The invention relates to the technical field of batteries, in particular to a high-
conductivity composite
silicon-based negative
electrode material and a preparation method and application thereof. According to the method,
silicon and
sacrificial metal are co-deposited on a
graphite substrate, and then a
metal phase is removed through selective chemical
etching, so that a nanoscale
ion /
electron dual-
transmission channel is successfully constructed in the material. By means of the innovative structural design, the
electronic conductivity of the material is remarkably improved, the defect of poor
conductivity is effectively overcome,
lithium ion transmission dynamics is promoted, meanwhile, the three-dimensional nano-
channel network can effectively buffer
volume expansion of
silicon in the charging and discharging process, pulverization and structural collapse of the
electrode material are restrained, and the service life of the
electrode material is prolonged. Therefore, the
conductivity, the
structural stability and the cycle life of the material are synergistically improved. According to the method, a process
route combining physical deposition and mild chemical
etching is adopted, so that the process is green, safe and controllable.