The invention provides a photocatalysis and microorganism composite anode fuel battery system, relates to a battery system and aims at solving the problems the output power density of the existing microbial fuel cell is low, the generated voltage is low, electricity energy is difficult to recycle, the cost of the negative electrode is high, and organic matters which have biotoxicity in sewage can not be continuously degraded. The photocatalysis and microorganism composite anode fuel battery system comprises a box body, a microorganism anode chamber, an ion exchange membrane, a photocatalysis anode, a resistor, a quartz glass window, a light source, a light anode chamber water inlet, a light anode chamber water outlet, a microorganism anode, a cathode, an opening, a microorganism anode chamber water inlet, a microorganism fuel battery water outlet, a light anode chamber, a water feeding pipe, a guide pipe and a water discharging pipe. According to the photocatalysis and microorganism composite anode fuel battery system, the luminous energy and the biological energy are utilized at the same time, and the production efficiency of the system is improved by 29-65%.