3501 results about "Pyrrolidinones" patented technology

The invention provides a nitrification inhibitor and a preparation method thereof as well as stable urea and a preparation method thereof, and relates to the technical field of fertilizers. The nitrification inhibitor provided by the invention is prepared from the following components in percentage by mass: 20 to 45 percent of 3, 4-dimethyl pyrazole phosphate (DMPP), 30 to 70 percent of amino acid and the balance of auxiliaries, the auxiliary agent is one or more of polysaccharide, polyvinylpyrrolidone, poloxamer and carbomer. According to the invention, the DMPP and the amino acid are compounded, the amino acid is used as a stabilizer of the DMPP, so that the stability of the DMPP can be remarkably improved, and meanwhile, the polymer additive is used as an adhesive, so that the stability of the DMPP can be further improved. The nitrification inhibitor provided by the invention has excellent stability; the stable urea can be obtained by adopting an endogenous adding mode and adding the stable urea into the urea with relatively low loss, and the stable urea has multiple effects of improving the urea utilization rate, improving the crop quality, improving the soil biological environment, improving the soil fertility and the like.

The invention discloses high-thermal-conductivity carbon black and a preparation method and application thereof, and relates to the technical field of carbon black modification.The preparation method of the high-thermal-conductivity carbon black comprises the following steps that carbon black is subjected to oxidation treatment, silanization treatment and tannic acid coating treatment, and modified carbon black is obtained; preparing a graphene / boron nitride / modified carbon black multi-dimensional filler; carrying out primary modification on the graphene / boron nitride / modified carbon black multi-dimensional filler by adopting lignin, polyvinylpyrrolidone and samarium chloride, and then carrying out secondary modification by adopting 6-aminocaproic acid to obtain the high-thermal-conductivity carbon black. The high-thermal-conductivity carbon black prepared by the invention not only has good dispersity, but also can well improve the thermal conductivity and mechanical properties of a rubber matrix.

The invention discloses a temperature / CO2 dual-response zwitterionic hydrogel profile control agent, which is prepared by taking a monomer A, a monomer B and a monomer C as raw materials, adding a cross-linking agent and an initiator, and carrying out polymerization reaction in a water medium. The monomer A is selected from any one of acrylamide, acrylic acid and 1-vinyl-2-pyrrolidone; the monomer B is selected from any one of [2-(methacryloyloxy) ethyl] dimethyl-(3-sulfopropyl) ammonium hydroxide, 2-methacryloyloxyethyl phosphorylcholine and 3-((2-(methacryloyloxy) ethyl) dimethylamino) propionic acid inner salt; and the monomer C is selected from any one of 2-(dimethylamino) ethyl methacrylate, dimethylamino propyl methacrylamide and polyethyleneimine. The profile control agent has double swelling mechanisms, has outstanding temperature and salt resistance, resists 220000 mg / L of mineralization water, is suitable for high-salt reservoirs, and is good in long-term aging property.

The invention relates to hydrogel loaded with oxygen self-producing nanoparticles as well as a preparation method and application of the hydrogel. The preparation method comprises the following steps: 1, taking cross-linked methacrylamide silk fibroin and hyaluronic acid modified by arginine-glycine-aspartic acid peptide as base materials, and loading self-oxygen-producing nano particles CaO2 (at) PVP (at) Cu-EGCG, and the self-oxygen-producing nano particles CaO2 (at) PVP (at) Cu-EGCG are prepared by coating Cu-EGCG on calcium peroxide nano particles modified by PVP modified polyvinylpyrrolidone. The hydrogel can improve energy metabolism and regulate immune environment through dual mechanisms, realizes efficient promotion of myocardial repair, and provides a new strategy and thought for tissue regeneration and functional recovery after myocardial infarction.

The invention belongs to the technical field of phase-change ceramic fiber aerogel, and discloses high-temperature phase-change heat-insulation ceramic fiber aerogel and a preparation method thereof.The preparation method comprises the steps that polycarbosilane and polyvinylpyrrolidone are added into an organic solvent to be mixed and stirred till the polycarbosilane and the polyvinylpyrrolidone are completely dissolved, and a precursor solution is obtained; dispersing a high-temperature phase change microcapsule into the precursor solution, and stirring until the high-temperature phase change microcapsule is uniformly dispersed to obtain a spinning solution; a ceramic precursor fiber membrane is obtained through electrostatic spinning, and the high-temperature phase-change heat-insulation ceramic fiber aerogel is obtained through cross-linking curing and sintering. The thermal conductivity of the high-temperature phase-change heat-insulation ceramic fiber aerogel is adjustable between 0.03 W / (m.k) and 0.05 W / (m.k), the phase-change temperature ranges from 550 DEG C to 600 DEG C, and the phase-change enthalpy value ranges from 400 J / g to 500 J / g. Compared with traditional ceramic aerogel, the aerogel can regulate and control the environment temperature, is more resistant to high temperature and safer, and has wide application in the field of high-temperature heat insulation of aviation power batteries.

The invention discloses an oxygen-sulfur double-vacancy modified SnO2 / SnS2 / C nano material as well as a preparation method and application thereof, and belongs to the technical field of electrode materials. The preparation method comprises the following steps: mixing a structure regulating agent with tin salt, dropwise adding alkali liquor, stirring, and carrying out suction filtration to obtain Sn6O4 (OH) 4; the preparation method comprises the following steps: adding glucose and polyvinylpyrrolidone into distilled water, stirring to form a uniform solution, adding Sn6O4 (OH) 4 into the uniform solution, stirring, and carrying out ultrasonic and hydrothermal reaction to obtain SnO2 / glucose; and calcining the SnO2 / glucose and a sulfur source in an inert atmosphere to obtain the SnO2 / SnS2 / C nano material modified by oxygen and sulfur double vacancies. The SnO2 / SnS2 / C disclosed by the invention is used for a lithium / sodium ion battery negative electrode, can effectively relieve volume expansion of tin-based oxysulfide and improve the conductivity of an electrode material, and shows high charge-discharge specific capacity, excellent rate capability and high-rate long-cycle stability.

The invention discloses a polyion liquid / polyvinylidene fluoride-hexafluoropropylene-based solid electrolyte with a microscopic liquid phase and a preparation method and application thereof, and the preparation method comprises the following steps: adding a lithium salt into N-methyl-2-pyrrolidone, and stirring until the lithium salt is completely dissolved; then adding imidazolyl polyion liquid to prepare a solution A; adding polyvinylidene fluoride-hexafluoropropylene into N-methyl-2-pyrrolidone to prepare a solution, adding the solution into the solution A, continuously stirring until the solution is fully dissolved to obtain a precursor solution of the solid electrolyte, casting the precursor solution onto a polytetrafluoroethylene mold, and carrying out vacuum drying to obtain the solid electrolyte. And the polyvinylidene fluoride-hexafluoropropylene polymer-based solid electrolyte added with the imidazolyl polyion liquid is prepared by adding the imidazolyl polyion liquid into the polyvinylidene fluoride-hexafluoropropylene polymer-based solid electrolyte. The polymer-based solid electrolyte with a microscopic liquid phase is obtained through an electrolyte preparation process which is mild in condition, simple to operate and easy for large-scale production, and the solid electrolyte has good conductivity and mechanical properties.

The invention discloses an antibacterial drug delivery system based on a dynamic response type microneedle patch and a preparation method, and belongs to the field of biomedical materials.The antibacterial drug delivery system comprises a substrate layer and a needle point layer arranged on the surface of the substrate layer, the substrate layer is a mixed matrix of polyvinyl alcohol (PVA) and polyvinylpyrrolidone (PVP), and the needle point layer is made of nano-silver; the needle tip layer is a phenylboronic acid modified oxidized hyaluronic acid and polyvinyl alcohol composite system. The antibacterial drug delivery system based on the dynamic response type microneedle patch, namely the microneedle patch with the pH response drug release function, is suitable for antibacterial treatment of infectious wounds, the mechanical strength of the needle point layer is improved, it can be better guaranteed that a microneedle completely penetrates into the skin, and the delivery efficiency is improved; meanwhile, drug release can be responded according to the pH of a bacterial infection part, and the antibacterial effect is good.

The invention relates to the technical field of conductive materials, in particular to a high-concentration dispersion system and a preparation method thereof. The high-concentration dispersion system comprises a conductive agent, a dispersing agent, a solvent and a viscosity reduction auxiliary agent, the conductive agent is modified carbon nanotubes, the dispersing agent is modified polyvinylpyrrolidone, the solvent is N-methyl pyrrolidone or deionized water, and the viscosity reduction auxiliary agent is piperazine anhydrous; wherein the modified carbon nano tube is obtained by mixing and heating a carbon nano tube and a mixed acid solution of nitric acid and sulfuric acid, then cooling, filtering, washing, drying, then dispersing in 75% ethanol, and finally adding 3-[3-carboxyl allylamido] propyltriethoxysilane for modification; the modified polyvinylpyrrolidone is obtained by heating polyvinylpyrrolidone at 310-330 DEG C and then oxidizing the polyvinylpyrrolidone. The conductive agent content of the high-concentration dispersion system is high, the conductive agent accounts for 15%-20% of the high-concentration dispersion system by mass, and the high-concentration dispersion system is low in viscosity, high in dispersity and good in conductivity.

The invention provides a diaphragm and a preparation method thereof and a lithium ion battery, the diaphragm comprises a base membrane layer and a composite functional layer, the composite functional layer comprises hydrophobic SiO2 aerogel modified by a hydrophobic agent, a conductive ion polymer and a solid electrolyte, and the composite functional layer respectively accounts for 3-12wt%, 0.5-1.0 wt% and 0.5-1.5 wt% of the total mass of the diaphragm; the hydrophobic agent comprises trimethylchlorosilane, hexamethyldisilazane, perfluorooctyltriethoxysilane, polyvinylidene fluoride, polydimethylsiloxane and the like, the conductive ionic polymer comprises polyvinylpyrrolidone, lithium polymethacrylate, lithium polystyrene sulfonate, polyacrylamide and the like, and the solid electrolyte comprises lithium lanthanum titanium oxide, lithium lanthanum zirconium oxide, lithium lanthanum zirconium tantalum oxide and the like. The wettability is improved by the high porosity of the hydrophobic SiO2 aerogel, the stability and strong conductivity of a physical conductive network of the solid electrolyte and the ion affinity and amphoteric binding capacity of the conductive ion polymer are optimized, the electrochemical performance and thermal stability of the interface are optimized, and comprehensive optimization of the thermal-electric-interface performance of the diaphragm is realized through combination.

The invention relates to the field of coating materials, and provides an antiskid coating based on carbon fibers and a preparation method thereof. The coating is composed of a component A and a component B, the component A comprises KH-570 silane coupling agent surface modified carbon fibers, dog bone-shaped nano silicon dioxide, epoxy modified hydroxy acrylic resin, quartz sand antiskid aggregate, propylene glycol methyl ether acetate, iron oxide pigment and other auxiliaries, and the component B is an HDI tripolymer curing agent. The surface modified carbon fiber is prepared through the steps of cleaning and activating, silane coupling agent dipping, drying and curing and the like, and the dog bone-shaped nano silicon dioxide is prepared through a sol-gel method with hexadecyl trimethyl ammonium bromide and polyvinylpyrrolidone as morphology guiding agents. The preparation method comprises the steps of iron oxide color paste preparation, functional component dispersion, quartz sand addition, curing treatment, double-component mixing and curing and the like. The coating has excellent dry skid resistance, wet skid resistance, wear resistance and durability, and is suitable for the field of ground skid resistance coating.

The invention relates to bionic skin barrier cream with a three-layer phospholipid structure and a preparation method of the bionic skin barrier cream, and belongs to the technical field of cosmetics, the bionic skin barrier cream comprises the following raw materials: lecithin, wax ester, triglyceride, composite ceramide, phytosterol oleate, squalane, an antioxidant, polyol, composite amino acid, pyrrolidone carboxylic acid, urea and arginine. A stabilizing agent, a treating agent and the balance of deionized water. The bionic skin barrier cream prepared by the invention has a three-layer phospholipid structure, and compared with a double-layer phospholipid structure in the market, the firmness and hydrophobicity of the double-layer structure are further improved by the added third-layer structure, so that the prepared bionic skin barrier cream has outstanding waterproof, sweat-resistant and light pollution-resistant effects; in addition, the wax ester, the triglyceride, the phytosterol oleate, the pyrrolidone carboxylic acid and the urea selected in the invention have a synergistic effect, and can generate excellent moisturizing and repairing effects and certain protection effects.

The invention discloses a cerium-modified manganese-based NH3-SCR (Selective Catalytic Reduction) denitration catalyst as well as a preparation method and application thereof. The catalyst is obtained by uniformly mixing and stirring manganous nitrate, cerous nitrate, polyvinylpyrrolidone, citric acid and deionized water, stirring and evaporating to a gel state, drying to form a precursor, and roasting the precursor in an air atmosphere. Ce is used for modifying MnOx, polyvinylpyrrolidone and citric acid are used as a surfactant and a complexing agent in the preparation process of the catalyst, the interaction between Ce and Mn is enhanced, the phase of the catalyst is adjusted, and under the conditions of high NOx concentration (1000 ppm) and high space velocity (GHSV = 120,000 mL h <-1 > g <-1 >), the catalyst can be used for preparing the catalyst, and the catalyst can be used for preparing the catalyst. The catalyst has excellent low-temperature catalytic activity, a wide working temperature window and good reaction stability, and has good water resistance and sulfur dioxide poisoning resistance.

The invention discloses a starch-based full-biodegradable mulching film capable of being rapidly degraded and a preparation method of the starch-based full-biodegradable mulching film, and belongs to the technical field of degradable materials.The preparation method comprises the steps of tea polyphenol calcium salt preparation, filler preparation, thermal plasticization and film preparation. The preparation of the filler comprises the following steps: adding silicon dioxide into a polyacrylic acid aqueous solution, stirring and centrifuging at room temperature, taking a precipitate, adding the precipitate into a polyvinylpyrrolidone aqueous solution, adjusting the pH value to 3-3.5, stirring and centrifuging at room temperature, taking the precipitate, adding the precipitate into the polyacrylic acid aqueous solution, adjusting the pH value to 3-3.5, stirring and centrifuging at room temperature, taking the precipitate, and freeze-drying to obtain the filler. The starch-based full-biodegradable mulching film prepared by the preparation method disclosed by the invention is good in processability, waterproofness and heat resistance and high in mechanical strength, the problem of phase separation does not occur in preparation, the problem of plasticizer precipitation does not easily occur in long-term use, and rapid degradation can be realized.

The invention discloses a bimetal MOFs-loaded electrostatic spinning fiber membrane for oil-water separation and a preparation method thereof, and belongs to the technical field of membrane separation, and the preparation method comprises the following steps: (1) preparing a hydroxyl-modified metal organic framework material MIL-53 (Al)-OH through a solvothermal reaction; (2) preparing an MIL-53 (Fe) precursor solution by using ferric salt, terephthalic acid, polyvinylpyrrolidone and an organic solvent, ultrasonically dispersing MIL-53 (Al)-OH in the MIL-53 (Fe) precursor solution, uniformly mixing, and soaking the electrostatic spinning fiber membrane in the MIL-53 (Fe) precursor solution for 1-3 hours; and (3) transferring the system in the step (2) into a reaction kettle, reacting at 130-150 DEG C for 10-15 hours to enable the bimetallic MOFs to grow on the surface of the electrostatic spinning fiber membrane, washing, and drying to obtain the bimetallic MOFs-loaded electrostatic spinning fiber membrane for oil-water separation. The bimetal MOFs-loaded electrostatic spinning fiber membrane has the advantages of good oil-water separation performance, strong antifouling ability and strong dye degradation ability.

The invention provides a preparation method of a liner-free all-composite pressure vessel. The preparation method comprises the following steps: compounding polyvinyl alcohol, dimethyl sulfoxide and polyvinylpyrrolidone into a core mold adhesive according to a preset proportion; the preparation method comprises the following steps: grading a filler by adopting various glass beads with different mesh numbers and chopped glass fibers according to a specific proportion, and then blending with a core mold adhesive according to a specific proportion to prepare a sand core material; a sand core material is pressed into the pretreated core mold, the surface of the sand core material is scraped to be flat after the sand core material is tamped, and core mold adhesive is coated for mold closing; the closed core mold is placed in a curing oven for curing operation, after curing is completed, natural cooling is conducted, demolding is conducted, and a core mold is obtained; uniformly winding a layer of carbon fibers on the surface of the core mold, and dissolving the core mold in a normal-temperature water area after curing; and continuously winding the carbon fibers by using the carbon fiber body as rigidity attachment until the carbon fibers are completely wound to obtain the liner-free pressure vessel. According to the method, the mechanical behavior requirement of an original core mold is greatly reduced, the dead weight of the core mold can be effectively reduced, and good manufacturability is achieved.

The invention relates to the technical field of hydraulic fracturing exploitation of deep / ultra-deep oil and gas reservoirs, and discloses a gel-coated temporary plugging agent and a preparation method and application thereof.The gel-coated temporary plugging agent comprises a proppant inner core and a degradable gel shell coating the outer surface of the proppant inner core; the degradable gel shell is formed by a gel shell gelling solution, the gel shell gelling solution comprises small-molecule comonomers and a degradable cross-linking agent, and the small-molecule comonomers comprise acrylamide, N, N-dimethylformamide, N, N-dimethylformamide, N, N-dimethylformamide, N, N-dimethylformamide, N, N-dimethylformamide, N, N-dimethylformamide the initiator is one or more of N, N-dimethylacrylamide, acrylic acid, hydroxyethyl acrylate, benzyl acrylate, 2-propyl acrylic acid, 2-acrylamide-2-methylpropanesulfonic acid and N-vinyl pyrrolidone; and the initiator is one or more of N, N-dimethylacrylamide, acrylic acid, hydroxyethyl acrylate, benzyl acrylate, 2-propyl acrylic acid, 2-acrylamide-2-methylpropanesulfonic acid and N-vinyl pyrrolidone. The gel-coated temporary plugging agent can be used for effectively plugging in a fracturing time period at high temperature / ultrahigh temperature, and the flow conductivity of fractured cracks can be enhanced by exposing an internal propping agent after the gel-coated temporary plugging agent is degraded.

The invention provides a traditional Chinese medicine gel patch for treating gouty arthritis and a preparation method thereof. The traditional Chinese medicine gel patch for treating gouty arthritis comprises at least a gel layer loaded with traditional Chinese medicine extracts; the traditional Chinese medicine extracts comprise the following raw materials: coix seed, phellodendron amurense, clematis root, radix scutellariae, atractylodes lancea, radix ophiopogonis, radix scutellariae, acer scutellariae, radix scutellariae, radix aconiti kusnezoffii, radix strychnii, frankincense, myrrh, angelica sinensis, safflower, cyathula root, radix paeoniae rubra, radix smilacis gracile, radix striatae, eucalyptus glomeratae, sophora flavescens, andrographis paniculatae, radix lobeliae, rhizoma coptidis, radix scutellariae, cassia twig, zanthoxylum bungeanum, and borneol; and a matrix of the gel layer comprises the following raw materials in parts by weight: silk fibroin, polyvinyl pyrrolidone, azido-polyethylene glycol-carboxylic acid, 1-ethynylcyclopropylcarboxylic acid, 2,5-dicarboxylic acid-3,4-ethylenedioxythiophene, and glycerol. The traditional Chinese medicine gel plaster of the present invention can achieve good therapeutic effects through percutaneous absorption.

The invention relates to a temperature-resistant and salt-resistant gel for deep plugging and a preparation method thereof. The gel comprises a main agent, a cross-linking agent, a cross-linking promoting agent, a reinforcing agent, a stabilizing agent and water. The main agent is an acrylamide / 2-acrylamide-2-methylpropanesulfonic acid / N-vinyl pyrrolidone (AM / AMPS / NVP) terpolymer, the temperature-resistant and salt-resistant gel for deep plugging control is suitable for oil reservoirs with the temperature of 110-130 DEG C and the formation water mineralization degree of 5 * 10 < 5 >-10 * 10 < 5 > mg / L, the gelling time is controllable within 73-98 hours, the gel strength after gelling is high, the thermal stability is good, and the temperature-resistant and salt-resistant gel for deep plugging control is suitable for the oil reservoirs with the temperature of 110-130 DEG C and the formation water mineralization degree of 5 * 10 < 5 >-10 * 10 < 5 > mg / L. And long-time deep effective plugging of high-temperature and high-salt oil reservoirs can be realized.

The invention discloses a preparation method of a vehicle-mounted OCA optical adhesive, and belongs to the technical field of optical adhesive materials. The vehicle-mounted OCA optical adhesive comprises an optical light release film, an acrylic adhesive layer and an optical heavy release film which are sequentially arranged from top to bottom, the preparation method comprises the following steps: mixing and stirring an acrylic pressure-sensitive adhesive, 2-ethylhexyl acrylate, isobornyl acrylate, acryloylmorpholine, dodecyl ester, N-vinyl pyrrolidone, a bridging agent and a photoinitiator, filtering, and defoaming to obtain an acrylic adhesive; and coating a release film with the obtained acrylic adhesive, and irradiating the release film with a halogen lamp to obtain the vehicle-mounted OCA optical cement. The vehicle-mounted OCA optical adhesive prepared by the invention has better high-temperature-resistant and high-temperature-resistant and high-humidity-resistant effects, is simple in preparation process and is suitable for large-scale production.

The invention discloses a paper-based electrode based on liquid metal assisted laser-induced graphene and a preparation method thereof.The paper-based electrode comprises a substrate layer, a functional layer, a conductive layer and a hydrophobic layer which are sequentially arranged, the substrate layer is made of paper, the functional layer is formed by coating liquid metal nanoparticles, and the conductive layer is formed by coating liquid metal nanoparticles. The conductive layer is an electrode formed by a laser-induced graphene technology, and the hydrophobic layer is a fluid control area formed by wax packaging. According to the invention, paper is used as a substrate, liquid metal is combined with a laser-induced graphene technology, surface modification is carried out through eutectic gallium indium (EGaIn), polyimide (PI) and N-methyl pyrrolidone (NMP) composite slurry, and then a conductive electrode pattern is formed on the surface of the paper substrate by using a laser-induced graphene (LIG) technology. The method has the advantages of simple preparation, low cost, environmental friendliness and the like, and the prepared paper-based electrochemical biosensor has excellent conductivity, mechanical flexibility and electrochemical activity.

A dry eye composition containing hypochlorous acid and a demulcent. The demulcent can be polyvinylpyrrolidoe with a molecular weight of 30-50 kDa. The composition can be applied to the surface of the eye with a dropper device or a spray dispenser. Critically, hypochlorous acid is stable in the dry eye composition and maintains its effectiveness at preventing microbial growth.

The invention relates to the technical field of heat dissipation materials, and discloses a graphite cooling fin of a multi-layer composite structure and a manufacturing process of the graphite cooling fin of the multi-layer composite structure. 15 to 25 parts of artificial graphite powder; 3 to 8 parts of an aniline-p-phenylenediamine copolymer; 2 to 6 parts of antimony oxide nano particles; 2 to 5 parts of urea; 1 to 3 parts of polyvinylpyrrolidone; the preparation method comprises the following steps: carrying out heat treatment on the artificial graphite film, and then carrying out mechanical pulverization; mixing the graphite oxide with an ethanol or water mixed solvent containing ammonia water; mixing the raw materials; performing vacuum defoamation and then coating on a base material; and performing carbonization treatment on the graphene film crude product, and performing lamination calendering treatment to form a final product. According to the technical scheme, the antimony oxide nano particles are adopted to synergistically adjust the heat conductivity, the effect of remarkably improving the transverse heat conductivity of the film body is achieved, the heat conductivity is enhanced, and material embrittlement caused by overfilling is avoided.

The invention provides a grinding fluid, the grinding fluid comprises a base fluid, a grinding material, nano-diamond and a dispersion stabilizer, the base fluid comprises polyether and silicone oil, the grinding material comprises surface modified silicon carbide particles, and the dispersion stabilizer comprises polyethylene glycol stearate and polyvinylpyrrolidone. The surface roughness of a grinding piece can be reduced, the scratch density and microcracks of the surface are reduced, damage of grinding fluid to the grinding piece is reduced or even avoided, and the service life of a cutter can be prolonged. The invention also provides a preparation method of the grinding fluid and a process method using the grinding fluid.

The invention discloses a high-heat-power thermoelectric cell hydrogel for low-grade heat energy collection and a preparation method thereof, and belongs to the technical field of heat energy recovery. The polyacrylamide hydrogel is selected as a substrate of the thermoelectric cell hydrogel, so that a hydrogel internal structure which is easy to regulate and control can be obtained; excellent hydrogel stretchability is obtained by using a cross-linking agent and an initiator with relatively low concentration; potassium ferricyanide and potassium ferrocyanide are used as redox ions to generate a thermoelectric effect, so that stable P-type thermal power is obtained; by using guanidine hydrochloride, the solvation entropy difference between potassium ferricyanide and potassium ferrocyanide is enlarged, and the thermal power of the hydrogel in the thermoelectric cell is greatly improved; sodium pyrrolidone carboxylate is used, so that the concentration of ions in the hydrogel is further improved, the conductivity of the thermoelectric cell hydrogel is improved, meanwhile, a hydrogen bond network between water molecules is destroyed, and the water-retaining property of the thermoelectric cell hydrogel is improved.

The invention belongs to the technical field of chemical analysis and detection, and relates to a method for rapidly detecting sodium ions in cigarette paper by nano-enzyme laccase. According to the method, 2-aminoterephthalic acid, copper nitrate and cerous nitrate are taken as precursors, polyvinylpyrrolidone is taken as a stabilizer, and a solvothermal method is adopted to synthesize the copper-cerium-containing MOF-based nano-enzyme with laccase-like activity, namely Cu / Ce-BDC-NH2 nano-enzyme; cu / Ce-BDC-NH2 nano-enzyme oxidizes 2, 4-dichlorophenol and 4-aminoantipyrine to obtain a red product, the potassium pyroantimonate ligand is adsorbed on the surface of Cu / Ce-BDC-NH2 to inhibit catalytic action, so that laccase-like activity is reduced, Na < + > is introduced to react with potassium pyroantimonate to generate a stable complex, the activity of Cu / Ce-BDC-NH2 laccase is recovered, and the red color of a solution is deepened. The invention establishes a novel colorimetric rapid detection method for sodium ions.

The invention provides ZrB2 / SiC / TiB2 ultrahigh-temperature ceramic and a preparation method thereof, and belongs to the field of ultrahigh-temperature ceramic. The preparation method comprises the following steps: preparing SiC / TiB2 composite particles, modifying and compounding the SiC / TiB2 composite particles, preparing ceramic slurry, forming and calcining. The compounding step comprises the following steps: putting modified SiC / TiB2 composite particles and modified ZrB2 particles into N-methyl pyrrolidone, uniformly stirring, adding 4, 4 '-bismaleimide diphenylmethane, and stirring at 110-115 DEG C for 2.8-3.2 hours to obtain ZrB2 / SiC / TiB2 particles; the ceramic product prepared by the invention is high in interface bonding strength, uniform in internal structure, relatively high in toughness and strength, good in temperature resistance, stable in overall performance and excellent in comprehensive performance.

The invention discloses a sodium ion positive electrode material and a failure re-repairing method thereof.The failure re-repairing method of the sodium ion positive electrode material is used for re-repairing the sodium ion positive electrode material which fails due to exposure to a wet environment and comprises the following steps that S1, the failed sodium ion positive electrode material is washed with absolute ethyl alcohol and then subjected to vacuum drying, and the sodium ion positive electrode material is obtained; the pretreated layered oxygen positive electrode material is obtained; s2, preparing a repairing solvent, wherein the repairing solvent is prepared by dissolving hydrochloric acid modified polyaniline and multi-walled carbon nanotubes in N-methyl pyrrolidone; s3, dissolving the layered oxygen positive electrode material in a repairing solvent, and stirring to obtain a sodium ion positive electrode material to be dried; and S4, carrying out vacuum drying on the sodium ion positive electrode material to be dried, and cooling to obtain the repaired layered oxide positive electrode material. The method can effectively remove moisture and impurities on the surface of the failed material, recover the basic performance, and improve the stability of the repaired material structure, the specific capacity of current discharge and the cycle performance of the material.

The invention discloses a diluent for whole blood lateral immunochromatography detection as well as a preparation method and a detection method thereof, and belongs to the technical field of immunochromatography detection. The diluent solves the technical problems of unsmooth chromatography, background interference, poor stability of detection results and the like caused by red blood cells during direct detection of whole blood samples. The diluent comprises a buffer system, an osmotic pressure regulator glycine, a nonionic surfactant polysorbate, an erythrocyte aggregation inducer polyvinylpyrrolidone, a dynamic viscosity regulator trehalose, a blocking protein, a stabilizer combination L-methionine and L-histidine, and a composite formula of water. Red blood cells are effectively induced to gather and intercept on the sample pad through the synergistic effect of all the components, and meanwhile the stability of the chromatography process and the activity of the detection reagent are maintained. The diluent is mainly used for lateral immunochromatography quantitative detection of markers such as pro-enkephalin, C-reactive protein, cardiac troponin I or N-terminal pro-brain natriuretic peptide in a whole blood sample.

The invention discloses a low-temperature vacuum microwave freeze-dried sinomenine hydrochloride preparation and a preparation method thereof in the technical field of pharmaceutical preparations, and solves the problems of long drying time, high energy consumption and poor product stability in the traditional freeze-drying technology. A vacuum microwave collaborative freeze-drying technology is adopted, microwave internal heating is achieved through a 2.45 GHz magnetron microwave generator and a rectangular waveguide tube under the conditions that the vacuum degree is 20-30 Pa and the plate layer temperature ranges from-40 DEG C to-35 DEG C, the microwave power density in the primary drying stage ranges from 0.3 W / g to 0.5 W / g, the microwave power density in the secondary drying stage ranges from 0.1 W / g to 0.3 W / g, and collaborative control over the microwave power, the vacuum degree, the temperature and the time is achieved in cooperation with a quaternary coupling precise control system. The preparation contains 50 mg of sinomenine hydrochloride, 100 mg of mannitol and 10 mg of sodium carboxymethyl cellulose grafted modified polyvinylpyrrolidone, the residual moisture is controlled to be 0.4-0.6%, the activity retention rate is 94-96%, and the drying time is shortened to 12-16 hours.