The invention discloses an electrochromic intelligent window with a precise mode regulation and
control function and a preparation method and application of the electrochromic intelligent window, and belongs to the technical field of intelligent buildings. In order to solve the problems that an existing electrochromic intelligent window is insufficient in energy-saving effect, poor in warm mode regulation and control performance and the like, the electrochromic intelligent window is made of a
lithium /
viologen-based
electrolyte and
tungsten oxide (WO3) bi-component electrochromic material,
zoning regulation of visible light (380-780 nm) and near-
infrared light (780-2500 nm) is independently achieved through
voltage regulation and control, and the three
modes of brightness, warm and
darkness are achieved. In a warm mode, the visible light
transmittance (TVIS < = 10%) is extremely low, the near-
infrared light
transmittance modulation range (
delta TNIR < = 10%) is small, and excellent
privacy protection and heat preservation performance is provided; and in the
dark mode, visible light (TVIS < = 5%) is synchronously reduced, near-
infrared light (DeltaTNIR > = 30%) is significantly modulated, and the energy-saving effect is significantly improved. Besides, high-
emissivity and low-
emissivity materials are designed on the outer layer of the device, and long-wave infrared light (2.5-25 microns)
radiation is regulated and controlled in combination with mechanical overturning, so that the energy efficiency performance of the intelligent window in cooling in summer and heat preservation in winter is further enhanced.