The invention discloses a preparation method of an ESBR / SiO2-coated ESSBR
composite material, and belongs to the technical field of rubber
composite material production, and the preparation method comprises the following steps: S1, preparing white
carbon black nanoparticles; s2, preparing a
dopamine solution; s3, additionally preparing white
carbon black (SiO2-PDA) modified by
dopamine; s4, preparing a SiO2 coated ESSBR (
Ethylene Styrene Butadiene Rubber) organic
hybrid filler; s5, flocculating a mixture of
emulsion polymerized
styrene-butadiene rubber and the SiO2 (at) ESSBR organic
hybrid filler to obtain a rubber master batch; s6, adding the rubber master batch,
zinc oxide,
stearic acid and an
antioxidant 4020 into the internal mixer, mixing for 6 minutes, discharging rubber, cooling to
room temperature, mixing on an open mill, adding
sulfur and an
accelerant CZ, batching out, and cooling for later use; s7, vulcanizing the rubber compound in a press vulcanizer, and fully cooling at
room temperature after
vulcanization to obtain the ESBR / SiO2-coated ESSBR
composite material, the technical problems of low
grafting rate of white
carbon black, poor dispersibility of
silicon dioxide and poor compatibility of
silicon dioxide and a rubber matrix are solved, and the ESBR / SiO2-coated ESSBR composite material is widely applied to production of rubber composite materials.