The invention belongs to the technical field of
carbon steel surface modification and
corrosion protection, and particularly relates to a preparation method of
carbon steel surface high-
corrosion-resistance electroplated
copper. In order to solve the problems that an existing
cyanide-free
copper plating process is poor in activation, a matrix is prone to damage, and the plating layer
binding force and
corrosion resistance are insufficient, the four-step process of matrix pretreatment,
anode electrolytic activation,
cyanide-free
citric acid system electrochemical
copper plating and high-temperature curing is adopted, and
sodium nitrate and
sodium chloride mixed
electrolyte is used for low-current-density mild activation; and in cooperation with a
copper plating solution with specific components and curing at 132-148 DEG C, a plating layer is compact and free of holes, and
interface bonding is tight. The method has the advantages of being
environmentally friendly, non-toxic, simple and controllable in technological process and the like, the thickness of the obtained
copper plating layer is 15-30 microns, the corrosion resistance of the obtained
copper plating layer in an alkaline environment is improved by 1.6-3.0 times compared with a traditional copper plating layer, the corrosion rate of the obtained copper plating layer in an alkaline medium is smaller than or equal to 0.06 mm / year, and the corrosion resistance of the obtained copper plating layer is remarkably improved compared with a traditional technology.