999 results about "Chain transfer" patented technology

The invention discloses deep eutectic gel polymer electrolyte as well as preparation and application thereof, belongs to the technical field of battery electrolyte, solves the problems of low thermal stability, low ionic conductivity and poor mechanical property in the prior art, and comprises a bimetallic salt-eutectic solvent and a polymer chain which are dynamically crosslinked and constructed, the bimetallic salt-eutectic solvent comprises lithium ions, heterogeneous metal salt and Lewis base, and the polymer chain is formed by free radical polymerization, atom transfer radical polymerization (ATRP) or reversible addition-fragmentation chain transfer radical polymerization (RAFT). According to the invention, the deep eutectic solvent is introduced as a reaction solution, so that the organic gel monomer is subjected to photopolymerization or thermal polymerization in the solution, the elongation at break can reach more than 500%, the organic gel has excellent mechanical stretchability, a polymer network is formed by utilizing a long-chain molecular formula of a polymer chain, the deep eutectic solution is wrapped in the polymer network, and the organic gel has excellent thermal stability; and the good ionic conductivity of the electrolyte is ensured.

The invention discloses a bionic lignin-based saline-alkali soil improvement material and a preparation method thereof, and belongs to the technical field of high polymer materials and soil improvement. According to the saline-alkali soil improving material, lignin or a derivative thereof serves as a framework, glutenin charge distribution and a dynamic disulfide bond sodium ion response function are simulated, and the sequence and the proportion of chain segments of sulfonic acid groups and quaternary ammonium salt groups are accurately regulated and controlled through step-by-step activation and alternate copolymerization in an aqueous solution polymerization reaction system; positive and negative charges form more uniform sequence distribution, so that the amphipathy of the lignin compound is realized; then, sulfydryl is introduced through click chemistry, linear regulation and control of material viscosity and water solubility are achieved through the chain transfer characteristic of multi-sulfydryl functional groups, and the requirements of different saline-alkali soil application scenes are met. The limitation that a traditional lignin product is single in function is broken through, efficient utilization of lignin is achieved, and the intelligent saline-alkali soil improvement material integrating high stability and pH and Na < + > multi-environment response is developed.

The invention discloses a special grinding aid for gold ore and a preparation method thereof, and belongs to the technical field of mineral processing, the special grinding aid for gold ore comprises the following raw materials: a monomer, an initiator, a chain transfer agent and a solvent; the monomers are an unsaturated polyether monomer A and an unsaturated carboxylic acid monomer B; or a monomer C containing an ethylenically unsaturated sulfonic acid group. The preparation method comprises the following steps: putting the raw materials into a water bath kettle, and polymerizing in a separate dropwise adding manner to prepare the special grinding aid for the gold ore. The prepared grinding aid can improve the problems of particle agglomeration, low fine grinding efficiency, low gold dissociation efficiency and the like in the gold ore grinding process, the concentrated utilization of the grinding aid limited in the fields of cement, ceramics and the like is improved, the grinding energy consumption can be reduced, and the material quality can be improved.

The invention discloses polymer graft modified graphene oxide as well as a preparation method and application thereof, and belongs to the field of building materials. The polymer grafted modified graphene oxide comprises graphene oxide and a polymer grafted on the surface of the graphene oxide through an ester bond, and the grafting mass ratio of the graphene oxide to the polymer is 1: (0.15-0.75). The preparation method of the polymer grafted modified graphene oxide comprises the following steps: firstly, carrying out esterification reaction on hydroxyl on the surface of graphene oxide and a reversible addition-fragmentation chain transfer polymerization (RAFT) chain transfer agent to generate GO of which the surface is grafted with the RAFT chain transfer agent; and adding a methacrylic acid monomer and an initiator, and carrying out RAFT polymerization on the surface of the GO to obtain a target product. The polymer grafting modified graphene oxide provided by the invention can achieve the effects of high polymer grafting ratio and capability of improving the fluidity of cement paste.

The invention discloses a C6 monomer polycarboxylate superplasticizer and a preparation method thereof. The C6 monomer polycarboxylate superplasticizer is prepared from the following raw materials in parts by mass: 300-380 parts of C6 ethylene glycol monovinyl polyglycol ether polyether macromonomer, 7.5-11.0 parts of acrylic acid, 0.3-1 part of chain transfer agent, 0.15-1.0 part of reducing agent and 0.6-1.2 parts of oxidizing agent. The water reducing agent prepared by the invention has the advantages of simple process, energy conservation, environmental protection, shortened synthesis time, improved production efficiency, high adaptability and better water reducing property.

The invention discloses a single-chain nanoparticle composite reinforced and toughened plastic material and a preparation method thereof, and belongs to the technical field of polymer plastics. The reinforced and toughened plastic material is prepared from the following raw materials in parts by weight: 10 to 20 parts of polymer monomer, 0.004 to 0.005 part of initiator, 0.05 to 0.06 part of chain transfer agent, 8 to 12 parts of solvent and 0.1 to 0.2 part of functional filler, the preparation method specifically comprises the following steps: (1) weighing the raw materials; (2) uniformly mixing the raw materials, and performing nitrogen atmosphere replacement and polymerization reaction; and (3) re-precipitating, and drying in vacuum to obtain the product. The reinforced and toughened plastic material disclosed by the invention not only has excellent performance in the aspect of tensile property, but also shows excellent mechanical response under a bending-resistant load, and is suitable for engineering plastic application scenes with relatively high requirements on structural stability and use safety.

The invention belongs to the technical field of polycarboxylate superplasticizers for concrete, and particularly relates to a sodium glutamate modified polycarboxylate superplasticizer and a preparation method thereof. The sodium glutamate modified polycarboxylate superplasticizer is prepared from a polyether monomer, acrylic acid, an initiator, a chain transfer agent, a reducing agent, sodium glutamate and water. By adding sodium glutamate, the molecular structure of the polycarboxylate superplasticizer is influenced, the water-reducing rate, slump holding time and neat paste fluidity of the polycarboxylate superplasticizer are improved, and the solubility of the polycarboxylate superplasticizer in water is improved, so that the dispersity, plasticity retaining property and the like of the polycarboxylate superplasticizer in concrete are improved; the working performance of the concrete is obviously improved.

The invention discloses a super-retarding type polycarboxylic acid water reducing agent and a preparation method and application thereof, and belongs to the field of concrete water reducing agents. The preparation method comprises the following steps: taking acrylic acid AA, isobutenol polyoxyethylene ether HPEG and hydroxyethyl acrylate HEA as monomers, taking mercaptopropionic acid MPA as a chain transfer agent, taking hydrogen peroxide H2O2 and L-ascorbic acid Vc, and mixing in proportion to serve as an initiator; preparing a first and second monomer mixed solution; adding bottom water into the reaction kettle, and carrying out stepwise polymerization reaction; and cooling the reaction liquid, adjusting the pH value, filtering, and discharging to obtain the product. According to the invention, an ester functional monomer hydroxyethyl acrylate HEA is introduced, and a step-by-step polymerization technology is adopted to control the dispersion process of water reducing agent molecules on cement particles, so that the water reducing agent molecules continuously disperse the cement particles within a certain period of time; the problem that the slump loss is too fast due to long-time and long-distance transportation of concrete or transportation in high-temperature weather is effectively relieved.

The invention belongs to the technical field of concrete, and particularly relates to a polycarboxylate superplasticizer and a preparation method thereof. The polycarboxylate superplasticizer is prepared from an unsaturated polyether macromonomer, an unsaturated acid monomer, an unsaturated carbonate monomer, an unsaturated amino monomer, an initiator, a reducing agent, a chain transfer agent, deionized water, a solubilizer and organic alcohol amine. Wherein the unsaturated carbonate monomer is allyl methyl carbonate, and the unsaturated amino monomer is 2-aminoethyl methacrylate hydrochloride. According to the invention, excellent water reducing effect and stable control capability on concrete slump are maintained, and micro-cracks can be effectively made up through a dual mechanism formed by carbonate release and CaCO3 precipitation in the early and later stages of concrete hardening.

The invention relates to a dry-jet wet-spinning ultra-high-performance polyacrylonitrile-based carbon fiber and a preparation method thereof, and belongs to the technical field of carbon fibers. A preparation method of dry-jet wet-spinning ultra-high-performance polyacrylonitrile-based carbon fiber comprises the following steps: S1, mixing acrylonitrile, a comonomer, a chain transfer agent, an initiator and a solvent, carrying out polymerization reaction through a solvent dropwise addition method, and preparing a spinning solution; wherein the comonomers comprise a first comonomer, a second comonomer and a third comonomer; s2, the spinning solution is subjected to solidification, water washing, water drawing, oiling, drying and steam drawing, and precursor fibers are obtained; s3, the precursor fiber is sequentially subjected to pre-oxidation, low-temperature carbonization, high-temperature carbonization, graphitization, surface treatment, sizing and drying, and the ultra-high-performance polyacrylonitrile-based carbon fiber is prepared. Wherein the pre-oxidation adopts four-stage pre-oxidation treatment. The strength and modulus of the carbon fiber can be effectively and synergistically optimized, and the carbon fiber with high strength and high modulus is prepared.

The invention belongs to the technical field of polyurethane, and particularly relates to multi-element synergistic flame-retardant polymer polyol and a preparation method thereof. The flame-retardant polyether polyol is prepared from phosphorus-halogen mixed flame-retardant basic polyether polyol, a halogen-containing flame-retardant vinyl unsaturated monomer, a silicon-containing flame-retardant vinyl unsaturated monomer, a nitrogen-containing modified polyether dispersant, styrene, acrylonitrile, an initiator and a chain transfer agent through reaction. The halogen-containing monomer introduced into the POP polymerization monomer directly participates in free polymerization, and cooperates with the flame-retardant elements in the basic polyether, so that the content of the flame-retardant elements in the POP can be effectively increased, and the flame retardance is improved. A vinyl silicon structure is added in a POP polymeric monomer, and a silicon element is introduced into a molecular chain, so that the flame retardance is improved, the hydrophobicity of POP can be improved, and the viscosity of the composite material is reduced. The macromolecular nitrogen-containing dispersing agent forms a nitrogen-phosphorus-bromine ternary synergistic flame-retardant system by adopting a DMC catalytic process and a polyurethane synthesis technology, so that the flame retardance of POP is further improved.

The invention relates to the technical field of concrete admixtures in building materials, in particular to a viscosity reduction type polycarboxylic acid water reducer suitable for high-strength concrete and a preparation method of the viscosity reduction type polycarboxylic acid water reducer. The hydrophobic modified unsaturated double-chain polyether macromonomer is prepared from the following components in parts by mass: 20 to 30 parts of unsaturated acid, 200 to 300 parts of hydrophobic modified unsaturated double-chain polyether macromonomer, 10 to 15 parts of phosphate monomer, 2 to 4 parts of oxidizing agent, 1 to 2 parts of reducing agent, 1 to 2 parts of chain transfer agent, 5 to 10 parts of neutralizing agent and 120 to 180 parts of water. According to the invention, the polyether chain can unfold in a pore solution, the steric hindrance effect is further enhanced, cement particles are ensured to be effectively dispersed in a compact space, and meanwhile, the hydrophobic part of the side chain can effectively reduce the surface tension of the pore solution, so that the condition of overhigh viscosity is avoided, and the flowability and constructability of the concrete are improved.

The invention belongs to the field of membrane materials, and particularly relates to a polyether-based block copolymer and a preparation method and carbon capture application thereof. According to the invention, dichloromethane is taken as a solvent, trifluoromethanesulfonic acid is taken as an initiator, and in the presence of a chain transfer agent ethylene glycol, 1, 3-dioxolane is subjected to cationic ring-opening polymerization to generate PDXL (HO-PDXL-OH) of which two terminal groups are hydroxyl groups. Further, N, N-dimethylformamide is used as a solvent, dibutyltin dilaurate is used as a catalyst, and HO-PDXL-OH and diphenylmethane diisocyanate are subjected to polycondensation to synthesize block copolymer polyurethane (PU). The polyether-based segmented copolymer prepared by the preparation method disclosed by the invention is used as a gas separation membrane material and has relatively high CO2 capture performance, and the CO2 separation performance of the polyether-based segmented copolymer is superior to that of other polyether-based membrane materials and is close to the Robeson upper limit.

Disclosed in the present invention is a composition for preparing a vinyl block copolymer, the composition comprising: a first monomer ethylene, a second monomer a C3-C20 α-olefin and at least one regulation monomer, the regulation monomer being an olefin or a substituted olefin with the C atom number greater than 3, or styrene / a styrene derivative, and in the same composition, the second monomer being different from the regulation monomer. The composition is catalyzed by a main catalyst and a co-catalyst to obtain the vinyl block copolymer, wherein the main catalyst is a complex L-MR1R2R3 that contains three substituents and that is formed by an IVB-group metal and a monoanionic ligand, and the co-catalyst includes alkyl aluminum, polymerized or oligomerized aluminoxane, a neutral Lewis acid, a non-polymer, a non-coordinated ionic compound, or a mixture of two or more described above. Provided in the present invention is a composition capable of obtaining a lower-olefin block copolymer, the composition can obtain a lower-olefin block copolymer without the need of replenishing monomers or adding a chain transfer reagent for polymerization during polymerization processes, so that a production process is simple and involves low cost.

The invention discloses a viscosity reduction type concrete admixture and a preparation method thereof, and belongs to the technical field of concrete admixtures. The admixture comprises a viscosity reduction type polycarboxylic acid water reducing agent, a hydrophobic surfactant, an air entraining agent, a defoaming agent, a retarder and water, wherein the viscosity reduction type polycarboxylic acid water reducing agent is prepared from a polyether monomer, unsaturated acid, a viscosity reduction functional monomer, an oxidizing agent, a reducing agent, a chain transfer agent, a neutralizing agent, a catalyst and deionized water. The viscosity reduction type polycarboxylic acid water reducer added in the admixture effectively reduces the HLB (hydrophile-lipophile balance) value of the surface of cement paste through the polymerization of phosphate groups in the viscosity reduction functional monomer, improves the flowability of concrete, and realizes the viscosity reduction effect. The mixing amount level of the admixture is 1.0-1.8%, and the admixture has the characteristics of low mixing amount, environment-friendly preparation process and excellent viscosity reduction effect, and has no negative influence on indexes such as concrete strength and the like.

The disclosure relates to block copolymer nanoparticles for therapeutic delivery of nucleic acids, and methods therefor. More particularly, the invention relates to polymer nanoparticles, such as reversible addition-fragmentation chain transfer (RAFT) polymer compositions, for delivering miRNAs.

The application discloses a PAG bonding type photosensitive photoresist resin and a preparation method and application thereof. The photoresist resin is as follows: formula. The PAG bonding type resin is prepared through the following reaction process: 1) performing a RAFT polymerization reaction on p-acetoxystyrene, p-styrene sulfonamide trifluoromethyl potassium salt and a RAFT chain transfer agent under the action of an initiator to obtain an intermediate I, 2) performing a hydrolysis reaction on the intermediate I to obtain an intermediate II, 3) performing a protection group introduction reaction on the intermediate II and di-tert-butyl dicarbonate to obtain an intermediate III; and 4) performing an ion exchange reaction on the intermediate III and triphenylsulfonium bromide. The application realizes the bonding of the PAG into the resin skeleton, and improves the problems of poor compatibility between the PAG and the resin, phase separation, uneven distribution of the PAG and the like. Therefore, the photoresist prepared from the resin has the photo-generated acid bound by the polymer main chain and limited diffusion, the resolution is improved, and the photoetching effect is excellent.

Provided is a graft copolymer in which a (meth)acrylic acid ester-based polymer block (A) having a reactive silicon group and a polyoxyalkylene-based polymer block (B) having a number average molecular weight of 1,000 or more are bonded in the order of A-B-A. The content of (A) is 35-70 wt. % and the content of (B) is 30-65 wt. %. The (A) contains a structural unit derived from a (meth)acrylic acid ester (a1) and a structural unit derived from a chain transfer agent (a2) having a mercapto group. The content of the alkyl (meth) acrylate ester having an alkyl group with 7 or more carbon atoms is 7 wt. % or less in the graft copolymer. The sulfur atom concentration derived from (a2) is 4,500-10,000 ppm in the graft copolymer.

The invention belongs to the technical field of drilling fluid additives for petroleum drilling, and discloses a heat-resistant water-based drilling fluid additive as well as a preparation method and application thereof. The water-resistant water-based drilling fluid additive is a high-molecular compound which is formed by taking water as a solvent, dissolving animal bone glue to form a glue solution, and performing etherification reaction on the glue solution and bromoethane under the action of a chain transfer agent and a base catalyst. The preparation method comprises the following steps: adding animal bone glue into water, dissolving to obtain a glue solution, sequentially adding sodium hydroxide, sodium carbonate and bromoethane to form a reaction system solution, then adding a chain transfer agent, and heating and refluxing to react to obtain the water-resistant water-based drilling fluid additive. According to the prepared bromoethane modified bone glue, the chain transfer agent is added in the modification process, the technical defect that the molecular weight of the bone glue cannot be manually controlled is overcome, the inhibition effect is obvious, meanwhile, the rheological property of drilling fluid is not affected, and the problems of borehole wall instability and the like caused by shale hydration expansion in the drilling process can be effectively solved.

The invention provides an ester-ether copolymerization type slump-retaining polycarboxylic acid water reducer and a preparation method of the ester-ether copolymerization type slump-retaining polycarboxylic acid water reducer. The water reducing agent is prepared from the following raw materials in parts by weight: 80 to 120 parts of main chain macromonomer, 20 to 35 parts of unsaturated carboxylic acid, 1.5 to 3.2 parts of initiator, 0.2 to 0.5 part of reducing agent, 0.3 to 0.8 part of chain transfer agent, 8 to 15 parts of neutralizer, 200 to 300 parts of solvent, 5 to 10 parts of diphosphonic polyether monomer, 3 to 6 parts of temperature-sensitive dynamic crosslinking monomer and 2 to 5 parts of amide-ether bond grafting monomer. The water reducer has the comprehensive performance of dispersion, slump loss resistance, mud resistance, high-temperature response and the like.

The invention relates to polymer nanoparticle and DNA nanostructure delivery compositions for non-viral delivery, and methods therefor. More particularly, the invention relates to polymer nanoparticle delivery compositions, such as reversible addition-fragmentation chain transfer (RAFT) polymer compositions, and DNA nanostructure delivery compositions, such as DNA origami compositions, for the delivery of more than one payload, or for the delivery of a nucleic acid construct payload of 3 kB or more, and methods therefor.

The invention relates to the technical field of admixtures for cement concrete, in particular to a polycarboxylic acid admixture for enhancing low-activity admixtures and a preparation method thereof, the polycarboxylic acid admixture is formed by polymerizing the following components: polyether macromonomer, unsaturated carboxylic acid I, exciting functional monomer A, slump retaining functional monomer B, rheological functional monomer C, oxidizing agent, reducing agent, chain transfer agent and water; the exciting functional monomer A, the slump retaining functional monomer B and the rheological functional monomer C are sequentially added, and the exciting functional monomer A is formed by polymerizing polyhydric alcohol, unsaturated carboxylic acid II, an initiator, phosphonic acid and an alcohol amine small monomer. Through molecular design, key functional groups such as phosphonic acid groups, amino groups and sulfonic acid groups are innovatively introduced into a polycarboxylic acid main chain, so that the polycarboxylic acid admixture has multiple synergistic functions of reducing the cement consumption, effectively activating a low-activity cementing material, stably improving the working performance of concrete and the like.

The invention relates to the technical field of concrete admixtures, in particular to a viscosity reduction type polycarboxylate superplasticizer and a preparation method thereof. The viscosity reduction type polycarboxylate superplasticizer is formed by polymerizing a comonomer under the action of an oxidizing agent, a reducing agent and a chain transfer agent, the comonomer comprises methoxyallyl polyoxyethylene ether, an air-entraining functional monomer, a viscosity-reducing functional monomer, a silicon-containing functional monomer, unsaturated acid and ferrous sulfate. The polycarboxylate superplasticizer provided by the invention can effectively reduce the viscosity of concrete, so that a concrete mixture has good flowability, workability and wrapping property, meanwhile, the strength of the concrete is not influenced as far as possible, the strength of the concrete is kept at a good level, and the concrete keeps good constructability. Moreover, when the viscosity-reducing polycarboxylate superplasticizer is prepared, the reaction can be completed at the normal pressure of 20-25 DEG C, the preparation steps are simple, the reaction condition is mild, no toxic gas is released, energy can be effectively saved, and the viscosity-reducing polycarboxylate superplasticizer meets the green building material standard.

A solvent-type polyacrylate pressure-sensitive adhesive having a high solid content, a preparation method therefor, and the use thereof. The pressure-sensitive adhesive contains an acrylic resin polymer, the acrylic resin polymer being formed by polymerizing monomers under the actions of an initiator and a chain transfer agent in an organic solvent, the solid content of the acrylic resin polymer being 60-75%, the mass-average molecular mass of the acrylic resin polymer being 0.2-0.4 million, and the polydispersity of same being 1-1.3. The pressure-sensitive adhesive keeps excellent mechanical properties in the case of the ultra-high solid content, 180° peeling strength being 10-20 N / 25 mm, tack being > 2# ball, and holding power being > 72 hours.

The invention provides a retarding type polycarboxylate superplasticizer as well as a preparation method and application thereof, and belongs to the technical field of building material concrete admixtures. The retarding type polycarboxylic acid water reducing agent is prepared from the following raw materials in parts by weight: 300 to 400 parts of polyether macromonomer, 60 to 150 parts of unsaturated carboxylic acid micromonomer, 30 to 60 parts of unsaturated sulfonic acid monomer, 15 to 30 parts of alkylphenol polyoxyethylene ether phosphate, 1.5 to 12 parts of chain transfer agent, 2 to 15 parts of initiator, 15 to 50 parts of caustic soda liquid and 200 to 600 parts of solvent. The polycarboxylic acid water reducing agent product with the retarding characteristic is synthesized through an RAFT method, the binding force between phosphate radicals and calcium ions in a cement pore liquid of the preparation raw material alkylphenol polyoxyethylene ether phosphate is high, hydration of C3A and formation of ettringite are delayed, the retarding effect of the water reducing agent is enhanced, and the polycarboxylic acid water reducing agent has the anion characteristic and the nonionic characteristic and can be used as a water reducing agent. And the workability of the concrete is improved.

The invention relates to the technical field of water-soluble polymers, in particular to a preparation method of a low-temperature-resistant water-in-water emulsion, which comprises the following steps: mixing acrylamide, an anionic monomer, a hydrophobic monomer, a dispersing agent, a chain transfer agent and water, adjusting the pH value, mixing with a stabilizer, introducing nitrogen, sequentially adding an oxidizing agent and a reducing agent to initiate a polymerization reaction, and cooling to obtain the low-temperature-resistant water-in-water emulsion. Quickly adjusting the stirring speed when the viscosity of the mixed system is increased, always keeping vortex at the center of the liquid level in the reaction process, and adjusting the stirring speed to continue the reaction after the polymerization system forms emulsion drops; and when the temperature of the polymerization system begins to reduce, adding an excessive amount of a reducing agent into the reaction system to continue the reaction, and obtaining the low-temperature-resistant water-in-water emulsion after the reaction is finished. The emulsion has the advantages of low apparent viscosity, high dissolution speed, small environmental damage, low temperature resistance and the like.

The invention belongs to the technical field of fluorine chemical high-purity polymer synthesis, and particularly relates to high-purity polyvinylidene fluoride resin and a preparation method and application thereof.The preparation method comprises the following steps that ultrapure water and a reactive emulsifier are added into a reaction kettle, and vacuumizing and deoxygenization are conducted till the oxygen content is smaller than or equal to 20 ppm; the preparation method comprises the following steps: heating a reaction kettle to 60-100 DEG C, introducing vinylidene fluoride until the kettle pressure is 2.0-3.0 MPa, stirring, adding an inorganic peroxide initiator, starting a polymerization reaction, after reacting for 10-20 minutes, supplementing the inorganic peroxide initiator at a constant speed, and simultaneously adding a low-boiling-point chain transfer agent at a constant speed; keeping the kettle temperature and the kettle pressure constant, and stopping the reaction when the monomer reaction dose reaches a preset weight; unreacted monomers are recycled, polyvinylidene fluoride emulsion prepared through the reaction is put into washing, drying and pelleting integrated aftertreatment equipment to be treated, and the high-purity polyvinylidene fluoride resin is obtained. The anion content, the metal ion content and the TOC content of the prepared high-purity polyvinylidene fluoride resin all meet the SEMI F57 standard requirements.

The disclosure relates to block copolymer nanoparticles for therapeutic delivery of nucleotides, and methods therefor. More particularly, the invention relates to polymer nanoparticles, such as reversible addition-fragmentation chain transfer (RAFT) polymer compositions, for delivering miRNAs.

The invention discloses chain end modified liquid rubber, mixed rubber, a preparation process, a tire and a vehicle, and belongs to the technical field of liquid rubber and manufacturing thereof. According to the liquid rubber, butadiene monomers and a chain transfer agent are added in batches in the preparation process, negative ion active centers are frequently transferred to the chain transfer agent from the tail end of a polybutadiene-based lithium active chain to form new initiation growth centers, then newly introduced butadiene monomers are initiated to grow, the dosage of an n-butyllithium initiator is remarkably reduced, and the stability of the liquid rubber is improved. The production cost is greatly reduced, the generation of sewage is greatly avoided, the monomer concentration of the final rubber product can reach about 80 percent by weight, the productivity is improved, and large-scale production is facilitated; the rubber also enables the filler to have good dispersibility, and has good compatibility with base rubber such as styrene butadiene rubber, natural rubber and the like.

The application provides a solid waste-based high-fluidity filling material and a preparation method thereof. The solid waste-based filling material comprises 40-60 parts of Bayer red mud, 40-60 parts of fly ash, 10-20 parts of desulfurization gypsum, 3-5 parts of a pumping agent, 30-60 parts of water, and the pumping agent is a compounded product of an organic silicon polycarboxylic acid water reducing agent, a polymaleic acid and a water-soluble cellulose at a mass ratio of 3-5:3-5:10. The organic silicon polycarboxylic acid water reducing agent is copolymerized from an unsaturated carboxylic acid monomer, a polyethylene glycol monoallyl ether and an unsaturated silane monomer at a mass ratio of 1.5-2:2-4:0.8-1 in the presence of a chain transfer agent. The silane monomer forms a hydrophobic region, and through the balance of the hydrophilic and hydrophobic region structure, the electrostatic repulsion between the solid waste gel particles with the water reducing agent adsorbed on the surface is enhanced, the occurrence of the solid waste gel particles wrapping the water reducing agent is prevented, and the slurry fluidity and the filling material strength are improved.