The invention relates to a preparation method of a superconductive, thermally-conductive, ultrahigh-strength graphene composite film, which comprises the following steps: step 1, mixing 10%-80% by mass of nanometer graphene and 20%-90% by mass of liquid or powdery bridging carbon groups in a nitrogen-filling mixer at room temperature for 1-10 hours; step 2, pumping the mixed materials into a heating box by a vacuum pump, heating the materials to 100-500 DEG C for 1-20 hours; step 3, after heating, allowing the mixed materials to fall freely into a material distribution zone, uniformly spreading out the mixed materials by a scraper and a material-distributing roller, feeding the materials into a pre-press roller with a controlled pressure of 0.1-1.0 Mpa, pressing the materials tightly with several groups of press rollers so as to pull out a composite film with a thickness less than 100 microns; step 4, scanning the composite film line by line through a laser beam, an electron beam or an ion beam to allow the temperature of the scanned part of the composite film to be above 3000 DEG C so as to realize carbonization, graphitization, crystal growth, and the perfect combination of the molecular skeleton of nanometer graphene and the molecular skeleton of the bridging carbon groups; step 5, trimming the scanned composite film and rolling up. The invention has simple and compact steps, and can realize production with high efficiency by one continuous apparatus.