The invention relates to an HHOF-TGU307 enhanced
acrylic acid adhesive as well as a preparation method and application thereof, and belongs to the technical field of macromolecular functional materials. Aiming at the problem that the existing
acrylic acid adhesive is difficult to meet the high-
performance requirement in the aspects of
bonding strength and
mechanical property, and particularly the defects of insufficient
bonding strength, easy aging, interface failure and the like in the emerging application fields of
new energy and the like, HOF-TGU307 (
hydrogen bond organic framework) is introduced into an
adhesive system; the cohesive force and the adhesion capacity with a base material are obviously improved. The HOF-TGU307 material is a novel crystalline organic porous material with high specific surface area, high
crystallinity and adjustable aperture, the HOF-TGU307 material shows unique solution processability and easy regeneration due to reversibility and flexibility of
hydrogen bonds, and the HOF-TGU307 material has good
biocompatibility and low
cytotoxicity due to the
metal-free characteristic; the characteristics enable the HOF to become a new platform of functional materials. The adhesive is formed by
polymerization of two
acrylic monomers in an
ethanol solution through
ultraviolet initiation, the process is simple and environment-friendly, and the obtained product has good storage and transportation stability. Performance tests show that the
bonding strength of the adhesive on a PMMA (
polymethyl methacrylate) base material can reach 1.36 MPa, and Fourier
infrared spectroscopy and
scanning electron microscope analysis verify good compatibility and dispersion state between HOF-TGU307 crystals and a
polymer matrix. The adhesive provided by the invention has wide application prospects in the fields of structural bonding, photoelectric materials, automobiles,
new energy and the like.