39 results about "Diphenylethylenediamine" patented technology

Disclosed is a polishing composition which realizes both high planarity and reduction of corrosion in the surface of a wiring metal. Specifically disclosed is a polishing composition containing an oxidizing agent (A), at least one or more acids (B) selected from amino acids, carboxylic acids having 8 or less carbon atoms and inorganic acids, a sulfonic acid (C) having a concentration of not less than 0.01% by mass and an alkyl group having 8 or more carbon atoms, a fatty acid (D) having a concentration of not less than 0.001% by mass and an alkyl group having 8 or more carbon atoms, and at least one or more compounds (E) selected from pyridinecarbonyl compounds, nonionic water-soluble polymers, 2-pyrrolidone, N-methylpyrrolidone, 1,3-dimethyl-2-imidazolidinone, gramine, adenine, N,N'-diisopropylethylenediamine, N,N'-bis(2-hydroxyethyl)ethylenediamine, N,N'-dibenzylethylenediamine and N,N'-diphenylethylenediamine.

The invention provides a method for measuring the optical purity of chiral carboxylic acid by use of a chiral chemical shift reagent. A series of chiral diamines such as 1,2-diphenylethylenediamine, cyclohexyldiamine and dithio (diurea) derivatives of binaphthyldiamine are used as chiral shift reagents, and the optical purity of the chiral carboxylic acid is quickly detected by a nuclear magnetic resonance spectrometer. The method provided by the invention has the advantages of easy synthesis of shift reagents and simplicity in operation, and is a quick, efficient, convenient and practical detection means.

The invention relates to a pyridine type chiral Cu(II)-Salen ligand metal organic framework crystal material as well as a preparation method and application thereof. The material has the following chemical formula: {[Zn2(L)(BPDC)2].DMF.5H2O}n, wherein L is (R,R)-N,N'-bis(5-(4-pyridyl) diyl-2-hydroxyacetophenone)-1,2-diphenylethylenediamine copper (II), BPDC is a 4,4'-biphenyl dicarboxylate divalent anion, and n is the degree of polymerization. The metal organic framework crystal material provided by the invention adopts a solvothermal synthesis method, and is simple to operate, low in cost, high in yield and easy for large-scale industrial production. The prepared metal organic framework crystal material has a relatively high specific surface area (BET specific surface area is 752 m<2> / g),and the adsorption capacities of CO2 and N2 under 1atm and 273 K are 3.47 mmol / g and 0.57 mmol / g respectively. TEMPO is used as an additive, selective oxidation of benzyl alcohol is catalyzed in a water phase to generate benzaldehyde, the yield reaches 99%, the catalyst is recycled for five times with almost no activity loss, and the catalyst is a good heterogeneous catalyst.

The invention discloses a (R, R)-1,2-diphenylethylenediamine nickel azide complex. The (R, R)-1,2-diphenylethylenediamine nickel azide complex has a chemical formula of [Ni(L)2(N3)] infinity ClO4.0.5H2O, wherein L is a chiral bidentate nitrogen-containing organic ligand. The preparation method comprises the following steps: placing a methanol solution as an underlayer in which nickel perchlorate and chiral bidentate nitrogen-containing organic ligand L are dissolved into a reaction vessel, adding a mixed solution of methanol and water as an intermediate buffer layer, slowly adding a water solution as an uppermost layer in which sodium azide is dissolved into the reaction vessel, standing for 5 days, filtering, washing and carrying out vacuum drying to obtain the target product. A novel one-dimensional chain nickel complex is prepared by using azide anion as a bridging ligand, the preparation process is simple, the reaction is carried out under a normal temperature and a normal pressure, the posttreatment is easily performed, and the yield is high and can reach 83%. The (R, R)-1,2-diphenylethylenediamine nickel azide complex has good ferroelectric property and has potential broad application prospects in the field of information storage as a novel ferroelectric material.

The object of the present invention is to provide 3-hydroxy-3-(2-thienyl)propionamides useful as synthesis intermediates of pharmaceutical preparations and the like and a method for obtaining optically active 3-amino-1-(2-thienyl)-1-propanols using the same with high reaction yield, high optical yield and industrially low cost.According to the present invention, 3-amino-1-(2-thienyl)-1-propanols are obtained by carrying out asymmetric reduction of a β-ketocarbonyl compound having thiophene ring in the presence of a catalyst constituted from a compound of a group VIII or IX metal in the periodic table (e.g., a ruthenium compound) and an asymmetric ligand represented by a specified optically active diamine derivative (e.g., a diphenylethylenediamine derivative), or using a cell, a treated product of said cell or the like of a microorganism, and as occasion demands, carrying out amidation of the ester group and then carrying out reduction of the amido group.(each of the substituents is as described in claim 1).

The invention discloses a (R, R)-1,2-diphenylethylenediamine nickel azide complex. The (R, R)-1,2-diphenylethylenediamine nickel azide complex has a chemical formula of [Ni(L)2(N3)] infinity ClO4.0.5H2O, wherein L is a chiral bidentate nitrogen-containing organic ligand. The preparation method comprises the following steps: placing a methanol solution as an underlayer in which nickel perchlorate and chiral bidentate nitrogen-containing organic ligand L are dissolved into a reaction vessel, adding a mixed solution of methanol and water as an intermediate buffer layer, slowly adding a water solution as an uppermost layer in which sodium azide is dissolved into the reaction vessel, standing for 5 days, filtering, washing and carrying out vacuum drying to obtain the target product. A novel one-dimensional chain nickel complex is prepared by using azide anion as a bridging ligand, the preparation process is simple, the reaction is carried out under a normal temperature and a normal pressure, the posttreatment is easily performed, and the yield is high and can reach 83%. The (R, R)-1,2-diphenylethylenediamine nickel azide complex has good ferroelectric property and has potential broad application prospects in the field of information storage as a novel ferroelectric material.

The invention discloses a Ni (II)-Salen ligand metal organic framework crystal material and a preparation method and application thereof. The chemical formula of the material is {[Zn4O (L) 6]. DMF.H2O} n, wherein L is a dicarboxylic acid radical divalent anion of (R, R)-N, N '-bis (3-methyl-5-carboxyl salicylidene)-1, 2-diphenylethylenediamine nickel (II), and n is the polymerization degree. The metal organic framework crystal material is synthesized by a solvothermal synthesis method, which is simple to operate, low in cost, high in yield and easy for large-scale industrial production. The prepared metal organic framework crystal material has high thermal stability (400 DEG C), and the BET specific surface area is 228m <2> / g. And the adsorption quantity of CO2 at 273K and 1atm is 18.8 m<3> / g. In the presence of an oxidizing agent, styrene is catalyzed to be selectively oxidized to generate benzaldehyde in a water phase, the yield reaches 99%, the catalyst is recycled for five times, and the activity loss is small. In the presence of tetrabutylammonium bromide, 1 atm and 50 DEG C solvent-free catalysis is performed on epoxy styrene and CO2 to react to generate styrene carbonate, the yield is 91%, and the catalyst is recycled for five times and still keeps activity. The material is a good heterogeneous catalyst.

The invention relates to a novel niacin drug salt and a preparation method thereof. The salt is made from niacin and 1,2‑diphenylethylenediamine in a 2:1 molar ratio. The present invention adopts a green synthesis method of micro-liquid assisted grinding and two methods of slow volatilization at room temperature to prepare niacin-1,2-diphenylethylenediamine drug salt with high purity. The solubility of the obtained nicotinic acid drug salt is increased by 3.8 times, 6.7 times and 3.9 times in the buffer solution of pH=1.2, 4.5 and 6.8 respectively, and the crystal form is stable and does not decompose under the condition of normal temperature. The method requires only a trace amount of catalytic amount of organic solvent, has little pollution, mild reaction conditions, simple operation and high product purity.

A novel transition metal complex, preferably a ruthenium-phosphine complex or rhodium-phosphine complex, which is effectively usable in various asymmetric syntheses and, in particular, is more effectively usable in the asymmetric hydrogenation of various ketones; and a novel process for producing an optically active alcohol with the complex. The novel transition metal complex includes a ligand obtained by introducing a diarylphosphino group into each of the 2- and 2′-positions of diphenyl ether, benzophenone, benzhydrol, or the like. It preferably further includes an optically active 1,2-diphenylethylenediamine coordinated thereto. The complex preferably is a novel diphosphine-ruthenium-optically active diamine complex or diphosphine-rhodium-optically active diamine complex. The process comprises using the complex as an asymmetric hydrogenation catalyst to conduct the asymmetric hydrogenation of a ketone compound to thereby obtain an optically active alcohol in a high optical purity and a high yield.

The invention discloses a porous chiral organic polymer heterogeneous catalyst based on a chiral 1,2-diphenylethylenediamine metal complex, and a preparation method thereof and belongs to the field ofsynthesis and application of functional materials. The heterogeneous catalyst takes chiral 1,2-diphenylethylenediamine and the coordinated metal thereof as active species, and can be obtained throughtwo methods: method 1, carrying out copolymerization between alkylene chiral 1,2-diphenylethylenediamine and another monomer to obtain a porous organic polymer, and coordinating with the metal complex; method 2, firstly coordinating alkylene chiral 1,2-diphenylethylenediamine with the metal complex, and copolymerizing with another monomer. The heterogeneous catalyst of this type is applied to reactors of a fixed bed, a slurry bed, a trickle bed and the like. According to the heterogeneous catalyst provided by the invention, the catalyst is applied to reaction technologies of chiral hydrogenation, chiral hydrogen transfer and chiral hydrosilylation of aromatic ketone or aromatic amine, and the advantages of high-activity and high selectivity of the homogeneous phase metal complex, and easyseparation of the heterogeneous catalyst are remained.

The invention provides a chiral tridentate imine P, N, N-ligand, a preparation method and an application of the chiral tridentate imine P, N, N-ligand in Cu-catalyzed asymmetric propargyl conversion, the chiral tridentate imine P, N, N-ligand has stable properties, has good tolerance to air and humidity and contains N-H functional groups, and the chiral tridentate imine P, N, N-ligand is prepared from chiral ferrocenephosphine-1, 2, 3, 4-tetramethyl-1, 3, 4-tetramethyl-1, 3, 4-tetramethyl-1, 3, 4-tetramethyl-1, 3, 4-tetramethyl-1, 3, 4-tetramethyl-1, 3, 4 A 1, 2-diphenylethylenediamine compound and a 2-acyl pyridine compound are used as raw materials, and one-step reaction is performed under mild conditions under the action of a dehydrating agent. The catalyst composed of the novel chiral tridentate imine P, N, N-ligand and a Cu metal precursor has excellent catalytic activity and stereoselectivity in an asymmetric propargyl conversion reaction.

The invention provides a method for measuring the optical purity of chiral carboxylic acid by use of a chiral chemical shift reagent. A series of chiral diamines such as 1,2-diphenylethylenediamine, cyclohexyldiamine and dithio (diurea) derivatives of binaphthyldiamine are used as chiral shift reagents, and the optical purity of the chiral carboxylic acid is quickly detected by a nuclear magnetic resonance spectrometer. The method provided by the invention has the advantages of easy synthesis of shift reagents and simplicity in operation, and is a quick, efficient, convenient and practical detection means.

The invention discloses a preparation method for (+ / -)-1,2-diphenylethanediamine. The (+ / -)-1,2-diphenylethanediamine in the invention is prepared from 1,2-dibenzoyl dioxime by catalytic reduction in a polar solvent at 20 DEG C to 100 DEG C with one selected from the system consisting of hydrazine hydrate, formic acid, sodium formate, ammonium formate, and ammonium formate-triethylamine as a hydrogen source, and with raney nickel as a catalyst and activated carbon as a cocatalyst. The preparation method provided by the invention has the advantages of simple and wide raw material sources, low price, safe production process, short process flow, mild reaction conditions, low cost, environment friendliness, etc., and is suitable for industrial production.

Ni(II)-Salen ligand metal-organic framework crystal material and its preparation method and application. The chemical formula of the material: {[Zn 4 O(L) 6 ]·DMF·H 2 O} n , where L is the dicarboxylate dicarboxylate of (R,R)-N,N'-bis(3-methyl-5-carboxysalicylidene)-1,2-diphenylethylenediamine nickel(II) Valence anion, n is the degree of polymerization. The metal organic framework crystal material adopts a solvothermal synthesis method, has simple operation, low cost, high yield, and is easy for large-scale industrial production. The prepared MOF crystalline material has high thermal stability (400°C), and the BET specific surface area is 228m 2 / g. For CO at 273K, 1atm 2 The adsorption capacity is 18.8m 3 / g. In the presence of an oxidizing agent, the selective oxidation of styrene is catalyzed in an aqueous phase to generate benzaldehyde with a yield of 99%. The catalyst is recycled five times with little loss of activity. In the presence of tetrabutylammonium bromide, 1 atm, 50 ℃ solvent-free catalysis of epoxy styrene and CO 2 The reaction produces styrene carbonate with a yield of 91%. The catalyst is recycled five times and still maintains its activity. This material is a good heterogeneous catalyst.

The invention discloses a low-melting-point nylon hot-melt yarn for preparing fly-woven shoe uppers, which is formed by polymerizing polyamines and polyacids as reactants, and adding catalysts, modifiers and other auxiliary agents for further reaction; A mixture of decanediamine, pentaethylenehexamine and (1R,2R)‑(‑)‑N‑(p-toluenesulfonyl)‑1,2‑diphenylethylenediamine was chosen for the polyamine; A mixture of sebacic acid, terephthalic acid, and dodecenylsuccinic acid was selected; bis(pentamethylcyclopentadiene) zirconium dichloride, N,N-dimethylanilinium were selected as catalysts A mixture of tetrakis(pentafluorophenyl)borate; the modifiers are 3,5-diamino-1,2,4-triazole, bicyclo(2.2.2)oct-5-ene-2 , a mixture of 3‑dicarboxylic anhydride and 2,2‑bis[4‑(4‑aminophenoxy)phenyl]‑1,1,1,3,3,3‑hexafluoropropane. Nylon thermal fuse not only has a lower melting point, but also has greater fiber strength and elongation, and also has stronger anti-ultraviolet properties and better color fastness, and can be used to prepare fly-knit uppers.