The invention discloses an aluminum/iron-doped amorphous carbon film/aluminum nano-thin-film memory resistor storage device and a manufacturing method thereof. According to the method, a quartz glass substrate serves as a substrate, an iron-doped amorphous carbon film is prepared through a pulsed laser deposition method, then two aluminum layers are evaporated on the amorphous carbon film through a vacuum hot evaporating method to serve as electrodes, a voltage trigger is connected, and the memory resistor storage device is prepared. Under room temperature, the memory resistor storage device is in a high resistance state or a low resistance state, the resistance switching phenomenon is extremely obvious, writing can be conducted through simple pulse voltage, and reading is achieved by detecting the resistance states. The aluminum/iron-doped amorphous carbon film/aluminum nano-thin-film memory resistor storage device has the advantages of being high in writing speed and repeatability, simple in structure, stable, resistant to vibration, concise in process, free of pollution to the environment, low in raw material price, easy to recycle and the like.