The invention discloses a
titanium-base tubular
ruthenium dioxide
coating membrane
electrode and a preparation method thereof. According to the preparation method, a
titanium filter
pipe is utilized to replace a primary
titanium plate to be taken as a matrix, and as numerous holes with the bore diameters of several microns are formed in the surface of the titanium filter
pipe, compared with the normal
titanium plate, the specific surface area is increased; and a firmly-bonded, uniformly-dispersed, surface-compacted and crack-free
ruthenium dioxide
thin layer is formed at the surface of the titanium filter
pipe by utilizing a
thermal oxidation method, and an
oxide film can be firmly bonded with the titanium filter pipe after being subjected to the
thermal oxidation. The
electrode prepared by utilizing the preparation method has the advantages of firm
coating structure, good electro-catalytic property and the like; the
chlorine evolution potential of the
ruthenium dioxide
electrode is low, so that the
chlorine is beneficially separated out; meanwhile, the operation of the preparation process is easy to control, the cost is low, the device requirements are relatively low, and the prepared electrode has double functions of electrochemical oxidation and membrane separation. Due to a
diffusion action, the electrochemical oxidation efficiency can be improved, and meanwhile, the membrane
pollution can be reduced due to the electrochemical oxidation, so that pollutants which are difficult to be biologically degraded can be more effectively processed.