Production process of colored flat acrylic fiber and production line thereof
A production process and flat technology, applied in the production process of colored flat acrylic fiber and its production line, can solve the problems of less color spectrum, increased spinning difficulty, large particle size, etc., to solve uneven dyeing and looseness Excellent effect
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Embodiment 1~3
[0111] Acrylonitrile copolymer composed of acrylonitrile, methyl acrylate and sodium styrene sulfonate. Bulk feed concentration is 33%, and reaction temperature is 56 ℃, and reaction time is 53 minutes, and oxidizing agent is sodium chlorate, and consumption is 0.5wt% of total unit, and reducing agent is sodium metabisulfite, and reducing agent and oxidizing agent mol ratio are 1.45. After the polymerization reaction, the slurry was desingled under a vacuum of 57Kpa, washed at a vacuum of 55kPa and a temperature of 50°C, and then diluted to a concentration of 35%. After dissolving in NaSCN solution, the air bubbles were removed under the condition of vacuum degree of 8kPa and temperature difference of 22°C, and the spinning stock solution with total solid content of 12% was obtained by filtration. The spinning dope is coagulated into as-spun fibers in a coagulation bath with a sodium thiocyanate concentration of 14.0wt% and a temperature of 1.0°C through a spinneret of special...
Embodiment 4~6
[0113] Acrylonitrile copolymer composed of acrylonitrile, methyl methacrylate and sodium vinyl sulfonate, the comonomer ratio composition is acrylonitrile: methyl acrylate: sodium vinyl sulfonate = 90.8: 8.8: 0.4, the total The polymerization monomer feed concentration is 34%, the reaction temperature is 55°C, the reaction time is 54 minutes, the oxidizing agent is potassium persulfate, and the consumption is 0.6wt% of the total bill, the reducing agent is sodium bisulfite, the reducing agent and the oxidizing agent molar ratio is 1.55. After the polymerization reaction, the slurry was separated under a vacuum of 55Kpa, washed at a vacuum of 60kPa and a temperature of 51° C., and then diluted to a concentration of 34.7%. After dissolving in NaSCN solution, remove air bubbles under the conditions of vacuum degree of 7kPa and temperature difference of 21°C, and filter to obtain a spinning stock solution with a total solid content of 11.8%. The spinning dope is coagulated into a...
Embodiment 7~9
[0115] Acrylonitrile copolymer composed of acrylonitrile, vinyl acetate and sodium methacryl sulfonate. The bulk feed concentration is 35%, the reaction temperature is 54°C, the reaction time is 56 minutes, the oxidizing agent is ammonium persulfate, and the consumption is 0.55wt% of the total bill, the reducing agent is sodium bisulfite, and the reducing agent and oxidizing agent molar ratio is 1.5 . . After the polymerization reaction, the slurry was separated under a vacuum of 52Kpa, washed at a vacuum of 58kPa and a temperature of 53°C, and then diluted to a concentration of 34.0%. After dissolving in NaSCN solution, remove air bubbles under the conditions of vacuum degree of 5kPa and temperature difference of 20°C, and filter to obtain a spinning stock solution with a total solid content of 11%. The spinning dope is coagulated into as-spun fibers in a coagulation bath with a sodium thiocyanate concentration of 15.0wt% and a temperature of 3.0°C through a spinneret of sp...
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