The application relates to a
carbon nanotube substrate paper spray
ionization system and method for monitoring active intermediates and
chemical bond construction in situ, which comprises a reaction-
ionization integrated substrate unit, a high-
voltage electric field application unit and a
mass spectrum real-time detection unit. The reaction-
ionization integrated substrate unit comprises a multi-walled
carbon nanotube film substrate, and the multi-walled
carbon nanotube film substrate is used as a core
working electrode. The multi-walled carbon
nanotube film substrate is a self-supporting structure and is in the shape of an isosceles triangle. The high-
voltage electric field application unit is electrically connected with the multi-walled carbon
nanotube film substrate of the reaction-ionization integrated substrate unit. The high-
voltage electric field application unit comprises a high-voltage power supply. The
mass spectrum real-time detection unit comprises a
mass spectrometer. The sampling inlet of the mass
spectrometer is opposite to the top corner vertex of the multi-walled carbon
nanotube film substrate. Compared with the prior art, the carbon nanotube substrate with
high conductivity and large specific surface area is used to replace the traditional paper substrate, and a monitoring-driving-synthesis integrated paper spray ionization platform is constructed.