4106 results about "Ethyl fumarate" patented technology

Methods and systems for the production of ethyl acetate are described herein. The methods and systems incorporate the novel use of a high shear device to promote dispersion and mixing of a carbonyl co-reactant (e.g. acetic acid, acetaldehyde) with ethanol. The high shear device may allow for lower reaction temperatures and pressures and may also reduce reaction time with existing catalysts.

A process for hydrogenating acetic acid to form of ethyl acetate and mixtures of ethyl acetate and ethanol. The hydrogenation is done in the presence of catalyst, preferably on a support that optionally includes a support modifier.

Certain applicator liquids and application techniques are described, which can be used to form nanotube films or fabrics of controlled properties. An applicator liquid for preparation of a nanotube film or fabric includes a controlled concentration of nanotubes dispersed in ethyl lactate. The controlled concentration is sufficient to form a nanotube fabric or film of preselected density and uniformity.

The invention provides a preparation method of triazine structure containing benzoxazine intermediate, which sequentially includes: (1) performing synthetic reaction of aldehyde compound and amine compound at a molar ratio of at least 1:1 which includes adding aldehyde compound and solvent of at least one of clean water, methanol, ethanol, isopropanol, and ethyl acetate into a reactor at the room temperature under the normal pressure to obtain mixed solution with aldehyde mass concentration of no greater than 95%, adding amine compound while stirring, and reacting at 0-100 DEG C under the normal pressure for at least 15 minutes to obtain the reactant liquor; (2) pouring into the cleaning solution, stirring and cleaning, and filtering to collect solid substance, or directly filtering the reactant liquor to collect the solid substance; and (3) drying the solid substance obtained in step (2) at 30-100 DEG C.

The invention relates to two synthetic methods of 3,6-bis(4-bisfumaroyl aminobutyl)-2,5-diketopiperazine and a salt substitute thereof. The first synthetic method comprises the following steps of: obtaining a final product through the steps of cyclodehydration, hydrogenation, coupling, saponification, recrystallization and the like by using epsilon-benzoyloxycarbonyl-L-lysine and p-nitryl monoethyl fumarate as starting materials. The second synthetic method comprises the following steps of: obtaining the final product through the steps of cyclodehydration, coupling, saponification, recrystallization and the like by using N-6-trifluoroacetyl-L-lysine and the p-nitryl monoethyl fumarate (or p-nitryl monoethyl fumarate acyl chloride) as the starting materials. Meanwhile, the salt substitute of the 3,6-bis(4-bisfumaroyl aminobutyl)-2,5-diketopiperazine can also be generated by directly carrying out substitution reaction on the 3,6-bis(4-bisfumaroyl aminobutyl)-2,5-diketopiperazine as a reaction product and corresponding salt.

An application of 2-cyno-3-amino-3-ethyl phenylacrylate in preventing and controlling plant diseases and eliminating the petes which are caused by fusarium, uredinale, gray mold, etc. A synergistic agricultural chemical containingsaid compounds is also disclosed.

The invention discloses an extracting polyphenol, theanine, tea polysaccharide and tea pigment method from tea, which is characterized by the following: using deionized water for lixiviating tea at constant temperature with continuous flow upstream at multi-speed; adopting microstrainer to dislodge the foreign matter of raffinate; using hyperfiltration for putting-off pectin and protein; concentrating by hyperfiltration and dehydration; extracting tea polyphenol by acetic acid ethyl ester and recovering dissolvant; stripping caffeine of extracting extract phase, pesticide residue and dissolvant by CO2 supercritical fluid; getting tea polyphenol by low-temperature nitrogen spray-drying; using alcohol separation and low temperation vacuum drying by hyperfiltration trapped fluid to prepare tea polysaccharide; separating alcohol recrystallization by basic copper carbonate and hydrogen sulfide to get theanine; using enzymatic oxidation and alkaline air to oxygenate remain polyphenols substance of liquid phantom; getting tea pigment by hyperfiltration dehydration compression and vacuum drying; merging caffeine form carbon dioxide above-critical fluid and caffeine from carrene; recovering dissolvent; using deionized water for washing; obtaining caffeine by recrystallization vacuum drying.

The LixMn2O4 powder for cathode active material of a lithium secondary battery of the present invention is prepared by a method of comprising the steps of mixing an acetate aqueous solution using Li acetate and Mn acetate as metal precursors, and a chelating agent aqueous solution using PVB, GA, PAA or GC as a chelating agent; heating the mixed solution at 70 DIFFERENCE 90 DEG C. to form a sol; further heating the sol at 70 DIFFERENCE 90 DEG C. to form a gel precursor; calcining the produced gel precursor at 200 DIFFERENCE 900 DEG C. for 5 DIFFERENCE 30 hours under atmosphere. The cathode active material, LixMn2O4 powder for a lithium secondary battery in accordance with the present invention has a uniform particle size distribution, a high crystallinity and a pure spinel-phase, and a particle size, a specific surface area, a lattice of a cubic structure and the like can be controlled upon the preparing conditions. The present invention also provides a method of preparing LiNi1-xCoxO2 powder, which comprises the steps of providing a gel precursor using PAA as a chelating agent and hydroxide, nitrate or acetate of Li, Co and Ni as metal precursors; heating the gel precursor at 200 DIFFERENCE 900 DEG C. for 5 DIFFERENCE 30 hours to form a powder. The LixMn2O4 and LiNi1-xCoxO2 powder of the present invention can be used for a cathode active material of a lithium secondary battery such as a lithium ion battery or lithium polymer battery.

The invention discloses a Gemini quaternary ammonium salt cationic surfactant with sterilization effect. The preparation method of the Gemini quaternary ammonium salt cationic surfactant disclosed by the invention relates to that a dihalide and a fatty amine are reacted in an organic solvent, i.e. a dibromo-matter and an alkyl tertiary amine perform chemical reaction in an ethanol (or acetone or ethyl acetate) solution at the room temperature or at a low temperature and normal pressure condition, so as to synthesize a series of Gemini quaternary ammonium salt cationic surfactants. The method for synthesizing the Gemini quaternary ammonium salt cationic surfactant is simple and convenient, stable in reaction process, easy for operating and controlling with a higher product purity and yield; besides, compared with the novel geramine, the method has better sterilization effect and has important application in the aspect of oil field germicide at the same time.

The invention discloses a method for preparing an anode composite material for lithium sulfur secondary batteries, which comprises the following steps: 1) hydrolyzing ethyl orthosilicate to obtain nano SiO2 spheres; 2) mixing solution of a carbon source with the nano SiO2 spheres and heating the mixture to react the solution of the carbon source with the nano SiO2 spheres; 3) cooling, centrifuging, drying, calcining and carbonizing the product obtained by the previous step to obtain a SiO2-C core-shell structure material; 4) etching the SiO2-C core-shell structure material by using solution of HF, NaOH or KOH to obtain a hollow carbon sphere material; and 5) grinding and mixing sulfur and the hollow carbon sphere material, placing the mixture in a sealed container filled with an Ar gas, heating the mixture and casting the melt to obtain a S-C composite material. The method has the advantages that: 1) the process is simple; 2) the raw material is cheap and readily available and the production cost is low; and 3) the composite material has a special core-shell structure and therefore inhibits the loss of active materials, improves the conductive performance of the material and obviously improves the electrochemical performance of electrodes.

The invention relates to an ionic liquid based method for extracting lignin by a two-liquid-phase system, comprising the following steps of: 1, preparing a mixed solution of 40%-80% of imidazole salt ionic liquid and 20%-60% of organic solvents, and adding 0.5%-2% of deionized watert; 2, adding the mixed solution, a lignin-containing solid plant material or a plant material ramification into a reaction kettle, conducting oil bath for 0.5-3 hours under 403-443 K and 0.1-10 MPa, and then obtaining filter liquor and a filter cake; 3, adding 4-6 multiplied deionized water into the filter liquor, and separating rough lignin out; 4, purifying by a soxhlet extraction method, wherein the organic solvents are ethylacetate, dioxane and ethanol or methanol. The invention obtains lignin products, andreaction residuals can still be continuously used in slurrying process of the paper manufacturing industry; in addition, the invention has the advantages of high extraction rate of the lignin, solvent recycling, easy operation and low cost.

The invention discloses a method for transforming fatty acid ethyl ester into glyceride, which comprises the following steps of: mixing the fatty acid ethyl ester and glycerol in a material tank; making the material pass through a glycerol separator by using a pump to separate free glycerin; then putting the material in a reactor in which immobilized lipase is filled; and making the material passthrough a packed tower to remove ethanol; making the material finally flow back to the material tank for performing 6 to 300h circular reaction; then carrying out molecular distillation on the reaction product to remove the unconverted reactant so as to obtain glyceride products. The method can improve the stability and bioavailability of the products, and has high application value for transforming functional fatty acids such as ethyl ester fish oil, algae oil, conjugated linoleic acid, arachidonic acid and the like into glyceride products.

During the extraction of resveratrol from giant knotwood, giant knotwood glycoside is hydrolyzed and enriched through organic synthesis. The extraction process includes mixing giant knotwood raw material and composite stuffing, high pressure chromatography in a high-pressure chromatographic column apparatus, gradient elution with chloroform and ethyl acetate and thin chromatographic tracking detection. The said process can reach a kilogram level yield and high product purity. The present invention may be used in extracting resveratrol and other similar product from giant knotwood material.

The subject invention relates to a skin cream that can be used to moisturize and rejuvenate skin that has been damaged by exposure to sunlight or which has simply been affected over the years by intrinsic aging. It can also be used to slow the rate of photo-induced aging to maintain beautiful skin tone and texture over the years. It inhibits the formation of wrinkles and in some cases reduces the depth of existing wrinkles or eliminates them entirely. In some cases, the skin cream of this invention also lightens age spots and other types of blemishes associated with aging. This invention is based upon the discovery that alkyl lactates, such as ethyl lactate, can be used to improve the penetration of active ingredients in skin care formulations deep into lower layers of the skin tissue. For instance, ethyl lactate can be included in aqueous based skin creams, such as oil in water emulsions, to deliver active ingredients deep into the skin structure. Ethyl lactate is particularly desirable for utilization in conjunction with ascorbic acid (Vitamin C) containing skin cream formulations. This is beneficial because the overall effectiveness of skin creams that utilize ascorbic acid as an active ingredient is contingent upon delivery of the ascorbic acid through the outer layers of the stratum corneum and viable epidermis and into the dermis layer of the skin structure. The present invention more specifically discloses a topical formulation comprising about 1 weight percent to about 20 weight percent ascorbic acid, about 1 weight percent to about 10 weight percent of an amino acid selected from the group consisting of phenylalanine and tyrosine, about 0.5 weight percent to about 5 weight percent of a non-toxic zinc salt, about 0.01 weight percent to about 20 weight percent of an alkyl lactate, wherein the alkyl group in the alkyl lactate contains from 2 to about 12 carbon atoms, and a pharmaceutically acceptable carrier.

Catalysts and processes for making catalysts suitable for use in processes for hydrogenating acetic acid to form of ethyl acetate and mixtures of ethyl acetate and ethanol. In a first embodiment, the catalyst includes a high loading of nickel, palladium or platinum. In a second embodiment, the catalyst comprises a first metal selected from nickel and palladium and a second metal selected from tin and zinc. In a third embodiment, the catalyst comprises one or more metals on a support that has been modified with an acidic support modifier or a redox support modifier.

An extract of mulberry twigs is dislcosed, which can be used to prepare the food or the medicine to cure hyperuricemia and gout diseases. The said extract is prepared from mulberry twigs through extracting in solvent (aqueous solution of alcohol, chloroform, acetone, etc) at 10-100 deg.C more than one time, mergint the liquid extracts, recovering solvent, regulating pH value to 7.5-9.5, centrifugal separation to obtain supernatant, regulating pH value to 4-6, deposition, water washing wand drying. Several other approaches for purifying it are also disclosed.

The invention relates to a method for extracting chlorogenic acid, which belongs to the technical field of pharmaceutical chemicals. The method combines macroporous resin enrichment, ethyl acetate extraction and a mixed solvent split-phase method to achieve multi-step gradient purification of the chlorogenic acid so as to obtain a chlorogenic acid product with high purity. The method comprises the processes of water extraction, column passing, extraction, phase splitting and recrystallization. The macroporous resin adopted by the column passing process is 306 type or XAD series resin; and the split-phase agent adopted by the split-phase method is petroleum ether, chloroform or the mixture of the petroleum ether and the chloroform. The method is applicable to the process of extracting and preparing the chlorogenic acid from honeysuckles, cortex eucommiae leaves and cortex eucommiae barks.

Recovery of ethanol from a crude ethanol product obtained from the hydrogenation of acetic acid and by reacting a portion of the crude ethanol product or one or more derivative streams containing ethyl acetate obtained therefrom in the presence of hydrogen, via hydrogenolysis. The one or more derivative streams comprise ethyl acetate that are reacted in via hydrogenolysis form additional ethanol that may be directly or indirectly fed to the separation zone or the hydrogenation reactor.

The present invention relates to the extraction and separation of fucoxanthin, and is especially the process of separating fucoxanthin from algae. The process of separating fucoxanthin from algae includes the following steps: cleaning fresh algae or defrozen algae to eliminate surface salt ion, eliminating surface water, leaching algae with dimethyl sulfoxide in 2-6 ml for each gram of algae in dark for 15-60 min, and final extracting coloring matter from dimethyl sulfoxide leached liquid with the mixture solution of ethyl acetate and ammonium sulfate. The present invention has the advantages of simple operation, high separation speed and high yield, and is suitable for industrial production.