The invention provides a method for simultaneously detecting various micro-plastics in water, and belongs to the technical field of micro-plastic detection. The method comprises the steps of sample pretreatment, thermal
cracking-
gas chromatography-
mass spectrometer measurement,
qualitative analysis and quantitative analysis. The method comprises the following steps: taking a
water sample, uniformly shaking, filtering with a filter membrane, taking the filtered filter membrane, adding
acetone, carrying out ultrasonic
elution, washing the filter membrane, and collecting an eluent; adding
acetone into the eluted filter membrane, carrying out ultrasonic
elution again, washing the filter membrane, collecting the eluent, combining the two eluents, heating and concentrating in a water bath, adding
acetone, ultrasonically mixing, transferring into a
cracking cup, heating and volatilizing, and determining by a thermal
cracking-
gas chromatography-
mass spectrometer. Carrying out
qualitative analysis through analysis of cracking products with different types of micro-plastic characteristics, and then carrying out quantification through an external standard method; the method provided by the invention can accurately quantify the six
microplastics in the
effluent, and has the advantages of simple pretreatment, small sampling amount, high accuracy and lowest
detection limit of 0.012 [mu] g / L.