The present invention relates to a catalyst for synthesizing diphenyl carbonate by utilizing heterogeneous oxidation carbonylation and preparation method of said catalyst. Said preparation method includes the following steps: making palladium salt be loaded on the manganese series composite metal oxide carrier, said manganese series composite metal oxide carrier is formed from manganese oxygen compound and metal oxide of any one kind or more than one kind of La, Ce, Ti, Zr, V, Cr, Mo, W, Fe, Co, Ni, Cu, Ag, Zn, Bi, Pb and Sn, the loaded quantity of active component Pd is 0.01wt%-10wt%, utilizing impregnating process, precipitation process or mixed fuel burning process to make the active component palladium salt be loaded on the manganese series composite metal oxide carrier, drying and calcining for 1-8h at 200-600deg.C so as to obtain the invented solid catalyst. Said catalyst can be used for preparing diphenyl carbonate, its productivity is up to 22.0% and its selectivity is up to 98.3%.