5344 results about "Pyrrolidinones" patented technology

The invention relates to the field of electric heating materials, and provides a graphene-based heating coating and a preparation method thereof. The coating is prepared from functionalized graphene, a surface modified bismuth telluride nanobelt, polyaniline, bisphenol A epoxy acrylate, polyurethane acrylate, a dispersing agent, a flatting agent, a silane coupling agent, a defoaming agent and a propylene glycol methyl ether acetate / N-methyl pyrrolidone mixed solvent. The functionalized graphene is obtained by modifying a hyperbranched polyolefin-acryloyl-POSS copolymer, and carrying out ultrasonic stripping, centrifugal separation, gradient washing and vacuum drying; the surface-modified bismuth telluride nanobelt is modified by an amino silane coupling agent, so that the interfacial compatibility is improved. The preparation method comprises the steps of solvent premixing, nanofiller dispersion, ultrasonic homogenization, coupling agent modification, ultraviolet curing and thermocuring. The heating coating provided by the invention has high conductivity, excellent thermal stability and adhesive force, and can be widely applied to heating electric appliances and intelligent temperature control equipment.

A composite ozone catalyst, a preparation method and use thereof. The composite ozone catalyst of the present invention includes a co-carrier mixed with biochar and a silica-alumina-based material, and a metal element and a nitrogen element supported on the co-carrier. The preparation method includes mixing the biochar and the silica-alumina-based material powder and then placing the same in a metal precursor solution for impregnation, adding a polyvinyl pyrrolidone solution to the impregnated material, wet granulating to form a spherical material, and calcining the spherical material to obtain the composite ozone catalyst. The composite ozone catalyst has low production cost, simple preparation processes, good catalytic performance, and strong stability, which can meet the high-efficiency and low-consumption requirements of ozone catalytic oxidation in the advanced treatment of industrial wastewater.

The invention discloses a CO2 trapping absorbent which comprises 20%-50% of proton type ionic liquid, 20%-50% of a phase conversion driving agent and 20%-40% of water, and the phase inversion driving agent is one or a mixture of more of N, N-dimethyl formamide, N-methyl pyrrolidone, pentamethyldiethylenetriamine, tetramethylethylenediamine, tetramethylethylenediamine, tetramethylenediamine, tetramethylethylenediamine and dimethyl piperazine, and the phase inversion driving agent is one or a mixture of more of N, N-dimethyl formamide, N-methyl pyrrolidone, pentamethyldiethylenetriamine, tetramethylethylenediamine, tetramethylethylenediamine and dimethyl piperazine. The absorbent disclosed by the invention has the outstanding advantages of low viscosity, high absorption rate, high regeneration efficiency, high circulation capacity and low regeneration energy consumption, and has a good application prospect.

The invention relates to a preparation method and application of an inner-rigid outer-soft core-shell structure silicon dioxide blocking agent for marine drilling fluid, and belongs to the field of deepwater oil and gas drilling. N-vinyl-2-pyrrolidone, dimethyl diallyl ammonium chloride, acrylamide and 2-acrylamide-2-methylpropanesulfonic acid are polymerized and grafted on the surface of nano silicon dioxide to form the silicon dioxide blocking agent with a core-shell structure and a rigid inside and a soft outside; by means of rigid plugging of a nano material and deformation filling flexible plugging of a high-molecular polymer, shale micro-nano pores are efficiently plugged with rigid inside and flexible outside, so that the stability of a well wall is maintained, meanwhile, secondary generation of hydrates is effectively inhibited, and the safety and efficiency of deepwater drilling are improved; the plugging agent provided by the invention reduces the demand on a large number of thermodynamic inhibitors, not only saves the cost, but also has the characteristic of environmental protection.

The invention belongs to the technical field of sodium-ion batteries, and relates to sodium-ion battery positive electrode slurry and a preparation method thereof, and the sodium-ion battery positive electrode slurry comprises a positive electrode active material, a conductive agent, a binder, a dispersant, a slurry stabilizer and a solvent; the positive electrode active material is a transition metal layered oxide material, the conductive agent is one or a combination of more of conductive carbon black, ketjen black, conductive graphite and a carbon nanotube, the binder is polyvinylidene fluoride, the dispersant is polyvinylpyrrolidone, the slurry stabilizer is one or a combination of more of iron oxide, aluminum oxide, zirconium oxide and titanium boride, and the positive electrode active material is a positive electrode active material. The solvent is N-methyl pyrrolidone; in the slurry preparation step, a binder and a solvent are mixed and dissolved to prepare a glue solution; adding a conductive agent and a dispersing agent for dispersing to obtain a conductive adhesive; adding a positive active material and a slurry stabilizer, and dispersing to obtain final slurry; the invention can effectively solve the problem of slurry flocculation in the homogenizing process of the sodium ion battery positive electrode material.

A method for preparing flaky silver powder with the controllable single-crystal structure size comprises the steps that firstly, a silver nitrate aqueous solution is prepared, then a dispersing agent polyvinylpyrrolidone aqueous solution is added and stirred to be uniform, and then a trisodium citrate aqueous solution is added for reacting to prepare nano-silver seed crystals; finally, adding a polyvinyl alcohol aqueous solution serving as an end-capping reagent into the solution, and coating PVA on the crystal face of the nano-silver seed crystal {100} through a grinding dispersion machine to form a nano-silver seed crystal mixed solution containing silver nitrate, polyvinylpyrrolidone and coated PVA; preparing a nitric acid aqueous solution and an ascorbic acid aqueous solution, mixing and adding the nitric acid aqueous solution and the ascorbic acid aqueous solution into a reaction kettle, adding the mixed solution containing silver nitrate, polyvinylpyrrolidone and the PVA-coated nano-silver seed crystal under a stirring condition, and mixing to generate a reduction reaction; the PH value is adjusted through nitric acid to control the reduction reaction speed, the growth direction of nano-silver seed crystals is controlled through PVA, the particle size growth size is controlled through polyvinylpyrrolidone, and finally the flaky silver powder with the controllable single-crystal structure size is obtained.

The invention discloses a Zhejiang camellia japonica clone tissue culture and rapid propagation method. A Zhejiang camellia japonica clone tissue culture and rapid propagation technical system is established by taking a non-lignified tender stem as an explant, sterilizing and then performing primary induction, subculture multiplication, strong bud culture and rooting culture. The explants are soaked before primary inoculation, and vitamin C and polyvinylpyrrolidone with certain concentration are added into a primary induction culture medium, so that browning of the explants can be effectively inhibited; hormone regulation and control and nutrient addition are combined, so that the primary induction rate reaches up to 95.3%, the multiplication coefficient reaches about 6.8, the rooting rate reaches 83.5%, efficient and rapid propagation can be realized, and the method is not limited by factors such as seasons, climate and regions. The rapid propagation offspring obtained by the system can maintain all excellent characters of a stock plant, and the strong bud obtained in the process can be used as a scion for grafting propagation, so that a technical support is provided for protection, development and utilization of rare germplasm resources and excellent clone of the Zhejiang red camellia.

The invention relates to the technical field of thickening agents, and discloses a preparation method of a high-temperature-resistant thickening agent for fracturing. According to the preparation method disclosed by the invention, acrylamide, sulfobetaine modified acrylamide and pyrrolidone modified naphthyl melamine are polymerized, so that the thickening agent for high-temperature-resistant fracturing is obtained. A triazine ring structure and naphthyl have high stability, the rigidity of a polyacrylamide molecular chain and the hydrophobic association effect between molecules are enhanced, the high temperature resistance and the salt resistance are improved, and due to the conjugation effect formed by two benzene rings in naphthyl, the thermal stability is further enhanced; by introducing vinyl pyrrolidone, hydrolysis of amido in polyacrylamide can be inhibited, and the temperature resistance and salt resistance of the thickening agent are improved; under a high-salt condition, due to weakening and shielding of mutual attraction of salt ions to anionic and cationic groups in the sulfobetaine, polyacrylamide molecules are more stretched, macroscopically, the viscosity is increased or reduced slightly, and the temperature resistance and salt resistance are improved.

The invention discloses a negative electrode slurry cracking reduction method, which specifically comprises the following steps: S1, negative electrode slurry formula improvement: on the basis of original raw materials of negative electrode slurry: graphite, a conductive agent, a thickening agent, a binder and deionized water, adding a specific additive-N-methyl pyrrolidone accounting for 0.5% of the total weight of the raw materials; the invention relates to the technical field of battery manufacturing. According to the method for reducing the cracking of the negative electrode slurry, coating cracking is remarkably reduced: by adding NMP in a specific proportion, the problem of coating cracking of the negative electrode slurry is effectively improved, and the yield and quality of a negative electrode plate are improved; the cracking-free negative plate can maintain better structure and performance stability, and is beneficial to improving the overall performance and prolonging the service life of the lithium ion battery; the rejection rate and the rework rate caused by cracking are reduced, and the production cost and resource waste are reduced; nMP is used as a common solvent and is widely applied to the battery manufacturing industry.

The invention provides a nitrification inhibitor and a preparation method thereof as well as stable urea and a preparation method thereof, and relates to the technical field of fertilizers. The nitrification inhibitor provided by the invention is prepared from the following components in percentage by mass: 20 to 45 percent of 3, 4-dimethyl pyrazole phosphate (DMPP), 30 to 70 percent of amino acid and the balance of auxiliaries, the auxiliary agent is one or more of polysaccharide, polyvinylpyrrolidone, poloxamer and carbomer. According to the invention, the DMPP and the amino acid are compounded, the amino acid is used as a stabilizer of the DMPP, so that the stability of the DMPP can be remarkably improved, and meanwhile, the polymer additive is used as an adhesive, so that the stability of the DMPP can be further improved. The nitrification inhibitor provided by the invention has excellent stability; the stable urea can be obtained by adopting an endogenous adding mode and adding the stable urea into the urea with relatively low loss, and the stable urea has multiple effects of improving the urea utilization rate, improving the crop quality, improving the soil biological environment, improving the soil fertility and the like.

The invention discloses high-thermal-conductivity carbon black and a preparation method and application thereof, and relates to the technical field of carbon black modification.The preparation method of the high-thermal-conductivity carbon black comprises the following steps that carbon black is subjected to oxidation treatment, silanization treatment and tannic acid coating treatment, and modified carbon black is obtained; preparing a graphene / boron nitride / modified carbon black multi-dimensional filler; carrying out primary modification on the graphene / boron nitride / modified carbon black multi-dimensional filler by adopting lignin, polyvinylpyrrolidone and samarium chloride, and then carrying out secondary modification by adopting 6-aminocaproic acid to obtain the high-thermal-conductivity carbon black. The high-thermal-conductivity carbon black prepared by the invention not only has good dispersity, but also can well improve the thermal conductivity and mechanical properties of a rubber matrix.

The present invention relates to the technical field of nanofiltration membranes, and particularly relates to a preparation method for a positively charged nanofiltration membrane for improving a "trade-off" effect. The preparation method comprises the following process: sequentially adding a water phase and an oil phase to the surface of a support layer to perform a reaction, so as to prepare a polyamide layer; pouring in a functionalized graphene dispersion; and sequentially placing same into an N,N-dimethyl propane diamine solution, a sodium borohydride solution and an iodomethane solution to perform a reaction, so as to obtain a nanofiltration membrane, wherein the functionalized graphene is pyrrolidone-based graphene. According to the present invention, a mixture of piperazine and polyethyleneimine is used as a water phase and is subjected to interfacial polymerization with an oil phase 1,3,5-trimesoyl chloride on the surface of the support membrane; and by means of the compounding of micromolecular piperazine and macromolecular polyethyleneimine, the rapid formation of a polyamide layer is promoted, the distance of a system cross-linked network is increased, a positively charged polyamide layer having a large pore diameter and good hydrophilicity is formed, and a good water flux and a good rejection rate are achieved, thereby improving the "trade-off" effect.

Disclosed is a printing ink for heat-sensitive recording media, which is (A) or (B) below: (A) a heat-sensitive color-developing printing ink containing a leuco dye, a color developer, a vinylpyrrolidone-vinyl acetate copolymer, and a solvent, wherein the color developer is at least one selected from the group consisting of an N,N'-diaryl urea-based compound represented by general formula (1) (in the formula, R0 represents a C1-12 alkyl group, a C7-12 aralkyl group, or a C6-12 aryl group. The aralkyl group and the aryl group may be substituted with a C1-12 alkyl group, a C1-12 alkoxy group, a C6-12 aryl group, or a halogen atom. A plurality of R0s may be the same or different. A1 represents a hydrogen atom or a C1-4 alkyl group. A plurality of A1s may be the same or different.), a compound represented by general formula (2) (in the formula, R1 to R5 are the same or different, and represent a hydrogen atom, a halogen atom, a nitro group, an amino group, an alkyl group, an alkoxy group, an aryloxy group, an alkylcarbonyloxy group, an arylcarbonyloxy group, an alkylcarbonylamino group, an arylcarbonylamino group, an alkylsulfonylamino group, an arylsulfonylamino group, a monoalkylamino group, a dialkylamino group, or an arylamino group.), and 5-(N-3-methylphenyl-sulfonamide)-N',N''-bis-(3-methylphenyl)-isophthalic acid diamide; and (B) a protective layer printing ink for heat-sensitive recording media, the protective layer printing ink containing an adhesive, a slipperiness imparting agent, and a solvent, wherein the adhesive is a polyvinyl acetal resin, and the slipperiness imparting agent is an alkyl phosphate ester and / or a salt thereof.

The invention discloses a temperature / CO2 dual-response zwitterionic hydrogel profile control agent, which is prepared by taking a monomer A, a monomer B and a monomer C as raw materials, adding a cross-linking agent and an initiator, and carrying out polymerization reaction in a water medium. The monomer A is selected from any one of acrylamide, acrylic acid and 1-vinyl-2-pyrrolidone; the monomer B is selected from any one of [2-(methacryloyloxy) ethyl] dimethyl-(3-sulfopropyl) ammonium hydroxide, 2-methacryloyloxyethyl phosphorylcholine and 3-((2-(methacryloyloxy) ethyl) dimethylamino) propionic acid inner salt; and the monomer C is selected from any one of 2-(dimethylamino) ethyl methacrylate, dimethylamino propyl methacrylamide and polyethyleneimine. The profile control agent has double swelling mechanisms, has outstanding temperature and salt resistance, resists 220000 mg / L of mineralization water, is suitable for high-salt reservoirs, and is good in long-term aging property.

The invention relates to the technical field of carbon nanotube materials, in particular to high-dispersity carbon nanotube slurry and a preparation method thereof. Ammonium chloride, sodium azide, novolac epoxy resin and carbon nanotubes are added for modification treatment, and the modified carbon nanotubes are obtained. Then, a silane coupling agent KH550, an MXene material, a palmitic acid solution, 1-ethyl-(3-dimethylaminopropyl) carbodiimide hydrochloride and N-hydroxysuccinimide are added and mixed, and the modified MXene material is obtained. And performing ultrasonic dispersion on polyvinylpyrrolidone, N-methyl pyrrolidone, the modified carbon nanotubes and the modified MXene material to obtain the composite conductive filler. The finished product is obtained by adding the surfactant, the deionized water and the composite conductive filler. The finished product prepared by the method has good conductivity and dispersity, so that the finished product has a wide application prospect in the technical field of carbon nanotube materials.

The invention relates to a preparation method of a silver nanowire based on a phenolic compound and the silver nanowire, and the preparation method comprises the following steps: 1, respectively dissolving polyvinylpyrrolidone, small molecular phenolic acid, halide, a silver source and the phenolic compound in deionized water to obtain respective solutions; 2, sequentially adding a polyvinylpyrrolidone solution, a small molecular phenolic acid solution, a halide solution and a silver source solution, and stirring to obtain a reaction solution A; step 3, adding a phenolic compound solution into the reaction solution A to obtain a reaction system B, and stirring and reacting to obtain a mixed solution C containing silver nanowires; fourthly, the mixed solution C containing the silver nanowires is sequentially centrifuged and washed, and then the silver nanowires are prepared; the diameter of the silver nanowire is 20-150 nm, and the length of the silver nanowire is 5-100 [mu] m. Therefore, according to the design, water is adopted as a solvent to synthesize the silver nanowire, the reaction temperature is low, and the reaction speed is high.

The invention provides a bismuth oxybromide-based photocatalytic material, and a preparation method and application thereof, and the preparation method comprises the following steps: (1) dissolving bismuth nitrate pentahydrate and polyvinylpyrrolidone in an alcoholic solution, rapidly stirring to obtain a mixed solution, adding potassium bromide into the mixed solution, and continuing to fully stir for reaction; and (2) transferring the mixed solution into a reaction kettle with a polytetrafluoroethylene lining, carrying out solvothermal reaction, carrying out centrifugal suction filtration separation on the obtained product, washing and drying to obtain the photocatalytic material. The bismuth oxybromide-based photocatalytic material, the preparation method and the application have the advantages that the bismuth oxybromide-based photocatalytic material is excellent in performance and high in visible light response capability, dyes can be quickly degraded in a short time, and the treatment efficiency of printing and dyeing wastewater can be obviously improved.

The present disclosure relates with the development of a process for producing gels from polymeric materials crosslinked with organic agents and their use controlling water in porous media under high salinity and temperature conditions. The characteristics of these gels enable them to have a good performance withstanding extreme conditions in mature Mexican oil wells and in others located in other parts of the world. The gels featured in the present disclosure include novel ionic terpolymers based on acrylamide (AM), N-vinylpyrrolidone (VP), N,N′-methylenebisacrylamide (BAA), 1-vinyl-3-butylimidazolium bromide (VIM4C[Br]) and organic crosslinking agents.

The invention relates to hydrogel loaded with oxygen self-producing nanoparticles as well as a preparation method and application of the hydrogel. The preparation method comprises the following steps: 1, taking cross-linked methacrylamide silk fibroin and hyaluronic acid modified by arginine-glycine-aspartic acid peptide as base materials, and loading self-oxygen-producing nano particles CaO2 (at) PVP (at) Cu-EGCG, and the self-oxygen-producing nano particles CaO2 (at) PVP (at) Cu-EGCG are prepared by coating Cu-EGCG on calcium peroxide nano particles modified by PVP modified polyvinylpyrrolidone. The hydrogel can improve energy metabolism and regulate immune environment through dual mechanisms, realizes efficient promotion of myocardial repair, and provides a new strategy and thought for tissue regeneration and functional recovery after myocardial infarction.

The invention discloses an anti-tumor nano material based on copper death promotion as well as a preparation method and application of the anti-tumor nano material. The anti-tumor nano material is constructed by taking PCN-Cu as a metal organic framework compound and merging Pt nano particles with stable polyvinylpyrrolidone into the PCN-Cu, and the anti-tumor nano material is named as Pt-coated PCN-Cu. Experiments prove that the Pt-coated PCN-Cu can improve the concentration of copper ions in tumor cells, promote the lipoic acylation aggregation process of mitochondrial related proteins, promote degradation and proteotoxicity reaction of Fe-S cluster proteins and induce copper death of the tumor cells. The Pt-coated PCN-Cu has the advantages of being simple in preparation process, green, economical, low in cost, capable of being produced on a large scale and the like, has a good anti-tumor effect, expands a novel treatment mode for promoting tumor cell copper death, and provides a new technical means for tumor treatment.

The invention belongs to the technical field of phase-change ceramic fiber aerogel, and discloses high-temperature phase-change heat-insulation ceramic fiber aerogel and a preparation method thereof.The preparation method comprises the steps that polycarbosilane and polyvinylpyrrolidone are added into an organic solvent to be mixed and stirred till the polycarbosilane and the polyvinylpyrrolidone are completely dissolved, and a precursor solution is obtained; dispersing a high-temperature phase change microcapsule into the precursor solution, and stirring until the high-temperature phase change microcapsule is uniformly dispersed to obtain a spinning solution; a ceramic precursor fiber membrane is obtained through electrostatic spinning, and the high-temperature phase-change heat-insulation ceramic fiber aerogel is obtained through cross-linking curing and sintering. The thermal conductivity of the high-temperature phase-change heat-insulation ceramic fiber aerogel is adjustable between 0.03 W / (m.k) and 0.05 W / (m.k), the phase-change temperature ranges from 550 DEG C to 600 DEG C, and the phase-change enthalpy value ranges from 400 J / g to 500 J / g. Compared with traditional ceramic aerogel, the aerogel can regulate and control the environment temperature, is more resistant to high temperature and safer, and has wide application in the field of high-temperature heat insulation of aviation power batteries.

The invention belongs to the technical field of veterinary preparations, and particularly relates to a tilmicosin premix and a preparation method thereof. The tilmicosin premix is prepared from the following raw materials: tilmicosin, a polylactic acid-glycolic acid copolymer, lecithin, modified hydroxypropyl methyl cellulose, grafted polyvinylpyrrolidone, polyethylene glycol and an antioxidant, a solid dispersion is formed through lecithin and grafted polyvinylpyrrolidone, the solubility and stability of tilmicosin are enhanced, polylactic acid-glycolic acid copolymer nano-microspheres are prepared through a double-emulsion solvent evaporation method, slow release of drugs is achieved, dodecyl modified hydroxypropyl methyl cellulose and polyethylene glycol are combined, and the sustained release effect is achieved. The solubility and the slow release characteristic are further enhanced. The activity of the granular premix is effectively preserved, and the granular premix is convenient to use and transport.

The invention discloses an oxygen-sulfur double-vacancy modified SnO2 / SnS2 / C nano material as well as a preparation method and application thereof, and belongs to the technical field of electrode materials. The preparation method comprises the following steps: mixing a structure regulating agent with tin salt, dropwise adding alkali liquor, stirring, and carrying out suction filtration to obtain Sn6O4 (OH) 4; the preparation method comprises the following steps: adding glucose and polyvinylpyrrolidone into distilled water, stirring to form a uniform solution, adding Sn6O4 (OH) 4 into the uniform solution, stirring, and carrying out ultrasonic and hydrothermal reaction to obtain SnO2 / glucose; and calcining the SnO2 / glucose and a sulfur source in an inert atmosphere to obtain the SnO2 / SnS2 / C nano material modified by oxygen and sulfur double vacancies. The SnO2 / SnS2 / C disclosed by the invention is used for a lithium / sodium ion battery negative electrode, can effectively relieve volume expansion of tin-based oxysulfide and improve the conductivity of an electrode material, and shows high charge-discharge specific capacity, excellent rate capability and high-rate long-cycle stability.

The invention relates to a self-repairing waterborne polyurethane composite elastomer based on dynamic interface reinforcing and toughening as well as a preparation method and application thereof, and belongs to the technical field of self-repairing high polymer materials. The method comprises the following steps: preparing a waterborne polyurethane emulsion; the preparation method comprises the following steps: uniformly dispersing polyvinylpyrrolidone in an ethanol solution, adding polyfunctional mercaptan and polyfunctional isocyanate, and adding an amino-containing imidazole monomer to obtain microsphere powder; and uniformly dispersing the microsphere powder in a waterborne polyurethane emulsion, adding a metal salt solution, and then volatilizing water to form a film material, thereby obtaining the self-repairing waterborne polyurethane composite elastomer based on dynamic interface reinforcement and toughening. The self-repairing waterborne polyurethane elastomer with excellent comprehensive performance is obtained by designing the structure of waterborne polyurethane, modifying the surface of the microsphere and introducing a dynamic interface for compounding, and the strength, the toughness and the self-repairing capability of the elastomer are simultaneously improved.

The invention discloses a polyion liquid / polyvinylidene fluoride-hexafluoropropylene-based solid electrolyte with a microscopic liquid phase and a preparation method and application thereof, and the preparation method comprises the following steps: adding a lithium salt into N-methyl-2-pyrrolidone, and stirring until the lithium salt is completely dissolved; then adding imidazolyl polyion liquid to prepare a solution A; adding polyvinylidene fluoride-hexafluoropropylene into N-methyl-2-pyrrolidone to prepare a solution, adding the solution into the solution A, continuously stirring until the solution is fully dissolved to obtain a precursor solution of the solid electrolyte, casting the precursor solution onto a polytetrafluoroethylene mold, and carrying out vacuum drying to obtain the solid electrolyte. And the polyvinylidene fluoride-hexafluoropropylene polymer-based solid electrolyte added with the imidazolyl polyion liquid is prepared by adding the imidazolyl polyion liquid into the polyvinylidene fluoride-hexafluoropropylene polymer-based solid electrolyte. The polymer-based solid electrolyte with a microscopic liquid phase is obtained through an electrolyte preparation process which is mild in condition, simple to operate and easy for large-scale production, and the solid electrolyte has good conductivity and mechanical properties.

The invention discloses a gas-sensitive material for monitoring an environment-friendly gas characteristic substance CO as well as a preparation method and application thereof, and relates to the technical field of gas-sensitive materials. The preparation method comprises the following steps: dissolving tin tetrachloride pentahydrate, sodium hydroxide and polyvinylpyrrolidone, adding ammonium fluoride, reacting at 155-165 DEG C, drying the product, and calcining at 295-305 DEG C to obtain SnO2 nanoparticles; the preparation method comprises the following steps: performing ultrasonic mixing on SnO2 deionized water dispersion liquid and MoS2 nanosheet ethylene glycol dispersion liquid, and then drying to obtain the MoS2 / SnO2 composite material with a mesoporous hollow nanotube structure, and the volume ratio of ethylene glycol to deionized water is (0.9-1.1): 1. The MoS2 / SnO2 gas sensitive material has the advantages of low density, high pore volume, large specific surface area, high structural stability and the like. And when applied to a CO resistive sensor, the catalyst has good CO selectivity, high sensitivity and good long-term stability.

The invention relates to the technical field of all-vanadium redox flow batteries, in particular to a covalent organic framework cross-linked sulfonated polybenzimidazole proton exchange membrane as well as a preparation method and application thereof. The proton exchange membrane structurally comprises a polymer main chain, a sulfonic acid group, a connecting agent and a cross-linking agent molecule, a sulfonated polybenzimidazole polymer, a COF cross-linking agent and the connecting agent are dissolved in N-methyl pyrrolidone, and the COF cross-linked sulfonated polybenzimidazole proton exchange membrane is obtained after treatment. Aiming at the problems that vanadium ions of a positive electrode and a negative electrode of an all-vanadium redox flow battery are crossed, the capacity of the all-vanadium redox flow battery fades and the energy efficiency is low, the hydrophilicity of the sulfonated polybenzimidazole proton exchange membrane is improved through sulfonation treatment, and the mass transfer resistance is reduced. After the covalent organic framework is introduced, the increased free volume is beneficial to construction of a rapid proton transmission channel and can accommodate water molecules to limit swelling of the membrane material.

The invention discloses an antibacterial drug delivery system based on a dynamic response type microneedle patch and a preparation method, and belongs to the field of biomedical materials.The antibacterial drug delivery system comprises a substrate layer and a needle point layer arranged on the surface of the substrate layer, the substrate layer is a mixed matrix of polyvinyl alcohol (PVA) and polyvinylpyrrolidone (PVP), and the needle point layer is made of nano-silver; the needle tip layer is a phenylboronic acid modified oxidized hyaluronic acid and polyvinyl alcohol composite system. The antibacterial drug delivery system based on the dynamic response type microneedle patch, namely the microneedle patch with the pH response drug release function, is suitable for antibacterial treatment of infectious wounds, the mechanical strength of the needle point layer is improved, it can be better guaranteed that a microneedle completely penetrates into the skin, and the delivery efficiency is improved; meanwhile, drug release can be responded according to the pH of a bacterial infection part, and the antibacterial effect is good.

The invention relates to the technical field of conductive materials, in particular to a high-concentration dispersion system and a preparation method thereof. The high-concentration dispersion system comprises a conductive agent, a dispersing agent, a solvent and a viscosity reduction auxiliary agent, the conductive agent is modified carbon nanotubes, the dispersing agent is modified polyvinylpyrrolidone, the solvent is N-methyl pyrrolidone or deionized water, and the viscosity reduction auxiliary agent is piperazine anhydrous; wherein the modified carbon nano tube is obtained by mixing and heating a carbon nano tube and a mixed acid solution of nitric acid and sulfuric acid, then cooling, filtering, washing, drying, then dispersing in 75% ethanol, and finally adding 3-[3-carboxyl allylamido] propyltriethoxysilane for modification; the modified polyvinylpyrrolidone is obtained by heating polyvinylpyrrolidone at 310-330 DEG C and then oxidizing the polyvinylpyrrolidone. The conductive agent content of the high-concentration dispersion system is high, the conductive agent accounts for 15%-20% of the high-concentration dispersion system by mass, and the high-concentration dispersion system is low in viscosity, high in dispersity and good in conductivity.

The invention provides an amidoxime functionalized MXene / CoZn-MOF heterostructure flowing electrode, a preparation method thereof and application of the amidoxime functionalized MXene / CoZn-MOF heterostructure flowing electrode to efficient adsorption of uranium in wastewater, and belongs to the technical field of sewage treatment. The flow electrode with the amidoxime functionalized MXene / CoZn-MOF heterostructure is prepared by taking MXene nanosheets, polyvinylpyrrolidone, zinc nitrate, cobalt nitrate, imidazole-2-formaldehyde and amidoxime functionalized diaminomaleonitrile as raw materials, and is further applied to a flow electrode capacitive deionization system for efficient adsorption of uranyl ions. The flow electrode prepared by the invention has the advantages of multiple micropores, high specific capacitance, high conductivity, outstanding rheological property and the like, can still keep relatively high adsorption capacity under a seawater condition, can be used for treating wastewater containing hexavalent uranium, is easy to recycle and recycle, and is environment-friendly.