495 results about "Potassium sulfate" patented technology

The invention discloses a potassium fulvate chelated macroelement water-soluble fertilizer with stress resistance and growth promotion functions, and relates to the technical field of water-soluble fertilizers, the potassium fulvate chelated macroelement water-soluble fertilizer comprises the following raw materials by weight: 167-210 parts of mineral source potassium fulvate, 450-460 parts of potassium nitrate, 300-310 parts of urea, 150-160 parts of potassium dihydrogen phosphate, 30-40 parts of potassium sulfate, 15-25 parts of EDTA-disodium, and 5-15 parts of citric acid. 0.5 to 1.5 parts of brassinolide and 4 to 6 parts of polyaspartic acid; according to the potassium fulvate chelated macroelement water-soluble fertilizer with the stress-resistant and growth-promoting functions, through chelation cooperation of potassium fulvate and nitrogen, phosphorus and potassium, the solubility of the chelated phosphorus element in water is increased, and the chelated phosphorus element can be more uniformly distributed in soil; by adopting an EDTA-disodium and citric acid composite chelating system, volatilization and loss of nitrogen elements are reduced, the problem of precipitation of calcium, magnesium and phosphorus is solved, and the soil conditioner is suitable for hard water areas and especially has outstanding performance in saline-alkali soil and arid areas.

The invention discloses a biomass-inorganic-organic ternary composite flocculant and a preparation method and application thereof, and belongs to the field of coking wastewater treatment.The preparation method comprises the steps that chitosan serves as a substrate material, glutaraldehyde serves as a cross-linking agent, and polyferric sulfate (PFS) and chitosan are subjected to chemical cross-linking to generate an intermediate product PFS and chitosan composite particles; then potassium persulfate is used as an initiator, graft copolymerization of acrylamide and methacryloyloxyethyl trimethyl ammonium chloride is initiated through hydroxyl on the surface of PFS-chitosan, a cationic branched chain is introduced, and a final product is obtained. Through multi-component cooperation and structural design, the defects that a traditional flocculating agent is not thorough in demulsification, large in sludge amount, unstable in floc combination and the like in coking wastewater treatment are overcome, and the flocculating agent is particularly suitable for treating oil pollutants in coking wastewater.

Described herein are compositions comprising a polymer / plastic carrier and potassium metabisulphite for imparting antimicrobial activity to a plastic material. Methods for making the same, and uses of the same for microbial control, are also disclosed.

The invention discloses a treatment method of a lithium extraction leachate and a production method of lithium carbonate, wherein the treatment method can be used for efficiently recycling an aluminum resource in the leachate. The treatment method of the lithium extraction leachate comprises the following steps that 100, potassium sulfate is added into the lithium extraction leachate, and first liquid is obtained after the potassium sulfate is dissolved; step 200, performing freezing crystallization and solid-liquid separation treatment on the first liquid to obtain crude alum and lithium extraction mother liquor; step 300, dissolving crude alum in a solvent to obtain a second liquid; step 400, performing freezing crystallization and solid-liquid separation treatment on the second liquid to obtain high-purity alum and filtered mother liquor; wherein at least one of the lithium ion concentration, the rubidium ion concentration and the cesium ion concentration in the filtered mother liquor serves as a monitoring object to be monitored, when the monitoring object is larger than or equal to a threshold value, the filtered mother liquor and the lithium extraction mother liquor are mixed, and when the monitoring object is smaller than the threshold value, the filtered mother liquor serves as a solvent of crude alum.

The invention discloses a super absorbent material and side leakage prevention paper diapers, and belongs to the field of hygienic product materials. Comprising the following steps: cooling acrylic acid in an ice-water bath, and partially neutralizing the acrylic acid by using a sodium hydroxide solution; mixing potato starch with deionized water, and gelatinizing at high temperature to obtain gelatinized starch; mixing gelatinized starch, neutralized acrylic acid, potassium persulfate and deionized water; uniformly stirring under the protection of nitrogen, heating and carrying out graft copolymerization reaction to obtain a copolymer; adding modified silicon dioxide into the copolymer, and uniformly dispersing; then adding an oxetane compound, and carrying out a cross-linking reaction at a high temperature to obtain a super absorbent material; wherein the modified silicon dioxide has a porous structure, and nano-silver particles are loaded in pore walls. The super absorbent material disclosed by the invention effectively breaks through the gel blocking effect of the traditional high-molecular water-absorbent resin, has ultrahigh liquid absorption capacity and water locking capacity, and realizes slow-release long-acting bacteriostasis at the same time.

The invention discloses a core-shell structure P (MMA-MBA) copolymer heat-storage phase-change microcapsule, the microstructure is of a spherical structure, the core-shell structure is adopted, the core structure is hexadecane, the shell structure is a methyl methacrylate (MMA) and N, N-methylene bisacrylamide (MBA) copolymer, the emulsifier is lauryl sodium sulfate (SDS), the initiator is potassium persulfate, and the pH value of the core-shell structure P (MMA-MBA) copolymer heat-storage phase-change microcapsule is 7-8. And the coating efficiency is 70-75%. The preparation method comprises the following steps: 1, preparing an oil phase and a water phase; and 2, polymerization reaction of the microcapsule. A phase change cement material based on a core-shell structure P (MMA-MBA) copolymer heat storage phase change microcapsule is prepared by compounding the P (MMA-MBA) copolymer heat storage phase change microcapsule and a cement matrix, and has hydrophobicity; obvious weightlessness exists in two times.

The invention discloses a water-soluble fertilizer containing humic acid. The water-soluble fertilizer comprises the following components in parts by weight: 5-8 parts of ammonium sulfate, 28-32 parts of calcium ammonium nitrate, 18-22 parts of monoammonium phosphate, 32-38 parts of potassium sulfate and 10-15 parts of modified potassium humate. The preparation method comprises the following steps: carrying out alkali extraction on modified humic acid obtained by modifying lignite to prepare modified potassium humate, adding the modified potassium humate into a fertilizer raw material, and granulating to prepare the humic acid-containing water-soluble fertilizer. The preparation process comprises the following steps: S1, crushing and sieving the ammonium sulfate, the calcium ammonium nitrate, the monoammonium phosphate and the potassium sulfate, adding the modified potassium humate into a granulator in proportion, and uniformly stirring to obtain a mixture; s2, urea and water are prepared into a solution according to the mass ratio of 1: 3; and S3, uniformly spraying the urea guniting solution prepared in S2 into the raw material layer, and stirring until liquid drops and powder are in full contact to form particles to prepare the fertilizer. The humic acid-containing water-soluble fertilizer produced by the invention has the advantages of high nutrient content, soil structure improvement, crop root growth promotion and yield increase.

The invention discloses a bacterial culture medium for producing algin through liquid fermentation. The bacterial culture medium contains triclosan and SDS (Sodium Dodecyl Sulfate). Tests show that the PIB culture medium added with triclosan and SDS can improve the capability of producing algin by PFAC-PAO1 liquid fermentation. Accordingly, the inventor develops innovative research of optimizing the culture medium, the ChinaYin culture medium is finally obtained, and the specific formula of the ChinaYin culture medium is as follows: 20g / L of tryptone, 1.4 g / L of magnesium chloride, 10g / L of potassium sulfate, 20mL / L of glycerol, 50mu g / mL of triclosan and 125mu g / mL of SDS (Sodium Dodecyl Sulfate). Researches show that by applying the culture medium, the polysaccharide yield is higher than that of a PIB culture medium and a USAYu culture medium, the yield in 48 hours is higher than that of 24 hours and 72 hours, the yield of algin powder obtained in each culture bottle can reach 8 g / L, and it is indicated that the ChinaYin culture medium has the potential of being industrially amplified to be used for fermentation production of bacterial algin.

The invention provides a water-soluble fertilizer and a compound fertilizer for promoting growth of oats in saline-alkali soil as well as a preparation method and application of the water-soluble fertilizer and the compound fertilizer, and belongs to the technical field of fertilizers and preparation thereof. The water-soluble fertilizer comprises the following components in parts by weight: 20-30 parts of urea, 25-35 parts of ammonium sulfate, 10-20 parts of ammonium polyphosphate, 40-50 parts of potassium sulfate and 5-15 parts of humic acid. The compound fertilizer comprises the water-soluble fertilizer and a seed embedding agent, the seed embedding medium is prepared from the following components in parts by weight: 0.5 to 1.5 parts of bacillus subtilis, 1 to 3 parts of plant lactobacillus, 3 to 5 parts of basophilic halomonas and 10 to 15 parts of kaolin. The components and contents of the water-soluble fertilizer meet the nutritional requirements of the oats in the growth and development period, and the growth of the oats in the saline-alkali soil is promoted. By adding the microbial agent, the pH and salt content of the saline-alkali soil are reduced, the salinization of the saline-alkali soil is improved, and the oat plant height, the overground plant quantity and the seed yield of the saline-alkali soil are obviously increased.

The invention discloses a clean, efficient and low-cost lithium extraction slag utilization method which comprises the following steps: mixing lithium extraction slag with a fluxing agent, and sequentially carrying out roasting treatment, solid-liquid separation treatment, aging treatment and water leaching treatment to obtain a second solid-liquid mixture; carrying out solid-liquid separation treatment on the second solid-liquid mixture to obtain a second filter residue and a second filtrate; performing carbon separation method treatment on the first filtrate to obtain a third solid-liquid mixture; carrying out solid-liquid separation treatment on the third solid-liquid mixture to obtain a third filter residue and a third filtrate; the main component of the second filter residue and the third filter residue is white carbon black; performing heat treatment on the second filtrate and the third filtrate to obtain a fourth solid-liquid mixture; performing solid-liquid separation treatment on the fourth solid-liquid mixture to obtain fourth filter residues and fourth filtrate; the main components of the fourth filter residue are aluminum hydroxide and ferric hydroxide; and separating the fourth filtrate to obtain a sodium sulfate crystal substance and a potassium sulfate crystal substance.

The application discloses a preparation method of urolithin A. The method uses urolithin B as a raw material, adopts potassium persulfate to perform Elbs oxidation under alkaline conditions, and obtains urolithin A. A reaction route is as follows: wherein, formula I is a chemical structural formula of urolithin B, and formula II is a chemical structural formula of urolithin A. The preparation method of urolithin A provided by the application effectively reduces a synthesis cost, avoids use of dangerous and toxic reagents, effectively reduces generation of industrial three wastes, and is simple in process, convenient in operation, low in raw material cost, high in yield, and beneficial to large-scale industrial production.

The invention relates to the technical field of improvement of coastal saline-alkali land, in particular to a soil conditioner for salt-control fertile soil of coastal fishery reclamation saline-alkali land and a preparation method of the soil conditioner. The invention relates to a soil conditioner for salt-control fertile soil of coastal fishery receding reclamation saline-alkali land. The soil conditioner comprises the following raw material components in parts by mass: 40-60 parts of urea, 25-45 parts of calcium superphosphate, 30-45 parts of potassium sulfate, 20-25 parts of modified oyster shell powder, 10-15 parts of humic acid, 3-5 parts of a compound microbial agent, 10-20 parts of desulfurized gypsum and 25-35 parts of a biochar composite material, the biochar composite material is prepared from the following raw material components in parts by mass: 1 to 2 parts of sodium alginate, 1 to 2 parts of chitosan, 3 to 8 parts of biochar, 1 to 5 parts of calcium chloride, 10 to 20 parts of tuff stone powder, 0.25 to 2 parts of acidified attapulgite, 0.01 to 0.08 part of graphene oxide, 1 to 5 parts of ferric nitrate, 0.6 to 3 parts of copper nitrate and 0.1 to 0.5 part of silane coupling agent. By adopting the soil conditioner prepared by the invention, the pH value of soil, the volume weight of the soil and the total amount of water-soluble salts can be remarkably reduced, meanwhile, the organic matters of the soil are increased, and the porosity of the soil is increased.

The invention relates to the field of purification treatment of potassium sulfate byproduct hydrochloric acid, and discloses a novel purification system and a purification method for potassium sulfate byproduct hydrochloric acid. The system comprises an adsorption unit, a feeding pipeline, a discharging pipeline and a regeneration pipeline, the adsorption unit comprises two stages of adsorption towers which are connected in series, the first-stage adsorption tower is filled with resin for adsorbing iron ions, and the second-stage adsorption tower is filled with resin for adsorbing free chlorine. The method based on the system comprises the following steps: enabling yellow A acid hydrochloric acid which is a byproduct generated in production of potassium sulfate by a Mannheim method to pass through the first-stage adsorption tower at a certain flow rate, and adsorbing to remove iron ions; the hydrochloric acid treated in the step S1 passes through a second-stage adsorption tower, and free chlorine is removed through adsorption; and collecting hydrochloric acid flowing out after treatment in the step S2 to obtain colorless and transparent purified hydrochloric acid. The method is high in efficiency and good in economical efficiency, clear and transparent A acid can be stably produced, the content of iron ions in the obtained purified hydrochloric acid is smaller than or equal to 5 ppm, and the content of free chlorine is smaller than or equal to 10 ppm.

The invention relates to the field of industrial waste gas treatment, and discloses a technology for removing NOx and SOs in industrial flue gas through an ultrasonic atomization wet method. The technology comprises the steps that S1, the industrial flue gas is cooled and dedusted; s2, performing oxidation washing on NO by using a first washing solution and a second washing solution respectively; s3, absorbing NOx and SOs generated by oxidation of the industrial flue gas by using an absorption liquid subjected to ultrasonic atomization; s4, carrying out demisting treatment on the industrial flue gas; a first washing solution in the step S2 is a 0.5-1.5 wt% potassium persulfate aqueous solution, and a second washing solution is composed of 1-2wt% of ferrous sulfate, 0.5-1wt% of EDTA and the balance of water; the absorption liquid in the step S3 is prepared from basic hydroxide, carbonate, an interface modifier and water. According to the ultrasonic atomization wet process, the solid precipitation amount of the absorption liquid is small, the NOx and SOabsorptivity is high, and equipment cannot be corroded after long-term use.

The invention discloses a regenerated carbon aggregation medium as well as a preparation method and application thereof, and belongs to the technical field of organic matter recovery. The preparation method comprises the following steps: by taking a carbon aggregation medium enriched with organic matters as a matrix and hydrochloric acid or a hydroxide modifier, carrying out hydrothermal reaction in a stirring state, filtering, drying and grinding to obtain hydrothermal regenerated carbon; and adding water into the hydrothermal regenerated carbon, adjusting the pH value to 2-7, heating to 50-70 DEG C, adding potassium persulfate and a methacryloyloxyethyl trimethyl ammonium chloride solution in a protective atmosphere, and carrying out graft copolymerization reaction on the hydrothermal regenerated carbon and methacryloyloxyethyl trimethyl ammonium chloride under the initiation action of potassium persulfate to obtain the regenerated carbon aggregation medium. The grafting rate, grafting efficiency and charge density of the prepared regenerated carbon aggregation medium can reach 7.76%, 7.96% and 1.132 mmol / g respectively, and the removal rates of COD (Chemical Oxygen Demand) and turbidity are 62.81% and 88.87% respectively.

The utility model relates to the technical field of potassium sulfate processing, and discloses a potassium sulfate processing reaction furnace, which comprises a baffle plate slidably connected to the top of the reaction furnace, and one end of the baffle plate penetrates through and extends into a feed pipe; the connecting plate is fixedly connected to the end, away from the feeding pipe, of the baffle; the threaded block is in threaded connection with the exterior of the lead screw, slidably connected to the top of the reaction furnace and fixedly connected with the end, away from the baffle, of the connecting plate. Sulfuric acid is injected into a feeding pipe, a power supply of a mixing mechanism and a servo motor is started, the servo motor drives a lead screw to rotate forwards and backwards according to a certain rule, a threaded block drives a baffle to reciprocate on the feeding pipe through a connecting plate, and when the baffle is gradually inserted into the feeding pipe, the circulation sectional area of the sulfuric acid is reduced, and the flow is correspondingly reduced; when the baffle gradually extends out of the feeding pipe, the circulation sectional area of the sulfuric acid is increased, the flow is correspondingly increased, the reciprocating movement of the baffle realizes the effect of reciprocating addition of the sulfuric acid, and the reaction uniformity is improved by matching with the mixing mechanism.

The invention relates to the technical field of plant cultivation, in particular to a high-survival-rate seedling transplanting method. The transplanting method comprises the following steps: classifying and screening nursery stocks to obtain screened nursery stocks; lifting the screened seedlings according to a preset soil ball diameter to obtain a seedling transport body; loading the nursery stock transportation body into a container containing a pretreated nursery substrate (perlite, dried chicken manure, peat soil, straw and decomposed sweet potato seedlings) to obtain a nursery stock transplanting body; transferring the nursery stock transplanting body into the planting ditch for bed arrangement operation to obtain a nursery stock transplanting bed body; performing early-stage management on the nursery stock transplanting bed body to obtain a nursery stock bed; in the early-stage management, a compound organic fertilizer (rape seed cake, sheep manure, humic acid, wheat straw, bentonite, boric acid, magnesium sulfate, ammonium sulfate, calcium superphosphate, potassium sulfate and water) is used for additional fertilization; transplanting and planting the nursery stock bed to obtain transplanted nursery stocks. According to the method, by constructing a technical closed loop of root system microenvironment restoration, gradient adaptation and precise nutrition, the transplanting survival rate of the seedlings can be effectively increased.

The application discloses a method and system for recycling dust removal ash of blast furnace manganese iron smelting, and first proposes a technical route for recycling carbon powder, fluorite, manganese fluoride, manganese sulfate, potassium bicarbonate, potassium sulfate, sodium chloride and other valuable resources by water washing of the dust removal ash of blast furnace manganese iron smelting. The water washing slag and washing wastewater of the dust removal ash of blast furnace manganese iron smelting are simultaneously treated in a cooperative manner, the process can be designed according to the characteristics of the washing wastewater and the water washing slag, the multistage recovery of the valuable resources is realized, new impurities are not introduced, and the added value of the recovered resources is improved. In addition, the whole process does not discharge wastewater and waste gas, has high economic value and meets the green and environment-friendly production requirements.

The invention belongs to the field of building materials, and particularly relates to an anhydrous gypsum-based terrazzo floor material and a preparation method thereof. The anhydrite-based terrazzo floor material is prepared from the following raw materials: anhydrite, quenched stone, building gypsum, ash calcium, potassium sulfate, calcium formate, a water reducing agent, a defoaming agent, rubber powder and hydroxypropyl methyl cellulose. The invention relates to a building material, which is prepared from the following raw materials in parts by weight: 525 to 550 parts of anhydrite, 350 to 450 parts of quenched stone, 30 to 40 parts of building gypsum, 15 to 20 parts of ash calcium, 4 to 7 parts of potassium sulfate, 0.5 to 0.8 part of potassium acid calcium, 1.5 to 2.0 parts of water reducing agent, 0.4 to 0.6 part of defoaming agent, 0.10 to 0.15 part of hydroxypropyl methyl cellulose and 6 to 8 parts of rubber powder. The anhydrous gypsum-based terrazzo floor material is high in early strength and low in cost compared with a cement-based inorganic terrazzo in a construction period. The development of companies is facilitated, and the product is more competitive in the market.

The application provides a quick-dissolving mixed fertilizer for improving soil and a preparation method thereof, and relates to the technical field of fertilizers.The quick-dissolving mixed fertilizer for improving soil comprises the following raw materials in parts by weight: urea 20-25 parts, diammonium phosphate 10-16 parts, potassium sulfate 12-14 parts, magnesium sulfate 3-4 parts, potassium humate 5-6 parts, lignin 4-5 parts, zinc oxide 0.1-0.3 parts, manganese sulfate 0.5-0.6 parts, ammonium molybdate 0.5-1 part, coating material 6-10 parts and water 10-12 parts.The quick-dissolving mixed fertilizer for improving soil has the advantages of balanced nutrition, good quick-dissolving property, high nutrient utilization rate and remarkable soil improvement effect.The popularization and application of the mixed fertilizer will help to improve the fertility level of farmland and promote the sustainable development of agriculture.

The application relates to the technical field of waste drilling fluid treatment, and discloses a modifier for treating water-based drilling waste and a preparation method thereof; according to weight parts, the raw materials of the modifier include 30-40 parts of potassium persulfate, 10-25 parts of ferric chloride, 20-40 parts of quaternary ammonium cation polymer and 10-20 parts of magnetized modified attapulgite clay. The modifier for treating water-based drilling waste provided in the application solves the problem of incomplete gel breaking in the water-based drilling waste treatment process through synergistic action of various components, forms an oxidation-catalysis-flocculation-magnetic separation four-stage synergistic treatment process, reduces the metal ion content in the liquid phase after solid-liquid separation, makes the liquid phase meet the drilling fluid water preparation requirement without further treatment, simplifies the treatment process and reduces the cost.

The invention discloses a method for enhancing compost humification synergistic gas emission reduction and tetracycline degradation through thermal activation peroxide, and relates to the technical field of compost. The method comprises the following steps: mixing livestock and poultry manure and 1-3cm crop straws according to a dry weight ratio of (1-3): 1, and adjusting the carbon-nitrogen ratio to (20-30): 1 to complete raw material pretreatment; when the temperature of the pile body is 25-35 DEG C, peroxide (hydrogen peroxide, peracetic acid or potassium persulfate) is sprayed and mixed uniformly in the form of an aqueous solution, the addition amount is 0.125-1.25% of the dry weight of the raw materials, the moisture content of the pile body is controlled to be 55-75%, and continuous or intermittent ventilation composting is carried out at the speed of 0.2-1.0 m < 3 > h <-1 >. According to the method, the peroxide is activated by utilizing self-produced heat of compost, external energy sources and chemical activators are not needed, triple effects of compost humification improvement, ammonia gas and greenhouse gas emission reduction and tetracycline degradation are realized, and the method is green, environment-friendly, low in cost and suitable for organic solid waste treatment.

The invention relates to the field of resource utilization of industrial solid wastes, in particular to a method for preparing battery-grade manganese sulfate by purifying industrial solid wastes, which comprises the following steps: by taking silicomanganese metallurgical fly ash as a raw material, grinding, alkaline leaching, heating reaction and centrifugal separation to obtain manganese-containing filter residues; and the battery-grade manganese sulfate is prepared through the steps of sulfuric acid neutralization, filter pressing, oxalic acid-manganese monoxide refining, evaporative crystallization and the like. According to the method, all-component high-value utilization of elements such as manganese, silicon and potassium in the fly ash is achieved, the raw material recovery rate reaches 99.7% or above, the purity of the prepared manganese sulfate is larger than or equal to 99.5%, meanwhile, by-products such as potassium sulfate, sodium chloride, aluminum hydroxide and sludge containing 80% of silicon dioxide are produced, and remarkable economic benefits and ecological benefits are achieved.

The application relates to preparation of indoor potted solid water and belongs to the field of solid water preparation. A preparation method is as follows: nitrogen is introduced into a four-necked flask for 10 min to remove air, wheat bran and wheat B starch wastewater are added, heating and stirring are carried out, sodium alginate and gellan gum are added to prepare A liquid; acrylic acid is neutralized by adding 25% NaOH solution under the condition of an ice water bath, after the neutralized liquid is cooled to room temperature, 2-acrylamide-2-methylpropanesulfonic acid, bentonite, methylene bisacrylamide and potassium persulfate are added to prepare B liquid; B liquid is slowly added into A liquid, heating and stirring are carried out to perform polymerization reaction, after the reaction is completed, filtration is carried out, anhydrous ethanol and distilled water are used for washing, and indoor potted special solid water is obtained. The indoor potted solid water provided by the application can provide convenience for office workers to maintain potted plants, can improve soil permeability and water absorption and water retention capacity, has a long use period, and is prepared by using natural degradable materials and has low cost.

This invention belongs to the field of complex pollutant removal technology in water bodies, and specifically relates to a microbial composite hydrogel, its preparation method, and its application. The microbial composite hydrogel, by weight, comprises: 1-3 parts polyvinyl alcohol, 3-8 parts polyethylene glycol, 2-6 parts sodium alginate, 0.05-0.08 parts nano-titanium dioxide, 10-25 parts CaCl2, 10-25 parts boric acid, 5-15 parts potassium persulfate, and *Bacillus velezensis*, wherein the concentration of *Bacillus velezensis* is 0.35 × 10⁻⁶. 8 -0.6*10 8 Cells / mL. The microbial composite hydrogel of this invention can effectively treat multiple pollutants in wastewater simultaneously, has a more efficient pollutant degradation capacity and a wider range of applications, and realizes comprehensive integrated treatment of food wastewater.

The application discloses a preparation method of organic garbage carbon source by composite enzyme combined with nitrogen precipitation. Firstly, enzyme pretreatment is performed on organic garbage materials, starch enzyme, cellulase and hemicellulase are used in cooperation to make macromolecular structure of organic matter be broken, so that preliminary release and partial dissolution of carbon source substances are realized; subsequently, sodium tetraphenylborate is added in the pretreatment system to selectively precipitate nitrogen substances in the solution, and centrifugal separation is performed to reduce nitrogen content of the system; on the basis, potassium persulfate and iron substances are added into the obtained suspension liquid to build a Fenton-like reaction system, residual organic macromolecules are further oxidized and degraded, and the structure is optimized, so that availability and stability of the carbon source are improved. In the whole process, each link cooperates, so that the organic garbage can be efficiently converted into high-quality carbon source with high C / N ratio and COD value, and can be used in a sewage treatment system as stable external carbon source.

The invention provides a flow battery containing a thiosulfate and potassium sulfide mixed electrolyte, a negative electrode electrolyte is a mixed solution formed by dissolving thiosulfate and potassium sulfide in a supporting electrolyte solution, the concentration of thiosulfate ions (S2O3 < 2->) is 0.1-2 mol / L, and the molar ratio of potassium sulfide (K2S) to potassium thiosulfate (K2S2O3) ranges from 1: 0.2 to 1: 2; and the supporting electrolyte is an alkaline or neutral electrolyte solution with the concentration of 1-3 mol / L. By introducing thiosulfate radical (S2O3 < 2->), the thiosulfate radical and elemental sulfur form a soluble polythiosulfate complex in a negative electrode electrolyte, solid sulfur deposition is effectively inhibited, and the problems of electrode pore blockage, flow channel blockage, active substance loss and the like caused by solid sulfur deposition in an existing polysulfide or sulfide system flow battery are solved.

The invention discloses a nutrient element combined application combination for improving yield and quality of pinellia ternate and an application method. The nutrient element combined application combination comprises urea, calcium superphosphate, potassium sulfate, EDTA chelated copper, disodium octaborate tetrahydrate and sodium molybdate. The application method comprises the following steps: applying nitrogenous fertilizer and phosphatic fertilizer during sowing in April, applying nitrogenous fertilizer, phosphatic fertilizer, potash fertilizer, copper fertilizer, boric fertilizer and molybdenum fertilizer from June to July, and applying potash fertilizer, copper fertilizer, boric fertilizer and molybdenum fertilizer in August; according to the method, orthogonal experimental design is adopted, the nutrient element combined application combination most suitable for pinellia ternata production is obtained, the application method of the combined application combination designed by the invention is simple, convenient and easy to control, the yield of pinellia ternata can reach a relatively high level, the yield is 14619.42 kg: hm <-2 >, and the difference (P is less than 0.5) between the yield and the highest yield (14901.40 kg. Hm <-2 >) of the element combined application combination is not obvious.

A fertiliser product comprising potassium sulfate (sulfate of potash or “SOP”) and boron, wherein the amount of boron is equivalent to 0.2 to 3.0 wt. % B.

The present application relates to the technical fields of catalyst design and ammonia synthesis, and discloses a preparation method of a pyrazole trinuclear cobalt-based catalyst, which comprises the following steps: step 1, dissolving a metal cobalt compound in water to obtain a first mixed solution, dissolving a pyridine molecule in a mixed organic solution to obtain a second mixed solution, mixing and stirring the first mixed solution and the second mixed solution, and then transferring the mixture to a high-vacuum reaction tube, and then placing the high-vacuum reaction tube in an oil bath to perform a solvothermal reaction; step 2, after the solvothermal reaction is completed, washing, centrifuging and drying the obtained substance to obtain a trinuclear cobalt-based compound powder. The present application uses nitrate as a nitrogen source, a pyrazole cobalt-based compound as a catalyst, and a mixture of potassium sulfate and potassium nitrate as an electrolyte, and effectively synthesizes ammonia through electrochemical reduction. The catalyst exhibits high Faraday efficiency and high yield under high-concentration nitrate conditions.