerogel. The pyrolytic property of the phenolic aerogel is improved, the phthalonitrile modified phenolic aerogel with high carbon residue and high thermal stability is obtained under the condition of low-temperature heating, and the method is suitable for being applied to the field of thermal insulation ablation of a thermal protection system of aerospace equipment.

The invention discloses a water-borne epoxy resin coating which comprises a component A and a component B, the component A is prepared from 60 to 80 parts of 50 percent modified water-borne epoxy resin emulsion, 5 to 15 parts of deionized water, 0.5 to 1 part of wetting dispersant, 0.2 to 0.8 part of defoaming agent, 5 to 10 parts of modified zinc phosphate, 3 to 5 parts of ion exchange antirust pigment, 4 to 6 parts of sericite powder, 3 to 5 parts of glass flake, 5 to 10 parts of precipitated barium sulphate, 1 to 5 parts of nano silicon dioxide and 0.5 to 1 part of rheological additive; 1 to 2 parts of modified organic bentonite slurry; 0.1 to 0.3 part of a pH conditioning agent; and 0.2 to 0.8 part of a flash rust inhibitor. The component B is prepared from 40 to 50 parts of waterborne epoxy-amine adduct, 20 to 30 parts of 50 percent modified polyamide curing agent, 5 to 15 parts of 60 percent Mannich base phenolic aldehyde amine curing agent, 0.5 to 1.5 parts of epoxy silane coupling agent, 1 to 2 parts of nonionic surfactant and 15 to 20 parts of deionized water. The emulsion stability of the waterborne epoxy resin coating is improved through a bisphenol A / F mixed epoxy emulsion and a grafted polyethylene glycol hydrophilic chain segment.

The invention relates to a phenolic aldehyde-sodium alginate composite carbon material with a three-dimensional network porous structure as well as a preparation method and application of the phenolic aldehyde-sodium alginate composite carbon material. Cheap phenol and formaldehyde are subjected to addition polycondensation, the addition polycondensation reaction time is controlled, phenolic resin is prepared, the phenolic resin and sodium alginate are mixed, a phenolic resin polymer can be uniformly dispersed in sodium alginate hydrogel, then a cross-linking agent solution is added, a semi-interpenetrating network structure is formed, and the cross-linked sodium alginate hydrogel is prepared. The preparation method has the advantages that the flexibility and the controllability are high, the obtained carbon material has high specific surface area, high specific capacitance and high cycle stability, and a new preparation thought and a new material choice are provided for preparing efficient and clean supercapacitors.

The invention provides a modified amine curing agent, a preparation method, epoxy resin anticorrosive paint and application, and belongs to the technical field of paint. The modified amine curing agent provided by the invention is prepared from preparation raw materials including alicyclic diamine, m-xylylenediamine, a first glycidyl ether reagent, a second glycidyl ether reagent and a glycidyl ester reagent through amination reaction, the alicyclic diamine contains at least one primary amine group; the first glycidyl ether reagent is ethylene glycol diglycidyl ether and / or bisphenol A type diglycidyl ether; and the second glycidyl ether reagent is 1, 4-butanediol diglycidyl ether and / or C12-14 glycidyl ether. The modified amine curing agent is combined with the curing characteristics of amide and phenolic aldehyde amine, the epoxy resin anticorrosive paint prepared from the modified amine curing agent has a proper curing speed, the adhesive force of a cured coating is high, the anticorrosive effect is good, and the epoxy resin anticorrosive paint is particularly suitable for a high-humidity environment and an underwater environment.

The invention relates to the technical field of photoresist, in particular to a modification method suitable for photoresist. The photoresist is a positive photoresist and comprises phenolic polymer resin, a diazo naphthoquinone type photoinitiator, a solvent and an additive. According to the invention, a multi-carbon-based enol compound is used as a precursor to prepare a diazo naphthoquinone sulfonate type photosensitive compound, an aldehyde group carried in the diazo naphthoquinone sulfonate type photosensitive compound and an amine additive are used for grafting a photoinitiator-phenolic resin coupling product through a Schiff base reaction, and the dissolution inhibition effect of the photoinitiator-phenolic resin coupling product is adjusted; therefore, key characteristics such as resolution, etching resistance, edge roughness after exposure and development and the like of the photoresist are enhanced.

The invention belongs to the technical field of coatings, and particularly relates to a composite organic silicon anticorrosive coating and a preparation method thereof.The composite organic silicon anticorrosive coating further comprises the following raw materials in parts by weight besides a solvent: 80-95 parts of phenolic epoxy modified organic silicon resin; 1.4 to 3.5 parts of an amine curing agent; 0.08 part to 0.19 part of lithium chloride; 23 parts to 36 parts of filler; the amine curing agent comprises polyamine. According to the composite organic silicon anticorrosive paint disclosed by the invention, under the action of the amine curing agent containing polyamine and lithium chloride, the phenolic epoxy modified organic silicon resin and the filler are mixed and coated on a metal surface, and cross-linking curing of phenolic epoxy molecular chain extension and cross-linking curing of phenolic epoxy molecular chain branch linkage are uniformly carried out; the composite organic silicon anticorrosive coating with excellent impact resistance, hardness and adhesive force is formed.

The invention discloses a high-temperature-resistant metal surface coating and a preparation method thereof, and the high-temperature-resistant metal surface coating comprises the following components in parts by weight: 40-60 parts of ceramic silicon resin, 20-30 parts of polyether sulfone modified organic fluorine resin, 8-10 parts of water-based polyimide resin, 10-15 parts of zinc chrome, 4-6 parts of boron nitride, 3-5 parts of a modified phenolic aldehyde amine curing agent, 8-15 parts of barium sulfate and 8-10 parts of short carbon fiber. The invention relates to the technical field of preparation of metal surface coatings. The metal surface coating is prepared from the following components in parts by weight: 5-8 parts of hollow glass beads, 2-4 parts of a silane coupling agent, 1-3 parts of an organic silicon defoaming agent, 8-12 parts of a dispersing agent, 1-2 parts of a thickening agent and 6-9 parts of a composite coating anti-aging agent. According to the high-temperature-resistant metal surface coating and the preparation method thereof, the ceramic silicon resin, the polyethersulfone modified organic fluororesin and the water-based polyimide resin are adopted as main resin components, a stable structure can be formed at high temperature, and the high-temperature-resistant metal surface coating can bear higher temperature.

The invention provides an anti-compression master batch and a preparation method thereof as well as a low-compression-deformation foaming material and a preparation method thereof, and the anti-compression master batch is prepared by taking TPU (Thermoplastic Polyurethane) with carbon-carbon double bonds as a matrix, high-resilience rubber as a modifier and phenolic resin as an initiator through melt grafting reaction. The anti-compression master batch is added into a foaming material formula, the obtained foaming material is excellent in performance, the compression deformation resistance, the thermal shrinkage performance and the rebound resilience of the foaming material are greatly improved, and the foaming material has high application value.

The invention relates to high-flexibility phenolic-aldehyde-free rosin modified resin, and belongs to the technical field of rosin resin. The raw materials comprise rosin, maleic anhydride, phthalic anhydride, pentaerythritol, glycerol, an acrylate monomer and magnesium oxide. The preparation process comprises four key reactions: (1) rosin and maleic anhydride are subjected to a Diels-Alder reaction to construct a rigid skeleton; (2) introducing phthalic anhydride to form a compact cross-linked network; (3) carrying out composite esterification on pentaerythritol and glycerol; and (4) the interface binding energy is improved by regulating and controlling the in-situ RAFT polymerization of the acrylate monomer. The resin does not contain phenolic aldehyde components, VOCs emission is smaller than 50 g / L, free formaldehyde is not detected, and the resin has high flexibility, heat resistance and excellent chemical resistance.

The invention provides a double-component load-bearing adhesive and a preparation method thereof. The adhesive comprises a component A and a component B in a mass ratio of 1: (0.2-0.5), the component A comprises the following raw materials in parts by weight: 50 parts of epoxy resin; 20-40 parts of glass fiber, 20-40 parts of glass fiber, and 20-40 parts of glass fiber, based on 50 parts of epoxy resin; 2-10 parts of aluminum oxide; 10 to 20 parts of aluminum hydroxide; 1-13 parts of a plasticizer; 0.05 to 1 part of a modifier; wherein the epoxy resin comprises bisphenol A type epoxy resin, bisphenol F type epoxy resin and alicyclic epoxy resin; the component B comprises the following raw materials in parts by weight: 100 parts of a curing agent and 0-5 parts of an auxiliary agent based on 100 parts of the curing agent; wherein the curing agent comprises polyethylene polyamine, polyether amine, phenolic aldehyde amine and polyamide. The adhesive has excellent bonding strength, compression strength, toughness and heat resistance, and is suitable for fixing the bearing point of the LNG / LPG storage tank.

The application discloses a kind of ship super-long anticorrosion special nano powder coating, preparation method and application, belong to ship heavy anticorrosion material technical field.The preparation method of the ship super-long anticorrosion special nano powder coating is as follows: epoxy resin, graphene modified epoxy resin, core-shell structure ZnO@SiO2, modified 2,5-dimercapto-1,3,4-thiadiazole, borosilicate glass powder, flaky boron nitride, silane coupling agent modified silica, phenolic amine curing agent, 2-ethyl-4-methylimidazole, fumed silica, defoaming agent, ultraviolet absorber, high-temperature pigment are put into stirrer and stirred for 20-30min, then melt extrusion is carried out through double screw extruder, the extrusion temperature is 90-110 DEG C, grinds and sieves, and the ship super-long anticorrosion special nano powder coating is obtained.The coating prepared by the application has good anticorrosion performance and can be applied in the field of ship metal surface corrosion protection.

The invention discloses coal tar mixed phenol novolac epoxy resin as well as a preparation method and application thereof. The preparation method of the coal tar mixed phenol novolac epoxy resin comprises the following steps: S1, in an inert atmosphere, mixing and stirring refined coal tar mixed phenol, a solvent and an acid catalyst, then adding an aldehyde solution, and reacting to obtain phenolic resin; s2, in an inert atmosphere, mixing and stirring phenolic resin, a phase transfer catalyst and epoxy chloropropane, preheating to 70-100 DEG C, reacting for 1-4 hours, cooling to 65-70 DEG C, dropwise adding a basic catalyst, heating to 80-85 DEG C, continuously reacting for 2-3 hours, and naturally cooling; and carrying out post-treatment. According to the preparation method and application of the coal tar mixed phenol novolac epoxy resin, operation is easy and convenient, control is easy, and batch production can be achieved conveniently; in addition, the refined coal tar mixed phenol is low in price, the production cost of the anticorrosive paint is greatly reduced, the performance of the paint is improved, and the economic benefits of enterprises are improved.

The invention provides an epoxy resin composition, a prepreg, a laminated board and a metal foil-clad laminated board. The epoxy resin composition comprises the following components in parts by weight: A, 100 parts of epoxy resin; b, 120-390 parts of a curing agent; c, 50 to 200 parts of inorganic filler; the curing agent comprises B1 amino modified organosilicon polymer and B2 amine curing agent and / or phenolic curing agent, and the ratio of B1 to B2 is (1: 2)-(1: 7). The amino modified organic silicon and the amine and / or phenolic aldehyde curing agent are compounded to co-cure the epoxy resin, the overall crosslinking density is increased, and meanwhile, compounding of epoxy resin with different molecular weights is combined, so that the effect of increasing the heat resistance and toughness of a system is achieved. Meanwhile, an amino modified organosilicon polymer is introduced into an epoxy resin system, so that the soft degree of a curing molecular chain can be adjusted, the release of stress in the resin curing process is accelerated, and the effect of flatness of the surface of the prepreg and the plate is achieved.

The invention relates to the technical field of paint, in particular to buried pipeline outer coating paint and a preparation method thereof. The coating comprises a component A and a component B, and the mass ratio of the component A to the component B is (2.12-2.39): 1; the component A comprises the following components in parts by weight: 40-50 parts of epoxy resin, 0-5 parts of a reactive diluent, 2-3 parts of an epoxy resin toughening agent, 2-3 parts of aluminum paste, 0-20 parts of mica powder, 5-20 parts of talcum powder, 5-10 parts of pigment, 5-20 parts of glass flakes, 1-2 parts of organic bentonite, 1-2 parts of a silane coupling agent, 0.1-0.5 part of a dispersing agent, 0.1-0.5 part of a defoaming agent and 0.1-0.5 part of a flatting agent; the component B is a cardanol modified phenolic aldehyde amine curing agent; the hyperbranched modified epoxy resin cooperates with the cardanol modified phenolic aldehyde amine curing agent and the epoxy resin flexibilizer to improve the comprehensive performance of the coating; the cathodic disbonding resistance of the coating is improved through the aluminum paste; therefore, the paint which has good comprehensive performance and can meet various corrosive environments is obtained.

The invention relates to the field of C09J163 / 00, in particular to a fast-curing epoxy resin adhesive and a preparation method and application thereof. The fast-curing epoxy resin adhesive is composed of a component A and a component B, the component A at least comprises the following preparation raw materials: epoxy resin, a filler A, a diluent, a flexibilizer and a coupling agent A; the component B at least comprises the following preparation raw materials: a curing agent, a filler B, an accelerant and a coupling agent B; the curing agent is a combination of a polythiol curing agent and at least one of a phenolic aldehyde amine curing agent and a polyamide curing agent, by optimizing a formula system, the operable time (pot life), the curing speed and the hardness after curing of the product are effectively balanced, the product is rapidly cured within the proper operable time, the hardness after curing can be guaranteed, and the service life of the product is prolonged. And the actual application requirements of pipeline cold welding emergency repair are met.

The invention relates to the technical field of microsphere materials, in particular to microspheres and derivatives thereof, including phenolic resin-based hollow mesoporous carbon materials (hollow mesoporous carbon microspheres) and core-shell silicon dioxide microspheres as well as a preparation method and application thereof. The preparation method of the microspheres comprises the step of reacting resorcinol and aldehyde in a solvent in the absence of a surfactant in a system by taking ammonia water as a basic catalyst, when the molar ratio of the reaction amount of the aldehyde to the resorcinol is (0.5-1): 1, adding tetraethyl silicate to obtain microspheres; and carbonizing the microspheres and removing the silicon dioxide to obtain the phenolic aldehyde-based hollow mesoporous carbon microspheres. The preparation method provided by the invention can be used for preparing the hollow large mesoporous carbon microspheres under the reaction condition of no surfactant.

The invention discloses a polyurethane modified epoxy resin adhesive as well as a preparation method and application thereof, and the polyurethane modified epoxy resin adhesive is prepared from the following components in parts by mass: 7-10 parts of E51 type bisphenol A diglycidyl ether, 3.5 parts of a phenolic aldehyde amine T31 curing agent and 1-3 parts of synthetic polyurethane, the synthetic polyurethane is prepared from polyether triol, polyether amine, isophorone diisocyanate and glycerol carbonate, and a blending system of the synthetic polyurethane and bisphenol A diglycidyl ether is adopted to be subjected to covalent crosslinking with phenolic aldehyde amine T31, so that the adhesive has high toughness and strength guarantee; the synthetic polyurethane prepared by the method is obtained through simple, green and efficient solvent-free synthesis, and the synthesized product has certain fluidity at room temperature, so that the subsequent stirring preparation process of an adhesive is facilitated. And a solvent-free synthesis method is adopted, so that the use of a toxic organic solvent in the traditional polyurethane synthesis process is avoided, and the synthesis process is greener.

The invention relates to the technical field of petrochemical proppants, and discloses a high-performance phenolic resin material which comprises the following components in percentage by weight: 60%-75% of modified phenolic resin, 5%-15% of a curing accelerator, 10%-20% of a flexibilizer, 5%-20% of a filler and 3%-10% of a multifunctional additive, the modified phenolic resin is prepared by the following steps: mixing a phenolic compound and a formaldehyde solution in a reaction kettle, adding a basic catalyst, and reacting to obtain a phenolic prepolymer; gradually adding a modifier containing a hydroxyl group, an epoxy group and a carboxyl group into the phenolic prepolymer, and simultaneously stirring to obtain a mixture; heating the obtained mixture for reaction to complete crosslinking modification reaction to obtain modified phenolic resin; and cooling the modified phenolic resin to room temperature for later use. By adopting the design of the multifunctional flexibilizer and the composite filler, the toughness and thermal conductivity of the material are improved, meanwhile, the curing efficiency is accelerated through the curing accelerator, and the industrial cost is reduced.

The invention relates to the technical field of coatings, in particular to a corrosion-resistant coating material and a preparation method thereof. The corrosion-resistant coating material comprises the following components in parts by mass: 80-100 parts of epoxy resin, 5-20 parts of a modified phenolic aldehyde amine curing agent, 2-5 parts of a waterproof agent, 5-10 parts of a corrosion inhibitor and 40-55 parts of a lubricant. The modified phenolic aldehyde amine curing agent is obtained by carrying out Mannich reaction on phenol, thymol, aliphatic polyamine and formaldehyde. The phenol provides a rigid benzene ring structure, and endows a cured product with good heat resistance and chemical resistance. Thymol improves the flexibility and adhesive force of the cured product and enhances the hydrophobicity of the cured product at the same time. The epoxy resin and the modified phenolic aldehyde amine curing agent are polymerized, the waterproof agent, the corrosion inhibitor and the lubricant are wrapped, and the obtained coating material has good adhesive force and corrosion resistance.

The invention relates to a high-strength wear-resistant archaized brick and a preparation method thereof, and belongs to the technical field of archaized bricks, the high-strength wear-resistant archaized brick comprises the following raw materials: 25-30 parts of fly ash, 30-35 parts of superfine slag powder, 30-35 parts of clay, 8-10 parts of coke powder, 10-12 parts of diatomite, 12-15 parts of potassium feldspar, 10-15 parts of a modified binder and 8-12 parts of a reinforcing agent; according to the technical scheme, a polyhydroxy compound is combined with a silanization reinforcing filler, then combined with an anhydride compound and then combined with novolac epoxy resin, then an amine curing agent is added, and curing is conducted to obtain the modified binder; fly ash, superfine slag powder, clay and coke powder are subjected to ball milling, diatomite, potassium feldspar, a modified binder and a reinforcing agent are added, and the high-strength wear-resistant archaized brick is obtained through stirring, calcining and compression molding. The mechanical property, thermal stability and wear resistance of the archaized brick are improved on the whole, the densification degree of the archaized brick is enhanced, and the comprehensive performance is good.

The invention discloses a quick-curing high-temperature-resistant anticorrosive coating for two-component packaging and a preparation method of the quick-curing high-temperature-resistant anticorrosive coating. The component A of the coating is composed of novolac epoxy resin, epoxy resin, a reactive diluent, an auxiliary agent, an anti-rust pigment, a filler, aluminum powder and a solvent; and the component B consists of phenolic aldehyde amine, alicyclic amine and a solvent. Compared with a traditional phenolic epoxy coating, the product has the advantages of being high in single-time film forming thickness, rapid in curing, resistant to abrasion, high in thermal stability, resistant to cold and hot impact, resistant to corrosion and the like.

The invention relates to the technical field of coatings, in particular to a low-temperature curing anticorrosive coating and a preparation method thereof. The coating is composed of a component A and a component B, and the mass ratio of the component A to the component B is 100: (3-50.8); the component A comprises the following components in parts by weight: 25-35 parts of epoxy resin, 40-72 parts of pigment filler, 2.3-4.5 parts of an auxiliary agent and 10-14 parts of a solvent; the component B is a modified phenolic aldehyde amine curing agent; the epoxy resin is used as a main film-forming substance and is matched with the modified phenolic aldehyde amine curing agent to prepare the low-temperature curing epoxy coating, so that the problem that the epoxy coating cannot be cured at the temperature lower than-10 DEG C is solved, and a coating formed by the coating provided by the invention has good mechanical properties, salt spray resistance, high and low temperature resistance and the like.

The invention discloses a heavy-duty waterborne epoxy glass flake anticorrosive coating and a preparation method thereof, and belongs to the field of anticorrosive coatings. Wherein the component A is composed of a water-based phenolic epoxy emulsion, a water-based epoxy resin dispersion, glass flakes, an anti-rust pigment, titanium dioxide, a wetting dispersant, a coalescing agent, a silane coupling agent, a rheological agent, a base material wetting agent, an anti-flash-rust agent and water; the component B consists of a cardanol modified phenolic aldehyde amine water-based curing agent, a modified aliphatic amine water-based curing agent, a modified polyamide water-based curing agent, propylene glycol monomethyl ether and water; the coating is good in constructability, can be self-dried at normal temperature, has the technical advantages of low VOC (volatile organic compound) content, strong adhesive force, excellent water resistance, boiling resistance and chemical resistance, excellent corrosion resistance and the like, and is wide in raw material source and simple in preparation process.

This anticorrosive coating composition comprises a main agent (I) and a curing agent (II), wherein: the main agent (I) contains an epoxy resin (a); the epoxy resin (a) contains at least one of a bisphenol A epoxy resin (a-11) and a novolac epoxy resin (a-12) each having a weight average molecular weight of 6,000-12,000; the curing agent (II) contains a polyamine (b) and an alkylphenol (c); the polyamine (b) contains an alicyclic polyamine (b-1) having a cyclic aliphatic hydrocarbon group to which an amino group is bonded and contains a non-alicyclic polyamine (b-2) having no cyclic aliphatic hydrocarbon group to which an amino group is bonded; at least one of the main agent (I) and the curing agent (II) includes a vinyl-based defoaming agent (d) that has a constituent unit derived from at least one monomer selected from the group consisting of alkyl (meth)acrylates, alkyl vinyl ethers, and olefins and that has a number average molecular weight of 30,000-100,000 or 300,000-2,000,000; the content of the alicyclic polyamine (b-1) is 30%-80% by mass of the solid content of the curing agent (II); the content of the non-alicyclic polyamine (b-2) is 2%-45% by mass of the solid content of the curing agent (II); the content of the alkylphenol (c) is 5%-60% by mass of the solid content of the curing agent (II); and the content of the vinyl-based defoaming agent (d) is 0.005-3 parts by mass with respect to 100 parts by mass of the anticorrosive coating composition.

The invention belongs to the technical field of fire-extinguishing building materials, and discloses a microencapsulated efficient automatic fire-extinguishing patch and a preparation method thereof.The fire-extinguishing patch contains a fire-extinguishing microcapsule, the fire-extinguishing microcapsule is of a double-layer structure, the inner layer contains gelatin, kaolin, perfluorohexanone, sodium hexametaphosphate, resorcinol and glutaraldehyde, and the outer layer contains gelatin, kaolin, perfluorohexanone, sodium hexametaphosphate, resorcinol and glutaraldehyde; and the outer layer comprises a vinylidene fluoride-acrylic acid copolymer and glutaraldehyde. According to the invention, the flaky kaolin is used for enhancing the formaldehyde-free phenolic aldehyde inner layer and the vinylidene fluoride-acrylic acid copolymer outer layer to form a double-layer shell layer with high air tightness, so that the compactness and long-term stability of the shell layer of the microcapsule are greatly improved.

The invention discloses a high-temperature-stripping-resistant epoxy structural adhesive as well as a preparation method and application thereof, and belongs to the technical field of high-performance composite materials. The epoxy structural adhesive comprises bisphenol A type epoxy resin, novolac epoxy resin, polysiloxane-polyurethane modified epoxy resin, core-shell modified epoxy resin, PEEK ultrafine powder and other components, and through mutual cooperation of all the components, the problems that in a high-temperature service environment, the adhesive layer modulus of traditional adhesive is rapidly attenuated, and a bonding interface is prone to failure are solved; the epoxy structural adhesive provided by the invention has both rapid curing and heat resistance, is stable in interface bonding, has the highest modulus of 1.28 GPa at 80 DEG C, the highest peel strength of 7.8 N / mm at 80 DEG C, and a damage mode of cohesion or high-proportion mixed damage, and is especially suitable for structural bonding requirements of harsh scenes such as peripheral structures of automobile engines, high-temperature areas of electronic equipment and the like.

The invention relates to the technical field of aerogel, in particular to light-weight high-strength three-dimensional ordered structure silicon-boron modified phenolic aerogel and a preparation method of the light-weight high-strength three-dimensional ordered structure silicon-boron modified phenolic aerogel. The aerogel is prepared from raw materials including boron phenolic resin, an organic solvent, organic silicon resin, organic silicon, acidic pH adjusting liquid and a cross-linking agent, the mass ratio of the boron phenolic resin to the organic solvent is 1: (2.3-3.3), the molecular weight of the boron phenolic resin is 3000-5000, and the content of boron is 2%-10%; the aerogel forms a three-dimensional ordered pore structure. The aerogel provided by the invention has the characteristics of small shrinkage rate, high compression strength, small density, uniform and ordered pore size distribution and the like.