A technology for synthesizing dimethyl carbonate adopts a two-tower continuous reaction, and comprises the following steps: a raw material liquid methanol is fed from the upper part of a gas and liquid distributor of a first reactor, flows out of the gas and liquid distributor and enters the reaction section of a reactor, a raw material gas CO is introduced to the first reactor from the bottom ofthe reaction section of the reactor, O2 is divided into 2-5 passages, O2 in the 2-5 passages except one is distributed in the reaction section of the reactor, a reaction is continuously carried out under the action of a catalyst in the reaction section to generate dimethyl carbonate, a formed mixed liquid A flows into the water separation section of the first reactor, methanol and dimethyl carbonate in the mixed A go through a bottom hydrophobic membrane and continuously downwards flow into a tower bottom to form a mixed liquid B, water permeates a surrounding hydrophilic membrane, and then iscollected and discharged, the mixed liquid B in the bottom of the first reactor enters a second reactor, a crude product is extracted from the bottom of the second reactor, and non-condensable gasesCO, O2 and CO2 obtained after the reactions in the first reactor and the second reactor are discharged from the top of the reactors. The technology has the advantages of simple process, high methanolconversion rate and low energy consumption.