The invention relates to a cobalt oxide film of interrupted oxide material, which is in a polycrystal state and has a chemical formula of Co3O4 and a thickness of 200nm. The preparation method comprises the following steps: (1), preparing ceramic target material of CoOx (x is larger than 0 and less than 4/3); (2), fixing the target material of CoOx on a target, fixing a substrate on a substrate platform and arranging the target and the substrate platform in a growth chamber; (3), vacuumizing the growth chamber by a mechanical pump and a molecular pump, closing the mechanical pump, opening an inlet valve and pumping oxygen to the growth chamber until oxygen pressure is 20Pa; (4), focusing laser beams of a laser on the target material of CoOx by a lens; (5), heating the substrate platform by a resistance furnace so that the temperature of the substrate reaches a temperature of 660 DEG C; and (6), confirming sedimentation time according to single-pulse energy to sedimentate the film of Co3O4 with the thickness of 200nm on the substrate. The film is used to prepare a nonvolatile interrupted memory storage element which adopts a sandwich structure as a basic configuration, i.e., a polycrystal oxide film of Co3O4 is sedimentated on a Pt electrode film of a lower electrode, and a Pt probe is used as an upper electrode to form a memory unit.