The invention provides a non-stick pan coating layer and a preparation method thereof. The coating layer comprises Al-Cu-Fe-Cr-B quasicrystalline alloy which has components as follows by the atomic percentage: 70-90 of Al, 1-15 of Cu, 5-15 of Fe, 5-15 of Cr, and the balance of B and unavoidable impurity. The method comprises the specific steps as follows: (1) smelting alloy materials with a spraying device at a temperature of 900-1100 DEG C to prepare alloy powder; (2) spraying the alloy coating layer on a boiler basal body with a plasma spraying device, with a main gas feed rate of 65 L/min, a secondary gas feed rate of 20-30 L/min, an arc current of 550-590A, an arc voltage of 45-60V, a powder delivering amount of 10-15 g/min, and a coating layer thickness of about 100-200 micro. At a cooking temperature, the invention has the advantages of stable chemical property, large rigidness, lower cost than Teflon or organic silicon, low surface friction coefficient, and the like.