The invention relates to a high-hardness high-sulfur-corrosion-resistant electric arc spraying powder core wire which belongs to electric arc spraying powder cored wires which resist high-temperature oxidation and corrosion and used for the surface protection of metal materials. The high-hardness high-sulfur-corrosion-resistant electric arc spraying powder core wire belongs to the field of hot spraying in material processing engineering and is mainly used for the high-temperature corrosion, erosion and abrasion resistance of four tubes of a general coal-powder boiler of a coal-fired power station boiler, the corrosion prevention and the abrasion resistance of a converter smoke hood and a flue in a steel works and the repair of various axles, crankshafts, plunger pistons, paper-making drying cylinders, and the like. The high-hardness high-sulfur-corrosion-resistant electric arc spraying powder core wire is characterized by comprising the powder core components according to percentages by weight of 22-29 percent of crome metal, 5-9 percent of metallic molybdenum, 2.5-10 percent of metallic nickel, 4.0-6.5 percent of metallic aluminum, 0.5-1 percent of carbon, 1.0-3.0 percent of rare-earth, and metallic iron. A preparation method of the high-hardness high-sulfur-corrosion-resistant electric arc spraying powder core wire adopts the prior processes of firstly rolling a low-carbon cold-rolled strip into a U shape, adding powder core powders which account for 30-40 percent of the gross weight of spraying wires into the U-shaped groove, closing the U-shaped groove and wrapping the powder cores in the U-shaped groove, drawing gradually and lightening through a wire-drawing die to lead the diameter to reach 3.0mm.