1748 results about "Carbonic acid" patented technology

Adhesive compositions including a multivalent metal salt, an multidentate acidic organic compound, and an aqueous medium are disclosed. The multivalent metal salt and multidentate acidic organic compound can include, as a mixture, a carbonate salt and / or carbonic acid. The aqueous medium can include pH adjusting agent such as sodium hydroxide. The adhesive composition, upon curing, can have a porosity of 10-50%. The adhesive composition, upon curing, can include a plurality of pores. The adhesive composition can be porous, and upon curing can have a plurality of pores having a pore size of between 20 μm to 200 μm. Methods of producing the adhesive composition are disclosed. Methods of using the adhesive composition are further disclosed.

The invention discloses a synthesis method of a hydrazine dicarboxylate modified cerium dioxide abrasive, and belongs to the technical field of precise polishing materials. The method comprises the following steps: taking cerous nitrate as a raw material, and preparing a cerous carbonate precursor through an ammonium carbonate precipitation reaction; and grinding and calcining the obtained precursor and hydrazine dicarboxylate to obtain the CeO2 grinding material with the surface rich in oxygen vacancies. And Ce < 4 + > can be partially reduced into Ce < 3 + > by reducing fragments generated by decomposition of the hydrazine dicarboxylate in the calcining process, so that an oxygen vacancy structure is formed through induction, and the chemical activity and the reaction rate of the abrasive are improved. The obtained grinding material shows excellent performance in chemical mechanical polishing (CMP) of K9 glass, the material removal rate (MRR) is increased by about 3.6 times compared with that of unmodified CeO2, the surface roughness (Ra) is reduced to about 0.16 nm or below, and grinding material particles are good in dispersity and less in agglomeration. The used hydrazine dicarboxylate is stable, low in toxicity and mild in reaction, and the particle size can be prevented from excessively growing while the high oxygen vacancy concentration is kept.

The invention relates to the technical field of soil remediation, in particular to a charcoal-fungus symbiont for a freeze-thaw environment and a preparation method and application of the charcoal-fungus symbiont. The preparation method of the charcoal-fungus symbiont comprises the following steps: crushing a biomass raw material, and carrying out pyrolysis to prepare basic charcoal; placing the basic biochar in an iron oxide solution, and carrying out an iron oxide loading reaction to obtain iron oxide biochar; the preparation method comprises the following steps: dipping iron oxide biochar in a chitosan solution for coating modification, then continuously adding a cross-linking agent for cross-linking solidification, and freeze-drying to obtain chitosan-iron oxide composite modified biochar; and immersing the chitosan-iron oxide composite modified biochar into a bacterial suspension of functional microorganisms, oscillating and adsorbing, and freeze-drying to obtain the carbon-bacteria symbiont. The invention aims to improve the heavy metal pollution phenomenon of soil and the soybean root rot disaster in the freezing and thawing cycle environment at the same time.

The invention relates to the technical field of electrochemical machining, in particular to an electroplate liquid additive automatic supply control method based on conductivity monitoring data. The method comprises the steps that the temperature, the original conductivity and the carbonate concentration of electroplating liquid are obtained, an activation energy coefficient is determined based on the change trend of the original conductivity and the temperature, dynamic thermodynamic decoupling treatment is conducted on the original conductivity, and the net conductivity of the electroplating liquid is generated; according to the cumulative variation of the net conductivity in the historical time period and the total amount of the additive in the historical time period, the transmission inertia factor of the electroplating liquid is calculated in combination with the carbonate concentration, and the retardation risk index is determined based on the evolution trend of the transmission inertia factor, so that a PID control algorithm is reconstructed, and the supply amount of the additive is obtained; and performing automatic replenishment control based on the replenishment amount. According to the method, the accuracy of automatic supply control is improved by evaluating the degradation state of the bath solution components and self-adaptive integral saturation suppression.

This invention discloses a method for catalytically depolymerizing polyethylene terephthalate (PET) to prepare terephthalate. Under catalyst-free conditions or with a salt as a catalyst, PET or its composite system is treated in diester carbonate to achieve chemical depolymerization of PET, yielding PET monomers terephthalate and ethylene carbonate, and achieving complete depolymerization of PET in the composite. This invention, through the reaction of diester carbonate with PET, enables the depolymerization of PET under mild conditions, and further facilitates the research and development of related technologies for the chemical recovery of PET monomers from PET composite or mixed systems. The method provided by this invention has advantages such as high efficiency, environmental friendliness, and mild reaction conditions, and can catalyze the depolymerization of PET to generate its monomer terephthalate, possessing strong industrial application value.

The invention discloses a calcium carbonate sewage treatment intelligent monitoring method based on the Internet of Things, and relates to the technical field of environmental engineering, and the method comprises the following steps: constructing a multi-angle light beam scanning array, collecting a scattering reflection intensity matrix in real time, generating a hot spot candidate set through the matrix, and calculating an angle spectrum deviation coefficient corresponding to a pixel; the base line is used for establishing a bright spot identification base line; and based on the angle spectrum deviation coefficient, introducing a micro-area temperature difference mapping mechanism, collecting a micro-area temperature gradient curve, carrying out normalization comparison on the temperature gradient curve and the angle spectrum deviation coefficient, and extracting a synchronous transition point as a hot spot identification trigger threshold. Microbubble interference is shielded through the dynamic shielding mask, a turbidity monitoring window is corrected, bubble dissipation duration is calculated based on temperature difference attenuation, sedimentation judgment is delayed, advanced stirring and dosing stop caused by misjudgment is avoided, sedimentation sufficiency and water quality stability are improved, intervention frequency is reduced, and the method is suitable for treatment of industrial wastewater containing calcium carbonate particles.

The invention provides a battery and an electric device. A positive plate comprises a positive active material, and the positive active material is doped and / or coated with a lanthanum element; the surface of the diaphragm is coated with a ceramic coating; the electrolyte comprises a first solvent, a second solvent, a first additive and a second additive; the first solvent comprises a cyclic carbonate compound, the second solvent comprises a chain fluorosulfonamide compound, the first additive comprises mannitol carbonate sulfate, and the second additive comprises succinonitrile; the lanthanum element is doped / coated on the positive active material, so that the release of lattice oxygen at high voltage or high temperature can be effectively inhibited, and the exothermic reaction activity at the thermal runaway initial temperature is reduced; the first additive and the second additive in the electrolyte respectively form a compact CEI film and an SEI film with high thermal stability on the surfaces of the positive electrode and the negative electrode; the diaphragm ceramic coating provides a physical barrier, the thermal shrinkage temperature of the diaphragm is increased, and internal short circuit is prevented.

The production device comprises a base, a reaction barrel is fixedly arranged on the base, a mounting frame is fixedly arranged on the outer side of the reaction barrel, a motor is fixedly connected to the top end of the mounting frame, and a stirring device for stirring basic zirconium sulfate and tartaric acid is arranged in the reaction barrel. The feeding parts are sequentially added into the reaction barrel, and a discharging part for discharging reacted liquid is arranged in the reaction barrel; through the staggered and periodic coincidence design of discharging grooves of the inner barrel and the outer barrel in the feeding part, the rotating rod is matched to drive the outer barrel to spirally move downwards, accurate and quantitative adding of the basic zirconium sulfate solution is achieved, meanwhile, the adding time and flow of the tartaric acid solution are automatically controlled through magnetic ring adsorption of the upper barrel and the outer barrel and stored energy release of the first spring, and the feeding efficiency is improved. Manual intervention is reduced, efficiency loss caused by step-by-step feeding is avoided, and the preparation efficiency of the water repellent agent is remarkably improved.

The invention relates to the technical field of industrial control, and discloses a soda water production line intelligent control method and system based on the Internet of Things, and the method comprises the steps: obtaining a backpressure valve reference pressure value according to the obtained real-time dynamic data through employing a pre-constructed carbonation digital twin model, and calculating the backpressure valve reference pressure value according to the backpressure valve reference pressure value; the carbonation digital twinning model is set to obtain a theoretical pressure value by adopting the Henry law according to the target gas content and the real-time data of the mixed liquid temperature, and obtain a predicted pressure value by adopting the pre-constructed pressure prediction model according to the target gas content, the real-time data of the raw material liquid injection flow and the real-time data of the carbon dioxide injection flow; further obtaining a reference pressure value of the back pressure valve; according to a first difference value between the target gas content and the real-time gas content of the mixed liquid, a first feedback correction algorithm is adopted to correct the reference pressure value of the back pressure valve, and a dynamic pressure control instruction of the back pressure valve is obtained; and controlling the back pressure valve to execute the back pressure valve dynamic pressure control instruction. According to the method, the taste stability of the soda water is effectively improved.

The invention provides a method and a system for predicting the durability of an underwater non-dispersible concrete structure, and relates to the technical field of material engineering. Respectively measuring an anti-permeability vector consisting of an unsteady state chloride ion migration coefficient, an anti-permeability grade and an oxygen permeation coefficient, a freezing resistance vector consisting of a mass loss rate and a dynamic elastic modulus retention rate, and a corrosion resistance vector consisting of a mass change rate in a sulfate environment, the dynamic elastic modulus retention rate and a corrosion rate in a carbonic acid environment; a fitting formula among impermeability, freezing resistance and corrosion resistance is constructed based on a known high-durability concrete sample, and by calculating the decoupling degree of each vector combination of the concrete sample relative to the high-durability concrete sample, multi-parameter collaborative evaluation and accurate prediction of the durability of the concrete structure are realized.

The invention discloses a method for reducing the content of rare earth carbonate oil, which comprises the following steps: adding rare earth carbonate seed crystals and pure water into a precipitation tank, feeding a rare earth chloride solution after extraction separation into the precipitation tank, adding an ammonium bicarbonate solution, and carrying out precipitation reaction to obtain rare earth carbonate; the method comprises the following steps: treating rare earth carbonate with hydrochloric acid, converting into a rare earth chloride solution, and filtering the rare earth chloride solution to remove oil to obtain a refined rare earth chloride solution; adding rare earth carbonate into a precipitation tank as a seed crystal, adding the refined rare earth chloride solution and the prepared ammonium bicarbonate solution into the precipitation tank, and carrying out precipitation reaction to produce oil-free rare earth carbonate. According to the invention, oil entrained in the extraction feed liquid and oil dissolved in the feed liquid can be removed, and the quality of the rare earth carbonate product is improved.

The invention relates to the technical field of fluorination equipment, in particular to high-purity fluorocarbonate-based solvent purification equipment, which comprises a purification main body internally provided with a purification cavity; the liquefaction separation module is arranged at the top of the purification cavity and is used for exchanging heat with the crude gas entering the purification cavity, so that the crude gas is liquefied and then subjected to gas-liquid separation; the rotary crystallization module comprises a crystallization pond, a rotary crystal plate group and a collection assembly, the crystallization pond is arranged below the purification cavity and used for receiving the liquefied and separated liquid phase, the rotary crystal plate group partially extends into the crystallization pond, and the rotary crystal plate group continuously rotates, so that liquid in the crystallization pond is crystallized on the surface of the rotary crystal plate group; and then the crystals are collected by the collecting assembly after rotating to the upper part of the crystallizing pond. According to the purification equipment for the high-purity fluorocarbonic ester-based solvent, the high-purity fluorocarbonic ester-based solvent can be continuously obtained in a manner of liquefying and then continuously crystallizing and collecting, so that the purification equipment has a good industrial value.

The invention relates to the technical field of resource recycling of manganese-containing wastewater, in particular to a process for preparing industrial-grade manganese carbonate by using a recycled manganese chloride solution, which adopts a two-stage purification and impurity removal strategy, performs primary purification and impurity removal by using sodium sulfide and sodium fluoride, and performs secondary impurity removal by using iminodiacetic acid grafted chelating resin. According to the invention, the problems of poor adaptability and incomplete impurity removal of the manganese chloride solution in the prior art are solved, the purity of the product is obviously improved so as to meet the requirements of the industrial grade manganese carbonate, and the process flow is simple.

The invention relates to the technical field of purification of fine chemical intermediates, in particular to a purification method of a mannitol carbonate sulfate preparation process intermediate, which comprises the following steps: S1, synthesizing diacetone-D-mannitol; s2, preparing an organic solution containing solids; s3, performing deprotection reaction to prepare a solid crude product; s4, removing unreacted solids; s5, extracting and separating by-product solids; and S6, purifying the target product solid and recovering mannitol. Through system separation and multi-component recovery, preparation of a high-purity product and cyclic utilization of unreacted substances, byproducts and raw materials are realized, the yield is remarkably improved, the cost is reduced, and the quality of a final product is guaranteed.

The invention belongs to the technical field of synthesis of polyol carbonate materials, and discloses a preparation method of polyol carbonate. The preparation method disclosed by the invention comprises the following steps: mixing solid polyol with a eutectic component to form a low-melting-point eutectic substance, and then adding a reactant to carry out cyclization reaction, so as to prepare the cyclic or multi-cyclic polyol carbonate. According to the method, the polyol and the eutectic component are mixed to form a low-melting-point eutectic substance, and the hydrogen-bond interaction of the polyol is weakened through the intermolecular interaction of the eutectic component and the polyol, so that the cyclic or multi-cyclic polyol carbonate can be prepared at high selectivity and high yield under mild conditions.

The present invention relates to a method of producing a carbonated composite:a. providing a particulate mineral material, wherein the mineral material comprises metal slag, wherein the metal slag comprises steel slag;b. providing a modifier, wherein the modifier comprises sodium gluconate;c. mixing the mineral material and the modifier with water to form a slurry;d. treating the slurry with carbon dioxide, to form a wet solid residue, wherein the concentration of carbon dioxide is greater than about 10 vol%; ande. drying the wet solid residue to form the carbonated composite.

The invention relates to a method for recovering lithium and fluorine from aluminum electrolysis hazardous waste, which comprises the following steps: firstly, mixing organic polyol and alkaline hydroxide according to a molar ratio of 1: (0.5-2) to obtain a eutectic solvent; heating the eutectic solvent to 80-150 DEG C, and adding a proper amount of raw material fine powder and calcium oxide for reaction leaching; carbonating and filtering the leachate to obtain lithium carbonate; washing the leaching residues with an acetic acid solution to obtain a calcium fluoride product; the concentration of fluorine ions in the leachate is smaller than or equal to 200 ppm, and the purity of calcium fluoride is larger than or equal to 90%; the leaching rate of lithium in the method is greater than 85%; the slag feeding rate of fluorine is greater than 95%; and no hydrogen fluoride gas is generated in the method. According to the method, a non-toxic and biodegradable eutectic solvent is adopted as a leaching agent, and efficient leaching of lithium and fluorine in the aluminum electrolysis dangerous waste materials is achieved; calcium oxide is used as a precipitating agent, free fluorine is promoted to be precipitated and recycled as calcium fluoride, the whole process meets the requirement of green metallurgy, and the win-win situation of resources and the environment is achieved.

A method may include: introducing a resin modified cement slurry into a wellbore penetrating a subterranean formation, the subterranean formation comprising a caprock and a carbon dioxide injection zone, the resin modified cement slurry comprising: a resin; a hardener, a hydraulic cement; and water; and setting the resin modified cement slurry to form a set cement wherein the set cement forms a carbonation-resistant barrier in the carbon dioxide injection zone in the subterranean formation.

Methods for preparing catalysts for oxidative dehydrogenation (ODH) of alkanes such as ethane are provided. An exemplary method includes forming a slurry including metal oxides; one or more of a bismuth compound, an antimony compound, and a tellurium compound; a reducing agent; and water; and heating the slurry to form the catalyst. The metal oxides include an oxide of molybdenum and an oxide of vanadium. The bismuth compound includes bismuth oxide, bismuth hydroxide, or a bismuth carbonate. The antimony compound includes an oxide of antimony, an antimony acetate, or an antimony ethoxide. The tellurium compound includes tellurium dioxide. The reducing agent includes molybdenum dioxide and may further include vanadium dioxide. The methods use all inorganic reagents, with no build up COx pressure observed during the hydrothermal synthesis.

The invention discloses a preparation method and application of a multimode luminescent cesium yttrium chloride lead-free perovskite luminescent material. In the specific synthesis process, firstly, precursor materials-cesium carbonate, yttrium carbonate and cerium acetate are dissolved in a mixed solution of glacial acetic acid and hydrochloric acid, and a precursor solution is obtained; then dissolving a certain amount of antimony acetate with acetonitrile to form an anti-solvent solution; and finally, adding the precursor solution into the anti-solvent solution to obtain the Sb / Ce double-doped cesium yttrium chloride lead-free perovskite luminescent material. During application, the Cs3YCl6 Sb and the Cs3YCl6 Sb / Ce luminescent materials are combined for use to form a pattern, and protected information can be decrypted through a specific excitation wavelength. According to the invention, the cesium yttrium chloride lead-free perovskite luminescent material capable of realizing multimode luminescence can be prepared in a short time.

The invention provides a high ventilation method for maintaining equal carbonic acid through exogenous CO2 gas and a breathing device. Belongs to the technical field of gas exchange. The method comprises the steps that physiological monitoring data of a patient are collected in real time, and meanwhile parameters of a breathing machine are obtained; inputting the collected data into a pre-trained time sequence prediction model; performing data fusion based on the EtCO2 predicted value, the currently actually measured physiological data and the static parameters of the patient to form a comprehensive evaluation result; and through a control algorithm, an incremental adjustment instruction of the exogenous CO2 supplementary flow is obtained through calculation based on the comprehensive evaluation result. The CO2 demand is estimated in real time through a dynamic prediction model, static estimation is replaced, and the control accuracy and the response speed are remarkably improved; through a multi-modal data fusion technology, dynamic and static physiological parameters are comprehensively applied, so that a control strategy can better reflect the individualized physiological status of a patient.

The invention discloses a preparation method and application of a catalyst based on pyridine ionic liquid, and belongs to the technical field of catalyst preparation. According to the invention, a hydrolysis reaction of a silane coupling agent is utilized to prepare a silicon oxide nanotube containing a pyridine unit, and then a quaternization reaction is carried out to obtain the catalyst based on the pyridine ionic liquid. The catalyst has a high specific surface area and a rich pore channel structure, exposure of active sites and contact of the active sites and reactants are facilitated, and the catalytic rate is increased. Meanwhile, the silicon oxide nanotube contains hydroxyl, and can cooperate with a pyridine ionic liquid site to catalyze a carbon dioxide cycloaddition reaction. The obtained catalyst can catalyze the reaction of carbon dioxide and an epoxy compound to prepare cyclic carbonate under solvent-free and metal-free conditions, and the catalyst is easy to recover and simple in product purification, and has a good application prospect.

The invention provides a method for accelerating carbon dioxide mineralization and sequestration based on a calcium ion-containing aqueous solution, and relates to the technical field of carbon dioxide capture, utilization and sequestration. The method comprises the following steps: selecting a calcium-containing compound, dissolving the calcium-containing compound in water, and uniformly stirring and mixing to obtain an initial aqueous solution; the calcium ion concentration in the initial aqueous solution is within a preset calcium ion concentration range; an alkaline regulator is added into the initial aqueous solution, a target aqueous solution is obtained, and the pH value of the target aqueous solution is within a preset pH value range; injecting the target aqueous solution into formation water of a target formation through injection equipment; carbon dioxide to be sealed is injected into the formation water, and calcium ions in the target water solution and carbonate ions generated after the carbon dioxide is dissolved in the formation water are subjected to mineralization reaction to form calcium carbonate precipitates. According to the method, CO2 dissolution and carbonate conversion are effectively promoted, generation of calcium carbonate precipitates is greatly accelerated, and the key bottleneck of slow reaction kinetics of a traditional mineralization method is overcome.

The invention provides a preparation method of dicapryl carbonate, belongs to the field of preparation of dicapryl carbonate, and can solve the problems of unstable reaction system, low raw material conversion rate, low catalyst efficiency, poor phase contact effect, many side reactions, low product purity and poor quality in the existing preparation method of dicapryl carbonate. The preparation method of dicapryl carbonate comprises the following steps: fully mixing n-caprylic alcohol, a basic catalyst and a cosolvent, continuously dropwise adding low-grade dialkyl carbonate into the mixed solution for 5-10 hours through a liquid material distributor, carrying out ester exchange reaction, continuously extracting low-boiling-point substances, controlling the reflux quantity, and carrying out reduced pressure distillation to obtain the dicapryl carbonate. The method comprises the following steps: adding a cosolvent into a reaction solution, enabling the cosolvent with an initial addition amount to always exist in the reaction solution, after the reaction is finished, dealcoholizing by reduced pressure distillation, and removing impurities by washing to obtain a crude product of dioctyl carbonate, and rectifying to obtain a dioctyl carbonate product. The preparation method is high in raw material conversion rate and high in product yield, and the purity of the obtained product is gt; the content of impurities is low, and the method can be applied to preparation of cosmetics.

Low CAPEX / OPEX, effective, and environmentally friendly process of rapidly extracting lithium from geothermal brines and producing lithium carbonate. The method includes adjusting a unique parameter determined based on the modified alkalinity in a quantity of the geothermal brine to a preset value without needing to purposefully modify the pH. Interactions of the anionic reactant species with components within the geothermal brine cause a solid form of the lithium to precipitate out of the geothermal brine. After the solid separation, the spent brine is environmentally safe and returned underground or transported to a reservoir.

The invention belongs to the technical field of chemical synthesis, and discloses a method for synthesizing cyclic carbonate through urea alcoholysis under photo-thermal synergistic catalysis. Uniformly mixing the mixed solution of methanol and ionic liquid, zinc salt and other metal salts, and reacting; and after the reaction is finished, centrifugally separating a product, washing, drying, and calcining to obtain the zinc-based homojunction photo-thermal catalyst. The method comprises the following steps: mixing urea, dihydric alcohol and a zinc-based homojunction photo-thermal catalyst, and reacting for 1-6 hours under the conditions that the light intensity is 1-150 mW / cm, the temperature is 130-160 DEG C and the pressure is 5-30 kPa to obtain the cyclic carbonate. The catalyst used in the method effectively overcomes the limitations of low target product synthesis efficiency and high reaction energy barrier in single thermocatalysis, and the yield of the synthesized cyclic carbonate can reach up to 84.1%. Through light energy excitation coupling thermocatalysis, the harshness of reaction conditions is significantly reduced, and efficient synthesis of cyclic carbonate under mild conditions is realized.

The application discloses a preparation method of mesoporous copper oxide and application thereof. The preparation method comprises the following steps: S1, preparing a hydroxyl copper nitrate microplate by taking calcium carbonate paper as a substrate and copper nitrate as a solvent; S2, synthesizing an ordered copper hydroxide nanowire assembly through an alkali solution reaction; and S3, performing annealing treatment in a muffle furnace to obtain the mesoporous copper oxide microplate. Under the conditions of no hard template, no soft template and no strong acid treatment, the application provides a method for synthesizing the mesoporous copper oxide microplate material with uniform pore structure on the carbonic paper by adopting copper nitrate hydrolysis, alkali etching and annealing, and the synthesis method of the mesoporous structure has the advantages of simple operation, good controllability and low cost. The application also relates to application of the mesoporous copper oxide as an electrocatalyst material in the field of glucose electrochemical sensing.

The invention relates to the technical field of aluminum oxide preparation, in particular to a method for preparing flaky aluminum oxide by using electrolyte waste liquid and flaky aluminum oxide. The method comprises the following steps: carrying out carbonation reaction on the electrolyte waste liquid by using carbon dioxide to obtain aluminum hydroxide precipitate; washing the aluminum hydroxide precipitate for the first time by using a washing agent to obtain a washed aluminum hydroxide solid-phase substance with a preset sodium content; calcining the washed aluminum hydroxide solid-phase substance to obtain a gamma-type aluminum oxide precursor; carrying out molten salt reaction on the composite molten salt system and the gamma-type aluminum oxide precursor to obtain a flaky aluminum oxide crude product; wherein the composite molten salt system is a mixture of sodium chloride, potassium chloride and sodium sulfate; and carrying out secondary washing on the sheet-shaped aluminum oxide crude product to obtain a sheet-shaped aluminum oxide product. According to the method, the flaky alumina with the high radius-thickness ratio is prepared under fluoride-free and strong acid conditions through a three-step core strategy of resource utilization of waste electrolyte, accurate sodium content control and directional induction of composite molten salt.

The invention relates to a method and a system for preparing chloroethylene carbonate through continuous photochlorination. The system aims at solving the three technical problems that the mass transfer efficiency of chlorine is low under the high gas-liquid ratio, reaction balance is inhibited by accumulation of hydrogen chloride by-products, and selectivity is reduced due to excessive chlorination. The method provided by the invention comprises the following steps: dispersing chlorine into bubbles of 50 microns or below by adopting a metal sintering microbubble generator; a light source and a hollow fiber membrane separation assembly are arranged in the reactor, chlorine and ethylene carbonate are subjected to a reaction through photo-initiation to generate chloroethylene carbonate, and meanwhile generated hydrogen chloride is removed through membrane in-situ displacement by means of purging gas; the system adopts a two-section series structure, and the reaction depth is cooperatively controlled through sectional chlorine gas introduction and gradient illumination intensity. The method provided by the invention realizes efficient utilization of chlorine, real-time breaking of reaction balance and high-selectivity synthesis of monochlorinated products, and is suitable for continuous, safe and efficient industrial production of chloroethylene carbonate.

The invention belongs to the technical field of dangerous solid waste treatment, and relates to a cascade deep detoxification method and system for waste incineration fly ash. Comprising the following steps: carrying out natural carbonation pretreatment on the fly ash to stabilize the pH value of the fly ash to be about neutral so as to obtain pretreated fly ash; carrying out primary washing on the pretreated fly ash by adopting an EDTA (Ethylene Diamine Tetraacetic Acid) solution, and carrying out solid-liquid separation to obtain primary washing slag; wherein the residual heavy metals in the first-stage washing slag obtained by the first-stage washing are mainly distributed in a weak acid extraction state; and carrying out second-stage washing on the first-stage washing slag by adopting an acetic acid solution. The method provided by the invention synergistically realizes deep and efficient removal of heavy metals in fly ash, and the final product meets safe disposal or resource utilization standards.