The invention relates to a system for simultaneous desulfurization-denitrification-demercuration based on a combination of free radical pre-oxidation and wet absorption. The system adopts the structure that ultraviolet light and a catalyst are combined to decompose a peroxide; during decomposition, strong oxidative hydroxy or sulfate radical free radical are generated for oxidative removal of SO2, NOx and Hg0 in an impact bed; part of flue gas from an emission source and part of catalyst particles are mixed and sprayed into the impact bed through high-speed nozzles, and the other part of flue gas and catalyst particle are mixed and sprayed into the impact bed through the high-speed nozzles which are coaxially arranged in an opposite manner; meanwhile, a peroxide solution is sprayed into the impact bed through sprayers, so that such three gas steams are subjected to impact and mixing in the impact bed. The system has the advantages that the ultraviolet light and the catalyst are combined to decompose the peroxide, strong oxidative hydroxy or sulfate radical free radical are generated for oxidation of SO2, NOx and Hg0, so that gas-sate divalent mercury, nitrogen dioxide, sulfur trioxide, sulfuric acid and nitric acid are generated, and then SO2, NOx and Hg0 are removed in a wet desulfurization system at the tail part. Therefore, the system provided by the invention can be used for transforming the conventional coal burning boiler to achieve sulfur-nitrogen-mercury integrated removal, and has a broad market application prospect.