777 results about "Glutaraldehyde" patented technology

The invention discloses a preparation method of a degradable transparent conductive polymer film, and belongs to the technical field of film preparation. Preparing dispersion liquid I through graphene oxide quantum dots; preparing a dispersion liquid II from polyaniline nanofibers; dissolving pyrrole and toluenesulfonic acid in N, N-dimethylformamide to prepare a reaction solution, adding the dispersion liquid I and the dispersion liquid II, stirring, and adding ferric chloride hexahydrate to obtain a reaction solution; adjusting the pH value of the reaction solution to 1.5, and heating to obtain a polypyrrole solution; preparing cellulose acetate, polyvinyl alcohol and N, N-dimethylformamide to obtain a cellulose acetate solution; mixing the polypyrrole solution and the cellulose acetate solution, adding glutaraldehyde to obtain a mixed solution, and pouring the mixed solution into a mold to prepare a composite wet film; and putting the composite wet film into a hot-pressing forming machine for hot-pressing to generate the polymer film. The conductive polymer film prepared by the invention can be applied to the fields of supercapacitor electrode materials, electromagnetic shielding materials, flexible sensors and the like, and provides a new high-performance material choice for the development of related fields.

The invention discloses a solar interface evaporator and a preparation method and application thereof. The evaporator comprises a porous cellulose supporting layer and a photo-thermal composite hydrogel layer loaded on the cellulose supporting layer, and the porous cellulose supporting layer and the photo-thermal composite hydrogel layer are combined in a gel in-situ cross-linking mode to form an integrated composite structure. The photo-thermal composite hydrogel layer is composite hydrogel formed by cross-linking polyvinyl alcohol, chitosan quaternary ammonium salt and carbon black. The preparation method comprises the following steps: adding polyvinyl alcohol and chitosan quaternary ammonium salt into a solvent to form a transparent mixed solution, adding the carbon-based photothermal conversion material, and continuously heating and stirring to prepare a hydrogel precursor solution; then adding glutaraldehyde and hydrochloric acid, and carrying out cross-linking reaction to form a hydrogel system; and immersing the cellulose sponge, standing, circularly and alternately freezing and unfreezing, and finally freeze-drying to obtain the product. The evaporator disclosed by the invention integrates highlight absorption, high heat utilization, water transportation, salt resistance and antibiosis, can realize large-scale production, and is suitable for scenes such as seawater desalination, sewage purification and emergency water supply.

The invention relates to the field of drain pipes, and discloses an antibacterial polypropylene noise-reduction drain pipe and a preparation method thereof, the antibacterial polypropylene noise-reduction drain pipe comprises polypropylene, modified glass fiber, an antibacterial additive, a compatilizer and a stabilizer; the modified glass fiber is prepared by performing formylation modification on glass fiber by using 3-aminopropyltriethoxysilane and glutaraldehyde, grafting triethylene tetramine and DOPO into a glass fiber structure, and then grafting a hindered phenol antioxidant; the antibacterial additive is prepared by compounding chitosan Schiff base and modified nano titanium dioxide, the chitosan Schiff base is prepared by utilizing a Schiff base reaction between chitosan and vanillin, and the modified nano titanium dioxide is prepared by utilizing isocyanate propyl triethoxy silane and ethyl glycolate to modify nano titanium dioxide. By adding the modified glass fiber and the antibacterial additive, the pipe is endowed with excellent heat resistance, aging resistance, flame retardance and antibacterial performance.

The invention relates to the technical field of wastewater treatment, in particular to a multistage composite adsorbent for treating petrochemical wastewater and a preparation method thereof.The preparation method comprises the steps that S1, plant straw powder and 3-aminopropyltriethoxysilane are subjected to a constant-temperature reaction, and aminated plant straw is obtained; s2, carrying out hydrothermal reaction on the aminated plant straw and a cerium nitrate solution to obtain functionalized plant straw; s3, the halloysite nanotubes, glutaraldehyde and the functionalized plant straw are stirred for a reaction, high-temperature carbonization is conducted after the reaction is completed, and composite biochar is obtained; s4, carrying out a reaction on the composite biochar and an amino silane coupling agent to obtain aminated composite biochar; s5, calixarene, toluene diisocynate and the aminated composite biochar are subjected to a reaction, and the multi-stage composite adsorbent is obtained. According to the technical scheme, the comprehensive adsorption capacity and removal efficiency of various organic pollutants in the petrochemical wastewater are improved, and the defect that a traditional adsorbent is poor in selectivity is overcome.

The invention discloses a fruit and vegetable exosome extraction method based on ligand fishing. The fruit and vegetable exosome extraction method comprises the following steps: suspending amino-functionalized Fe3O4 (at) SiO2 nanoparticles in a glutaraldehyde solution, and adding activated agglutinin to obtain Fe3O4 (at) SiO2-agglutinin nanoparticles; adding a glutaraldehyde solution into agarose gel to obtain a size exclusion chromatographic column filler; the method comprises the following steps: dispersing Fe3O4 (at) SiO2-lectin nanoparticles in a PBS buffer solution to obtain a uniform suspension, adding the uniform suspension into a size exclusion chromatographic column filler to obtain a uniform slurry, filling the size exclusion chromatographic column with the uniform slurry, and flushing with the buffer solution to form a magnetic bead stationary phase; and loading fruit and vegetable supernatant into a size exclusion chromatographic column, passing through the magnetic bead stationary phase, cleaning residual impurities combined on the exosome-magnetic bead compound by using a buffer solution, and dissociating the exosome from the magnetic beads by using a competitive eluent of the exosome to obtain the high-purity fruit and vegetable exosome. The problem that an existing exosome extraction method is difficult to meet the requirements of high efficiency, simplicity, high purity and high activity at the same time is solved.

The invention discloses a sixteen-hole multifunctional polyester staple fiber and a preparation method thereof, and relates to the technical field of functional fibers. Sodium alginate is used as a skin layer, polyethylene glycol terephthalate is used as a core layer, functional layering is achieved through skin-core compounding, and the interface bonding force between sodium alginate and polyethylene glycol terephthalate is enhanced through glutaraldehyde; in the melting processing process of polyethylene glycol terephthalate, a chain extender is used for reducing the melting point of the polyethylene glycol terephthalate so as to reduce the pyrolysis risk of sodium alginate, meanwhile, a low-polarity lubricant is used for grafting zirconium carbide so as to balance the lubrication and enhancement functions and realize far infrared and antistatic properties, and then an aniline monomer is initiated to polymerize on the surface of zirconium carbide so as to prepare the far infrared anti-static polyethylene glycol terephthalate composite material. Seaweed-carbon can generate far infrared radiation and negative ions, and zirconium carbide can be used as an electron acceptor to enhance the carrier mobility, so that the far infrared and antistatic properties of the fiber are enhanced.

The invention relates to the field of biological agents, in particular to a compound probiotic preparation rich in organic selenium and a preparation method of the compound probiotic preparation, and efficient synergistic delivery is achieved through plant micromolecule organic selenium extraction and a multi-layer microemulsion embedding technology. The preparation consists of a core active component, a carrier system and a curcumin compound. The plant micromolecular organic selenium is extracted from cardamine hupingshanesis and high-selenium corn flour through an HLUP technology, and the bioavailability is remarkably improved. A corn protein modified W / O / W microemulsion is adopted as a carrier, an outer layer membrane is stable in an acid environment, and an inner layer accurately releases selenium to small intestines; a protective agent composed of trehalose and glucose inhibits ice crystal damage, and glutaraldehyde crosslinking enhances the mechanical strength of the membrane. Curcumin and selenium synergistically enhance antioxidant and immunomodulatory functions, and promote phagocytic activity of macrophages. The stability and bioavailability bottlenecks of a traditional preparation are broken through, and an innovative scheme is provided for functional food development.

The invention relates to the technical field of biology, in particular to a sample preservation solution for vagina micro-ecology detection and a preparation method of the sample preservation solution. The invention relates to a sample preservation solution for vaginal micro-ecology detection. The sample preservation solution comprises the following components in percentage by mass: 0.5-0.9% of paraformaldehyde, 0.08-0.12% of glutaraldehyde, 10-18% of a buffer solution, 0.1-0.4% of inositol, 1-10% of a stabilizer, 0.8-5% of a cell treatment agent and the balance of water, the stabilizing agent is prepared from sodium alginate, tween-20 and beta-cyclodextrin. The invention aims to solve the problems of high false negative and false positive rate or difficulty in interpretation caused by liquid-based cell accumulation, unstable subsequent dyeing and decoloration time and the like of a cell preservation solution in the prior art, so that the sample preservation solution for sample cells can keep the forms of cells, protozoa and the like unchanged, and ensures that gram staining negative and positive properties of bacteria and fungi are not changed. The staining and decoloring are relatively stable, the false negative and false positive rate of sample cell detection is effectively reduced, and the sample cell lesion detection and judgment are more accurate.

The invention provides a microbial slow-release porous composite material for sewage treatment as well as a preparation method and application thereof. The preparation method comprises the following steps: dropwise adding an organic ligand solution into a precursor solution consisting of a nanocellulose solution and a cobalt source solution; mixing the reaction solution with polyvinyl alcohol, injecting the mixture into a mold, and performing directional freezing to obtain an aerogel matrix; carrying out hydrophobic modification on the aerogel matrix to obtain a modified aerogel matrix; mixing the microbial suspension with sodium alginate, and homogenizing at high pressure to obtain a gel precursor emulsion; the preparation method comprises the following steps: dropwise adding a calcium chloride solution to gelatinize to obtain gel particles, and then cross-linking and drying by glutaraldehyde to obtain sustained-release capsule particles; dispersing the sustained-release capsule particles in deionized water to obtain dispersion liquid; and dipping the modified aerogel matrix in the dispersion liquid. An aerogel matrix with a hierarchical porous structure is compounded with a sustained-release capsule with a pH response mechanism, so that physical adsorption, chemical catalysis and biodegradation for sewage treatment are realized.

The invention relates to the technical field of fertilizers, and discloses a slow-release coated fertilizer and a preparation method thereof. Comprising the following raw materials in parts by weight: 57 to 77.6 parts of urea, 14.25 to 24.25 parts of diammonium phosphate, 0 to 5 parts of calcium superphosphate, 4.75 to 14.55 parts of potassium chloride, 0.03 to 0.2 part of chitosan, 0.0075 to 0.05 part of nano silicon dioxide, 0.001 to 0.015 part of glutaraldehyde, 2.96 to 4.94 parts of deionized water, 0.01 to 0.1 part of bacillus subtilis, 0.05 to 0.2 part of mesoporous silicon dioxide loaded nano selenium and 0.5 to 1 part of potassium fulvate. Chitosan, nano silicon dioxide and glutaraldehyde are matched with one another, and chitosan has pH responsiveness, so that the problems that a coating layer of a traditional slow-release fertilizer is prone to being affected by the environment and broken in advance, nutrients are rapidly released, and the slow-release effect is reduced are solved.

The invention discloses a biomass-inorganic-organic ternary composite flocculant and a preparation method and application thereof, and belongs to the field of coking wastewater treatment.The preparation method comprises the steps that chitosan serves as a substrate material, glutaraldehyde serves as a cross-linking agent, and polyferric sulfate (PFS) and chitosan are subjected to chemical cross-linking to generate an intermediate product PFS and chitosan composite particles; then potassium persulfate is used as an initiator, graft copolymerization of acrylamide and methacryloyloxyethyl trimethyl ammonium chloride is initiated through hydroxyl on the surface of PFS-chitosan, a cationic branched chain is introduced, and a final product is obtained. Through multi-component cooperation and structural design, the defects that a traditional flocculating agent is not thorough in demulsification, large in sludge amount, unstable in floc combination and the like in coking wastewater treatment are overcome, and the flocculating agent is particularly suitable for treating oil pollutants in coking wastewater.

The invention relates to the technical field of natural polymer material processing, and discloses a cross-linked composite chitosan solution which is composed of the following components in percentage by mass: 1%-5% of chitosan, 0.1%-5% of a cross-linking agent, 0.1%-5% of acetic acid and the balance of water, and the cross-linked composite chitosan solution is prepared from the following components in percentage by mass: 1%-5% of chitosan, 0.1%-5% of a cross-linking agent, 1%-5% of acetic acid and the balance of water. The cross-linking agent is one or more of glutaraldehyde, citric acid and epoxy chloropropane. According to the cross-linked composite chitosan solution and the preparation method of the chitosan fiber of the cross-linked composite chitosan solution, the adaptability of the cross-linked composite chitosan solution in a human body can be further improved and the immunoreaction can be reduced through a cross-linking reaction, so that the enhancement of the biocompatibility of the cross-linked composite chitosan solution can be ensured; by selecting different cross-linking agents and controlling the cross-linking degree, the biodegradation rate of the chitosan can be adjusted to a certain extent, so that the chitosan is more suitable for specific medical or environmental application requirements, and in addition, the water resistance of the chitosan can be remarkably improved through the cross-linking effect.

The invention relates to the field of biomedical materials, and particularly discloses a combined biovalve material anti-calcification method and a biovalve material. A combined bioprosthetic valve material anti-calcification method comprises the following steps: taking an animal-derived biological material, cleaning, removing adipose tissue, cutting a precordial region part to obtain a pericardium material, and storing the pericardium material in ice normal saline for later use; mixing the pericardium material and the decellularized treatment fluid A, oscillating and cleaning; adding the pericardium material into the decellularized treatment solution B, oscillating and cleaning; carrying out crosslinking treatment by utilizing a glutaraldehyde pericardium material; adding the crosslinked pericardium material into a reducing agent solution, oscillating and cleaning; the method comprises the following steps: putting a pericardium material into a glycerol-ethanol mixed solution or a glycerol-isopropanol mixed solution, and soaking for more than 24 hours; according to the anti-calcification method, on the basis that the mechanical property of the valve material is effectively maintained, the anti-calcification performance is improved, and the durability of the valve material is improved.

The invention belongs to the technical field of nanometer materials, and designs an ultra-long silver nanowire and a preparation method and application thereof.The raw materials of the preparation method comprise a reducing agent, a solvent, an etching agent and a passivator, a hydrothermal method is adopted, the reducing agent is one or more of glutaraldehyde, butanedialdehyde, adipaldehyde, heptanedialdehyde and octanedialdehyde, the solvent is water, and the etching agent is an organic solvent; the etching agent is soluble metal salt which contains chloride ions and does not contain iron ions; the maximum length of the prepared ultra-long silver nanowire is 185 to 786 m, and the length-diameter ratio of the prepared ultra-long silver nanowire is 1927 to 10077; according to the application, the ultra-long silver nanowire is used for preparing a flexible transparent conductive electrode. According to the method, the separation-free ultra-long silver nanowire can be prepared in a short time, the process is simple, the cost is low, and devices such as transparent conductive electrodes with high light transmittance can be prepared on the flexible substrate.

The invention belongs to the technical field of fire-extinguishing building materials, and discloses a microencapsulated efficient automatic fire-extinguishing patch and a preparation method thereof.The fire-extinguishing patch contains a fire-extinguishing microcapsule, the fire-extinguishing microcapsule is of a double-layer structure, the inner layer contains gelatin, kaolin, perfluorohexanone, sodium hexametaphosphate, resorcinol and glutaraldehyde, and the outer layer contains gelatin, kaolin, perfluorohexanone, sodium hexametaphosphate, resorcinol and glutaraldehyde; and the outer layer comprises a vinylidene fluoride-acrylic acid copolymer and glutaraldehyde. According to the invention, the flaky kaolin is used for enhancing the formaldehyde-free phenolic aldehyde inner layer and the vinylidene fluoride-acrylic acid copolymer outer layer to form a double-layer shell layer with high air tightness, so that the compactness and long-term stability of the shell layer of the microcapsule are greatly improved.

The invention belongs to the technical field of membrane separation, and particularly relates to a method for preparing a high-flux hollow fiber nanofiltration membrane based on interfacial polymerization, the obtained membrane and application. The method comprises the following steps: firstly, carrying out pre-adsorption treatment on a polyethersulfone hollow fiber ultrafiltration base membrane through a polyethyleneimine aqueous solution to form a reactive anchoring layer; then sequentially dipping in an aqueous phase solution containing piperazine, sodium phytate and nanoscale cellulose whiskers and an organic phase solution containing trimesoyl chloride and 5-isocyanate isopeptide acyl chloride for interfacial polymerization; and finally, carrying out heat treatment on the obtained primary composite membrane, and completing a gas-phase cross-linking reaction in a glutaraldehyde steam atmosphere. According to the method, the hollow fiber nanofiltration membrane with high flux, high selectivity, excellent chlorine resistance and pollution resistance is successfully prepared through a multi-stage strengthening process, and the hollow fiber nanofiltration membrane is suitable for the fields of drinking water purification, industrial wastewater reuse, material separation and the like.

The invention discloses a PVA / urea / CC lignocellulose composite mulching film as well as a preparation method and application thereof, and belongs to the technical field of agricultural mulching films. The composite mulching film disclosed by the invention is obtained by adding PVA (Polyvinyl Alcohol) into a corncob lignocellulose HTP-CC dispersion liquid subjected to hydrothermal pretreatment, then sequentially adding glutaraldehyde, urea and glycerol and carrying out cross-linking reaction. The mechanical property of the PUCH mulching film prepared by the invention meets the GB / T35795-2017 standard, and the PUCH mulching film has excellent water vapor barrier property, ultraviolet shielding property, urea controlled release property, heat insulation property and biodegradability. The characteristics not only can promote crop growth, but also can reduce agricultural environmental pollution. Therefore, the PUCH mulching film shows huge potential to replace the traditional plastic mulching film, and has important application prospects in agricultural planting.

A technology for preparing glutaraldehyde through cyclopentene oxidation belongs to the technical field of organic synthesis, glutaraldehyde is prepared through cyclopentene oxidation by adopting a photocatalysis-electrocatalysis synergistic catalyst g-C3N4 / TiO2 (at) Au-Co / N-G. The catalyst is of a unique core-shell structure, is stable in property, promotes an oxygen reduction reaction in a catalysis technology, and has good catalytic activity. The conversion rate of cyclopentene and the selectivity of glutaraldehyde are remarkably improved, and the effect is remarkable.

The invention belongs to the technical field of aerogel, and discloses MXene-based aerogel and a normal-pressure preparation method and application thereof.The preparation method comprises the steps that mixed dispersion liquid of chitosan and conductive filler is mixed with glutaraldehyde, standing and crosslinking are conducted, and hydrogel is obtained; in the hydrogel, the conductive filler accounts for 20-75% of the mass of a solid substance, the chitosan accounts for 15-55% of the mass of the solid substance, and the glutaraldehyde accounts for 1-20% of the mass of the solid substance; the filler is selected from MXene, a carbon nano tube, graphene, boron nitride or MOF (Metal Organic Framework); the hydrogel is frozen at the temperature ranging from-20 DEG C to-80 DEG C; and carrying out normal pressure drying on the frozen hydrogel at 25-80 DEG C to obtain the aerogel. The solvent exchange-free normal-pressure drying preparation process breaks through the limitation of solvent exchange on the size, the high cost of a large amount of solvent is saved, large-area extensible preparation can be realized on the basis of energy conservation and environmental protection, and meanwhile, the prepared aerogel has relatively high mechanical strength, and the application range is widened.

The invention relates to the technical field of biomedical materials, and discloses a polyvinyl alcohol and chitosan composite hydrogel and a preparation method thereof, the polyvinyl alcohol and chitosan composite hydrogel comprises the following components by weight: 6-10 parts of polyvinyl alcohol; 1 to 3 parts of chitosan; 0.5 to 1.5 parts of glutaraldehyde; 100 to 150 parts of acetic acid; 0.01 to 0.1 part of hydrochloric acid or sodium hydroxide; 0.01 to 1 part of sodium chloride; the hydrogel is of a three-dimensional network structure formed by a cross-linking reaction of polyvinyl alcohol and chitosan through glutaraldehyde, the concentration of glutaraldehyde is 0.25 mol / L, the volume of glutaraldehyde is 4 ml, and the cross-linking reaction of the hydrogel is carried out under the condition that the pH is 5.5-6.5. By constructing a glutaraldehyde difunctional bridging crosslinking mechanism and a dual-network synergistic structure and combining with a pH precise regulation and control and constant-temperature drying strategy, the mechanical property, rehydration property and structural stability of the hydrogel are remarkably improved.

The invention relates to the field of material chemistry on-line detection, in particular to a 1, 2, 4-trichlorobenzene on-line detection material and a preparation method thereof, and provides a film-forming sensitive layer material capable of being coated on the surface of a transducer, and the film-forming sensitive layer material comprises chitosan, a crosslinking component with the content of 0.1-5wt% in terms of glutaraldehyde and magnetic core-shell molecularly imprinted particles after being dried, the magnetic core-shell molecularly imprinted particle contains a ferroferric oxide magnetic inner core, a silicon dioxide middle layer and a molecularly imprinted polymer shell layer, and the shell layer is a cyclodextrin methacrylate and ethylene glycol dimethacrylate copolymer network and takes 1, 2, 4-trichlorobenzene as a template. The material keeps the membrane integrity and long-term stability under the working conditions of circulation and regeneration and also gives consideration to quick response, and the residual 1, 2, 4-trichlorobenzene is controlled to be not greater than 0.10 wt% and the residual glutaraldehyde is controlled to be not greater than 0.5 wt%. The method is used for relieving structural mass transfer contradiction and processing and coating coupling contradiction caused by high filler load, and has online detection application value.

The invention relates to the field of printing inks and discloses a wear-resistant and scratch-resistant printing ink, a preparation method thereof, and an application thereof. The printing ink comprises: a modified aqueous polyurethane emulsion, a modified mica sheet, a pigment, an additive, and deionized water; the modified aqueous polyurethane emulsion is prepared by introducing a double-terminal hydroxyl chain extender into a polymer; the double-terminal hydroxyl chain extender is reacted with a Schiff base intermediate obtained by reacting salicylaldehyde and p-aminobenzyl alcohol and isocyanoethyl methacrylate, and the obtained double-bonded Schiff base intermediate is reacted with 1,1,3,3-tetramethyldisiloxane to prepare the ink; the modified mica sheet is reacted with triethylenetetramine, formaldehyde, and acetone, and then formaldehyde is added under alkaline conditions for polycondensation, the obtained cationic polymer and glutaraldehyde are prepared into the cationic mica sheet, and finally polyaniline is grown on the surface of the mica sheet through interfacial polymerization. The ink prepared by the invention has good adhesion, high hardness, and excellent water resistance, wear resistance, heat resistance, antistatic properties, and antibacterial properties.

The invention discloses green leaf-imitated porous hydrogel as well as a preparation method and application thereof, and belongs to the technical field of hydrogel materials. The preparation method of the green leaf-imitated porous hydrogel comprises the following steps: mixing polyvinyl alcohol, tannic acid and a composite pigment in a solid state, and grinding to form uniformly dispersed mixed powder; then spraying a glutaraldehyde solution to the mixed powder, carrying out a cross-linking reaction at room temperature, and washing after the reaction to obtain hydrogel; soaking the hydrogel in a lithium chloride solution, and taking out the hydrogel after soaking to obtain the green leaf-imitated hydrogel with the automatic moisture absorption function; the hydrogel has a porous structure, can automatically absorb moisture and simulate a vegetation spectrum in a 400-2500nm wave band at high precision, is suitable for covering the surface of fabric or equipment so as to simulate the spectrum and thermal characteristics of vegetation, and can be widely applied to the field of infrared camouflage.

The invention belongs to the technical field of asphalt preparation, and provides a high-modulus composite modified asphalt material based on natural asphalt and a preparation method thereof. The method comprises the following steps: separating natural asphalt into a high-molecular asphaltene section and a medium-low-molecular colloid section, and preparing activated asphaltene and colloid sections through alkali treatment and spray drying; a styrene-butadiene-styrene block copolymer and a polyurethane prepolymer are taken as the basis, and a dynamic cross-linked polymer is synthesized through the steps of hydrazide treatment, boric acid group introduction, glutaraldehyde cross-linking and the like; organic modified clay and phenylated chitosan are prepared, a polyaniline composite material is prepared through in-situ polymerization of aniline, a PANI-clay-biomass compound is obtained, the ultraviolet absorption characteristic of polyaniline and the shielding effect of montmorillonite cooperate, the ultraviolet aging resistance of the material is improved, through multi-stage temperature control dispersion, the anti-aging performance of the material is improved, and the anti-aging performance of the material is improved. The various modified materials are compounded with a natural asphalt substrate to obtain the high-modulus composite modified asphalt material based on the natural asphalt.

The invention belongs to the technical field of water treatment, and particularly relates to a preparation method and application of a PDA / CS composite adsorbent loaded with a bimetallic system, and the preparation method comprises the following steps: 1) dissolving dopamine in a Tris buffer solution to prepare a dopamine prepolymer solution; then adding FeCl3, and carrying out constant-temperature water bath; centrifuging the obtained black suspension, performing suction filtration, washing, collecting a filter cake, and performing freeze drying to obtain PDA microspheres; 2) dispersing PDA microspheres in deionized water, and carrying out ultrasonic treatment until the PDA microspheres are uniformly dispersed; 3) dissolving chitosan in an acetic acid solution, and adding CuCl2 to prepare a mixed solution; the suspension obtained in the step 2 is dropwise added into a mixed solution for constant-temperature water bath, the pH of the mixed solution is adjusted through a NaOH solution, glutaraldehyde is added for constant-temperature water bath after constant-temperature water bath, and 4, the obtained suspension is subjected to centrifugation, suction filtration, washing, filter cake collection and freeze drying.

The invention belongs to the technical field of temporary plugging agents, and relates to a medium-temperature drilling fluid nano temporary plugging agent and a preparation method thereof. The temporary plugging agent is prepared from the following raw materials in parts by mass: 10 to 15 parts of small-particle-size coated silicon dioxide, 15 to 20 parts of medium-particle-size coated silicon dioxide, 30 to 50 parts of large-particle-size coated silicon dioxide, 15 to 20 parts of fiber, 5 to 8 parts of polyether diglycidyl ether, 5 to 8 parts of hyperbranched polyethyleneimine, 1 to 1.5 parts of water-soluble cellulose and 0.5 to 1 part of cationic quaternary ammonium salt. The coated silicon dioxide takes chitosan and glutaraldehyde as wall raw materials and silicon dioxide as a core material, and the particle size of the small-particle-size core material is 0.3-1 mu m; the particle size of the medium-particle-size particle core material is 150-250 microns; the particle size of the large-particle-size particle core material is 250-350 microns, the coated silicon dioxide particles are bonded together through a microscopic interpenetrating network formed by the reaction of hyperbranched polyethyleneimine and polyether diglycidyl ether, and the particles are matched with fibers to improve the bearing strength.

The invention discloses a super-hydrophobic chitosan aerogel PDMS (at) Co-PBA / CS and an application of the super-hydrophobic chitosan aerogel PDMS (at) Co-PBA / CS in oil-water separation. Adding Co-PBA into a chitosan aqueous solution, and then adding PVA; adding acetic acid and glutaraldehyde into the obtained mixed solution, stirring in a water bath, and freeze-drying to obtain Co-PBA / CS aerogel; and dissolving a hydrophobic material and a curing agent in an organic solvent, stirring to obtain a uniform suspension, immersing the Co-PBA / CS aerogel into the suspension, and carrying out vacuum drying to obtain PDMS-coated Co-PBA / CS. The super-hydrophobic chitosan aerogel PDMS (at) Co-PBA / CS prepared by the preparation method disclosed by the invention has relatively high adsorption capacity on both organic solvents and oil, and the removal efficiency is close to 100%. In addition, the composite material also has excellent self-cleaning and photo-thermal conversion performance, and can realize surface cleaning and removal of high-viscosity oil. The multifunctional aerogel provides a new strategy for removing pollutants such as oil in a complex and severe water environment.

The invention provides an adsorption material and a preparation method and application thereof, the adsorption material comprises a carrier and an endotoxin affinity binding ligand, the endotoxin affinity binding ligand comprises a recombinant C factor protein, and the carrier and the recombinant C factor protein are connected through a spacer arm; wherein the carrier comprises at least one of resin, chitosan, cellulose, agarose and glucan; the spacer arm comprises at least one of modified polyethylene glycol, polyvinyl pyrrolidone, polymethylacrylic acid-2-hydroxyethyl ester, polyvinyl alcohol, polyacrylic acid, hexamethylenediamine, divinyl sulfone and glutaraldehyde, and at least one end of the modified polyethylene glycol is provided with carboxyl, aldehyde or amino. The adsorption material provided by the invention can efficiently adsorb endotoxin, has the characteristics of low toxicity risk and excellent blood compatibility, and can improve the safety of blood purification.

This invention belongs to the field of silica technology, specifically relating to a method for preparing silica composite materials: silica microspheres or a silica mixture are added to a chitosan solution, followed by the addition of a PEI aqueous solution and stirring. A glutaraldehyde solution is then added, and the mixture is stirred again to obtain a gel-like product, which is then dried to obtain the silica composite material. The silica mixture includes a silica sponge-skeletal mixture, which is prepared by adding sponge-skeletal needles to a silica sol. This invention simplifies the preparation process of silica composite materials and improves the synergistic effect between silica and the matrix.

The invention relates to a chitosan-collagen synergistic self-assembly fiber material and a preparation method thereof, and belongs to the technical field of biological fiber materials. According to the method, the mass ratio of chitosan to collagen is controlled, co-assembly is induced through hydrogen bonds and electrostatic interaction in a low-temperature PBS solution, and then glutaraldehyde crosslinking, gradient dehydration and supercritical drying are performed to prepare the freeze-dried fiber. The obtained material completely retains the triple helix conformation of collagen, and has excellent conformation stability and enzymolysis resistance. The mechanical strength of the composite fiber is remarkably improved, and the composite fiber has excellent antibacterial property and cell affinity. The process does not need a toxic cross-linking agent, the operation is simple and convenient, and the prepared fiber is suitable for the high-end biomedical fields of tissue engineering scaffolds, intelligent antibacterial dressings, degradable nerve conduits and the like.