2674results about "Water/sewage treatment by electrochemical methods" patented technology

A treatment system provides treated or softened water to a point of use by removing at least a portion of any undesirable species contained in water from a water source. The treatment system can be operated to reduce the likelihood of formation of any scale that can be generated during normal operation of an electrochemical device. The formation of scale in the treatment system, including its wetted components, may be inhibited by reversing or substituting the flowing liquid having hardness-causing species with another liquid having a low tendency to produce scale, such as a low LSI water. Various arrangements of components in the treatment system can be flushed by directing the valves and the pumps of the system to displace liquid having hardness-causing species with a liquid that has little or no tendency to form scale.

A method and apparatus for electrolytically producing oxidation reduction potential water from aqueous salt solutions for use in disinfection, sterilization, decontamination, wound cleansing. The apparatus includes an electrolysis unit having a three-compartment cell (22) comprising a cathode chamber (18), an anode chamber (16), and a saline solution chamber (20) interposed between the anode and cathod chambers. Two communicating (24, 26) membranes separate the three chambers. The center chamber includes a fluid flow inlet (21a) and outlet (21b) and contains insulative material that ensures direct voltage potential does not travel through the chamber. A supply of water flows through the cathode and anode chambers at the respective sides of the saline chamber. Saline solution flows through the center chamber, either by circulating a pre-prepared aqueous solution containing ionic species, or, alternatively, by circulating pure water or an aqueous solution of, e.g., aqueous hydrogen chloride and ammonium hydroxide, over particulate insulative material coated with a solid electrolyte. Electrical current is provided to the communicating membranes separating the chambers, thus causing an electrolytic reaction that produces both oxidative (positive) and reductive (negative) ORP water.

The invention discloses a process to implement and maintain water bodies larger than 15,000 m3 for recreational use, such as lakes or artificial lagoons, with excellent color, transparency and cleanness properties at low cost, which comprises the following steps:

• • a.—providing a structure able to contain a large water body larger than 15,000 m3;
  • b.—feeding the structure of step (a) with inlet water having iron and manganese levels lower than 1.5 ppm and turbidity lower than 5 NTU;
  • c.—measuring water pH, ideally it should be within a range lower than 7.8;
  • d.—adding an oxidizing agent to the water contained in the structure of step (a), with which a 600 mV minimal ORP is controlled in water for a minimal period of 4 hours and in maximal cycles of 48 hours;
  • e.—adding a flocculating agent in concentrations within 0.02 and 1 ppm with maximal frequencies of 6 days and cleaning the bottom of the structure of step (a) with a suction device to remove precipitated impurities from the bottom of said structure, together with the additional flocculants and;
  • f.—generating a displacement of surface water containing impurities and surface oils by means of the injection of inlet water according to step (b), which generates said displacement in such a way to remove said surface water by means of a system for impurities and surface oils removal arranged in the structure of step (a), which together with step (e) replaces traditional filtering.

The present invention also discloses a structure to contain large water bodies comprising a system for the removal of impurities and surface oils by means of skimmers and the suction device to clean said structure.

A method and device for removing, deodorizing and purifying odor, smoke and harmful substances from exhaust gas or flue gas employs a water solution containing hypohalogen acid such as hypochlorous acid soda, an alkaline electrolyte such as potassium hydroxide or sodium hydroxide and a saline electrolyte such as sodium chloride, potassium chloride, sodium bromide or potassium bromide which is electrolyzed to produce an electrolytic water solution which is fed to a deodorizing tower and brought into contact with exhaust gas or flue gas to remove odor, smoke and harmful substances in the exhaust gas or flue gas.

A method and apparatus is provided for inhibiting scaling in an electrodeionization system and, more particularly, for increasing tolerance to hardness in the feed water to an electrodeionization unit by inhibiting precipitation of scale-forming metallic cations contained in the feed water and thereby increasing efficiencies of the electrodeionization system. Water to be purified is passed through an electrodeionization unit in which the flow in the diluting compartment is countercurrent to the flow in the concentrating compartment. This is to impede the migration of scale-forming metallic cations from the diluting compartment, through the cation exchange membrane, into the concentrating compartment and towards the concentrating compartment side of the anion exchange membrane, thereby preventing scale formation on the anion exchange membrane. The electrodeionization unit may be further modified by dividing the concentrating compartments into first and second compartments by a porous diaphragm or ion-conducting membrane. The porous diaphragm or ion-conducting membrane effectively eliminates convective transport of scale-forming metallic cations from the cation exchange membrane side of the concentrating compartment to the anion exchange membrane side of the concentrating compartment, thereby inhibiting scale formation on the anion exchange membrane.

The invention relates to a recycling water saving device of a washing machine, which belongs to the technical field of environmentally-friendly water treatment, comprises a shell, and is characterized in that a recycling water bucket, a water treatment device, a circuit integrated control operation actuator and a control circuit are respectively arranged in the shell, wherein the water treatment device is connected onto the recycling water bucket in parallel, a tap water inlet and a water outlet I of the water saving device are respectively arranged on the upper side of the shell, a water inlet and a water outlet II of the water saving device are respectively arranged on the lower side thereof, and the water treatment device consists of a double pole film and double liquid flow type hydroxyl free-radical generator, an aeration device and a filter unit. The invention comprehensively utilizes the initial discharged washing fluid, keeps the mixed liquid of a first rinsing and a second rinsing to repeatedly wash the clothing, not only the existence and accumulation of the salt content can be neglected, but also the purpose of saving the water resource is achieved. The water saving device is designed into an independent component so as to be compatible to various types of washing machines and detergents. In addition, a program control valve is designed and manufactured to realize the automation of the water saving device.

The present invention is directed to a water treatment or purification system and method for providing treated water in industrial, commercial and residential applications. The treatment system provides treated or softened water to a point of use by removing at least a portion of any hardness-causing species contained in water from a water source, such as municipal water, well water, brackish water and water containing foulants. The water treatment system includes an electrochemical device, such as an electrodeionization device, that can have at least one compartment that generates and traps hydrogen ions which can be used in another compartment of the electrochemical device such as, an electrode compartment, to reduce or at least dissolve any scale. Other applications of the system would be in the treatment and processing of foods and beverages, sugars, various industries such as the chemical, pharmaceutical, waste water treatment and power generating industries.

The invention relates to a process method for treating hardly-biodegradable organic wastewater, and the method comprises the following steps: mainly utilizing the combination of ultraviolet light, electrochemistry, ultrasonic waves and oxidation-reduction chemical reaction for treating the hardly-biodegradable organic wastewater, and treating the wastewater by three reaction units of an ultrasonic cavitation zone, an electrochemical reaction zone and an ultraviolet light catalytic reaction zone, thereby realizing the high-efficient multi-stage deep wastewater oxidation reaction which combines the ultrasonic wastewater treatment method, the ultrasonic light and the collaborative Fenton reagent oxidation wastewater treatment, as well as the electrochemistry and the collaborative Fenton reagent oxidation wastewater treatment, effectively treating a variety of types of hardly-biodegradable organic wastewater and leading the COD removal rate of the wastewater after the treatment to be more than 90%.

A water purification system having a porous anode electrode (21) and a porous cathode electrode (20), each of which is made of graphite, at least one metal oxide, and an ion-exchange, cross-linked, polarizable polymer, and optionally comprises microchannels. Disposed between the electrodes is a non-electron conductive, fluid permeable separator element (22), whereby wastewater is able to flow from one electrode to the other electrode. The electrodes and separator may be disposed within a housing (23) having a wastewater inlet opening (24), and exhaust waste outlet opening (26) and a purified water outlet opening (25). In this way, components of the system are easily replaced should the need arise.

An electrolytically activated, microcidal aqueous solution is disclosed which is used in the elimination and control of biofilm in dental unit water lines. The solution has a pH between 6.75 and 10 with microcidal as well as anti-oxidising, dispersing and surfactant properties, rendering the solution bio-compatible and non-corrosive, as well as capable of eliminating biofilm in dental unit water lines, while simultaneously dispersing and dislodging the biofilm from the water lines so as reduce the micro-organisms in the dental water to a predetermined level. The aqueous solution is produced using an electrolytic device that allows the independent manipulation of specific individual properties of two separate product streams (a cation-rich stream and an anion-rich stream), the manipulation being performed by separate and independent recirculation through the same electrode chamber or counter-electrode chamber of the electrolytic device to modulate the respective properties of the anion-containing and the cation-containing solutions.

Apparatus and methods are provided for producing electrolytic water using three chambers, rigid plates and ion exchange membranes. Benefits include reduced scale production and increased long-term bactericidal effects of the water produced.

This is a method of water and wastewater treatment for removal of pollutants in at least two-step process comprising (a) treatment of water producing at least partially treated intermediate effluent, (b) treatment of the intermediate effluent with a sacrificial metal and producing ions of said sacrificial metal, and providing very thoroughly treated effluent, (c) recuperating sacrificial metal ions generated in the step (b) and recycling the recuperated ions in the step (a), the recuperated and recycled ions from the step (c) improve treatment efficiency of step (a) by additionally removing pollutants from the intermediate effluent using recuperated ions, resulting in cleaner intermediate effluent, and, therefore, the pollutant loading rate in step (b) is reduced, intermediate effluent is further treated more thoroughly, and the demand for the sacrificial metal in step (b) is reduced. Step (a) can preferably be a biological, biological-abiotic, physical chemical, or combination of these steps. Step (b) is preferably a spontaneous cementation-driven electrochemical process. The combination of said steps (a), (b) and (c) produces a synergistic effect resulting in improved removal of said pollutants and in reduced need in said sacrificial metal. For example, a drinking quality water can be very economically and reliably obtained from wastewater. In addition to the superb treatment efficiency and reduced reagent requirements, the waste sludge from the system is beneficially disposed in-sewers, in sanitary landfills or on land.

An apparatus for producing deionized water consisting essentially of an electrodialyzer having cation exchange membranes and anion exchange membranes alternately arranged between a cathode and an anode to form demineralizing compartments and concentrating compartments, and ion exchangers accommodated in the demineralizing compartments, wherein a pressure of from 0.1 to 20 kg/cm2 is exerted between the ion exchangers accommodated in the demineralizing compartments and the cation exchange membranes and anion exchange membranes defining the demineralizing compartments.

A process and a device for the treatment of water, especially for removing therefrom a large variety of pollutants, especially organic, inorganic and biological pollutants through in situ generation of ozone. Ozone is economically produced in situ at a high concentration through the interaction of electrolytically produced oxygen and UV light having a wavelength of 189 nm. The device has a set of anode and cathode for electrolytically producing nascent oxygen which reacts with UV light at a wavelength of 189 nm to produce ozone "in situ" within a vessel where the polluted water is submitted to the combinative action of ozone and other oxidation reactions. The device also has a hydrocyclone or retention tank of removing cationic pollutants such as heavy metals, free radicals as well as undesirable electrolysis byproducts such as nascent hydrogen through a secondary outlet. Oxidation by-products are subsequently removed from the exiting water stream by means of decantation, flocculation, coagulation or filtration.

Methods and systems for treating a waste stream in a waste treatment system involve performing a unit process of the waste treatment system by contacting the waste stream with oxyhydrogen-rich gas generated on-site by an oxyhydrogen gas generator that implements water dissociation technology. In a preferred embodiment, the oxyhydrogen gas generator involves applying a pulsed electrical signal to a series of closely-spaced electrodes that are submerged in the waste stream to produce oxyhydrogen-rich gas from a water component of the waste stream. Operation of the oxyhydrogen gas generator in the waste stream may accomplish one or more unit processes for waste treatment, such as conditioning, stabilization, thickening, and dewatering, among others. At least a portion of the oxyhydrogen-rich gas can be conveyed for a second use in the waste treatment system, such as a source of combustible fuel for incineration or power generation, for example.

Process and apparatus for reducing organic content of brine comprising subjecting a brine solution to at least two purification treatments selected from electrochemical treatment, chlorinolysis, or other chemical oxidation treatment, carbon adsorption, extraction, biological treatment and chrystallizing treatment; wherein the organic content of purified brine is sufficiently low to enable sense of the purified brine in an industrial process.

The invention relates to a method for purifying water by forming in an electrolytic cell molecular halogen, hypohalic acid, hypohalite ions or combinations thereof, from halide ions dissolved in the water; and dissolving one or more soluble metal salts in the water to provide corresponding metal ions. The invention also relates to a system for purifying water, having an electrolytic cell comprising a plurality of electrodes sufficient to electrolytically convert halide ion in the water into molecular halogen, hypohalic acid, or hypohalite ions, or combinations thereof; and a metal generator, which provides concentrations of one or more metals to the water.

A mediated electrochemical oxidation process and apparatus are used to process biological and organic materials to provide hydrogen and oxygen for use as fuel in numerous types of equipment. Waste materials are introduced into an apparatus for contacting the waste with an electrolyte containing the oxidized form of one or more reversible redox couples, at least one of which is produced electrochemically by anodic oxidation at the anode of an electrochemical cell. The oxidized species of the redox couples oxidize the organic waste molecules and are themselves converted to their reduced form, whereupon they are reoxidized and the redox cycle continues until all oxidizable waste species have undergone the desired degree of oxidation. The entire process takes place at temperatures to avoid any possible formation of either dioxins or furans. The oxidation process may be enhanced by the addition of ultrasonic energy and/or ultraviolet radiation.

A method and apparatus for producing purified water. Treated water may be provided for domestic use wherein the water may be treated by removing selected dissolved species while retaining properties that may improve the properties or aesthetics of the water.