544 results about "Molybdic acid" patented technology

The invention discloses an aerogel fire extinguishing agent for fire fighting, a fire extinguishing device and a releasing method.The aerogel fire extinguishing agent for fire fighting is prepared from, by mass, 8-12 parts of silicon dioxide aerogel powder, 40-45 parts of perfluorohexanone, 1.5-2 parts of zinc molybdate, 0.8-1.2 parts of nano cerium oxide, 2-3 parts of hyperbranched polysiloxane and 0.2-0.3 part of 18-crown-6 ether. Solid-phase silicon dioxide aerogel powder is matched with liquid-phase perfluorohexanone, zinc molybdate, nano cerium oxide, hyperbranched polysiloxane, 18-crown-6 ether and the like are compounded to serve as auxiliaries, efficient fire extinguishing can be conducted on precise electrical elements, residues are few, loss of instruments and equipment is small, and the fire extinguishing agent is suitable for being applied to the electrical field.

The invention relates to the field of anticorrosive paint, in particular to anticorrosive paint containing lanthanum cerium oxide and a preparation method of the anticorrosive paint. The invention relates to an anticorrosive coating containing lanthanum cerium oxide. The anticorrosive coating is prepared from the following raw materials: 28 to 45 parts of ultraviolet stable composite film forming matter, 5 to 10 parts of composite rare earth filler, 6 to 12 parts of supported synergistic antirust agent, 18 to 30 parts of mixed solvent, 0.8 to 2.5 parts of dispersing agent, 2.7 to 5.3 parts of functional additive and 0.5 to 1.2 parts of nano montmorillonite, the composite rare earth filler is lanthanum cerium oxide-hydroxyapatite composite powder with a core-shell structure, wherein lanthanum cerium oxide is used as a core, hydroxyapatite is used as a shell, and the thickness of the shell layer is 10-20 nm; the ultraviolet stable composite film forming substance comprises epoxy resin and ultraviolet grafting modified polyurethane in a weight ratio of 1: (0.6-2.2); the supported synergistic antirust agent is a mixture of mesoporous silica supported benzotriazole and zinc molybdate. And the obtained coating is high in adhesive force and long in service life.

The invention relates to a composite reverse osmosis membrane acidic cleaning agent, a preparation method and a cleaning process thereof, and belongs to the technical field of environment-friendly water treatment. The cleaning agent comprises the following components in percentage by mass: 4-8% of inorganic acid, 20-40% of organic acid, 1-3% of a surfactant, 0.5-1% of a chelating agent, 0.5-1% of a compound corrosion inhibitor and the balance of deionized water. The composite corrosion inhibitor is formed by compounding 2-mercaptobenzothiazole and the like according to a specific mass ratio, the molecular weight of polyaspartic acid is 5000, and the molar ratio of Zn to Mo in the zinc-molybdate compound is 2: 1. The preparation method comprises the following four steps: firstly preparing a compound corrosion inhibitor premix, then preparing an acidic base solution, and then sequentially adding the components to finally obtain the cleaning solution. According to the cleaning process, a cleaning agent and deionized water are mixed, the membrane flux recovery rate is larger than or equal to 85% through cleaning of a specific process, the reverse osmosis membrane can be effectively cleaned, and the performance of the reverse osmosis membrane can be recovered.

The invention discloses a high-initial-efficiency fast-charge graphite composite material and a preparation method thereof, the composite material is of a core-shell structure, the core is graphite, and the shell is lithium sulfonate / lithium molybdate and an amorphous carbon coating layer thereof; the mass ratio of the shell is 5-15 wt% according to the mass ratio of the composite material being 100%. The preparation method comprises the following steps: adding a molybdenum compound into a solvent to prepare a solution, adding graphite oxide, an inorganic lithium salt and a carbon nanotube conductive solution, reacting for 2-12 hours at the temperature of 50-120 DEG C, filtering, carbonizing filter residues to obtain a lithium molybdate conductive agent coated graphite material, and depositing a lithium sulfonate derivative on the surface of the lithium molybdate conductive agent coated graphite material by an atomization method to obtain the lithium molybdate conductive agent coated graphite material. The electron and ion conductivity of the material can be improved, and the rate and the first efficiency of the material can be improved.

The invention provides a visual detection method for interface water droplet induced electron generation in a high-temperature and high-pressure hydrocarbon-water system, and belongs to the technical field of in-situ analysis of electrons in mixed fluid. The detection method comprises the following steps: preparing a fused quartz capillary reaction cavity; loading a sample in a fused quartz capillary reaction cavity: sequentially inserting a thin capillary syringe filled with a silicomolybdic acid aqueous solution and a thin capillary syringe filled with a hydrocarbon liquid into the fused quartz capillary reaction cavity, and injecting the silicomolybdic acid aqueous solution and the hydrocarbon liquid; and carrying out visual detection on the water droplets. Through the visual fused quartz capillary thermal simulation experiment device, the color change of the water droplets at the interface of the silicomolybdic acid aqueous solution and the hydrocarbon fluid under the conditions of high temperature and high pressure is visually displayed, and the color characteristics of the water droplets are observed in real time by using a microscope, so that whether the water droplets induce electron generation or not is judged; the problem that electrons generated by water droplets cannot be directly observed and detected under high-temperature and high-pressure conditions is solved.

The invention relates to the technical field of electro-catalysis oxygen evolution, and particularly discloses a nickel-molybdenum foam composite oxygen evolution electro-catalysis material with high-valence nickel induced by molybdate radicals and a preparation method of the nickel-molybdenum foam composite oxygen evolution electro-catalysis material aiming at the problem that an existing oxygen evolution electro-catalysis material is insufficient in comprehensive performance or poor in performance stability. Soaking in a NaCl aqueous solution, and taking out; s2, mixing the nickel-molybdenum alloy foam with a K3 [Fe (CN) 6] aqueous solution, heating, and carrying out a hydrothermal reaction; and S3, finally, the nickel-molybdenum alloy foam is placed in the air or oxygen atmosphere and heated to 350-450 DEG C, heat preservation treatment is conducted for 2 h, and the nickel-molybdenum foam composite oxygen evolution electro-catalysis material is obtained. Molybdate anions are adopted as a sustainable induction source to be coupled with a NixOy / Fe3O4 heterogeneous interface, integrated construction is achieved on a nickel-molybdenum foam framework, and the nickel-molybdenum foam composite material has the advantages of being low in overpotential, high in stability, high in activity, high in binding force and long-term in durability and meanwhile being simple in process, easy to amplify on a large scale and the like.

The invention provides a double-defect-modified porous carbon nitride photocatalyst prepared by one step from ferromolybdic acid as well as a preparation method and application of the double-defect-modified porous carbon nitride photocatalyst. The catalyst is of a thin-layer porous structure, so that the specific surface area of the catalyst is increased, and more surface active sites are provided for adsorption and reaction; compared with pure g-C3N4, the visible light absorption intensity of the catalyst is obviously enhanced, due to the existence of surface N vacancies and defects formed by doping of metal oxides, effective charge separation is enhanced, the photon-generated carrier separation and transfer capacity is higher under visible light irradiation, and the catalytic activity is remarkably improved. When the photocatalyst is applied to degradation of tetracycline antibiotic pollutants, photocatalytic degradation of tetracycline can be realized only under the condition of low-power 5W LED visible light, the preparation process is simple, and the cost is lower.

The present invention relates to a Glycol based antifreeze liquid composition for combustion engines, electric vehicles, industrial and submersible motors. More particularly, the present invention relates to a Glycol based corrosion-inhibited antifreeze liquid composition, the said liquid composition comprises glycols, deionized water, alkali molybdate, alkali metal octoate or neodecanoate, rare-metal octoate or neodecanoate, dyes. The liquid composition of the present invention is environment-friendly, ready to use composition that will improve efficiency of combustion engines, industrial and submersible motors to the great extent and also provides excellent corrosion protection to the internal parts of the cooling system of combustion engines, electric vehicles and industrial and submersible motors.

The invention provides an anodic oxidation passivation method of a neodymium-iron-boron permanent magnet zinc coating, which comprises the following steps of: performing electrochemical anodic oxidation by taking a neodymium-iron-boron permanent magnet with a zinc coating on the surface as an anode, a Pt sheet as a cathode and a passivation solution as an electrolyte, forming a passivation layer on the surface of the neodymium-iron-boron permanent magnet with the zinc coating on the surface, and cleaning and drying to obtain the neodymium-iron-boron permanent magnet with the zinc coating on the surface. A chromium-free passivation film is formed on the neodymium-iron-boron permanent magnet zinc coating, and passivation of the neodymium-iron-boron permanent magnet zinc coating is completed; the passivation solution is prepared from 10 g / L to 20 g / L of molybdate, 10 g / L to 15 g / L of ammonium fluozirconate, 1 g / L to 10 g / L of etidronic acid, 1 g / L to 10 g / L of sodium dihydrogen phosphate, 1 g / L to 10 g / L of nitric acid, 1 g / L to 10 g / L of phosphoric acid and the balance distilled water. According to the method disclosed by the invention, a complete, uniform and compact passivation film is formed on the surface of the zinc coating after passivation, the corrosion potential is improved while the corrosion current is effectively reduced, and the time for generating a rust spot in a salt spray test exceeds 72 hours.

The invention belongs to the technical field of metal surface rust prevention, and discloses a treating fluid for metal surface rust prevention and a preparation method of the treating fluid. The coating is prepared from components in parts by mass as follows: 5-15 parts of a silane coupling agent, 3-10 parts of nano titanium dioxide, 1-4 parts of benzotriazole, 1-4 parts of molybdate, 1-5 parts of a dispersing agent, 2-6 parts of a coalescing agent, 1-4 parts of a surfactant, 0.5-3 parts of an accelerant, 0.5-3 parts of citric acid, 1-5 parts of acetic acid and 50-80 parts of deionized water. The preparation method comprises the following steps: sequentially adding the components into a stirring processing container according to a certain sequence, and stirring at a certain speed to obtain a treating fluid; according to the technical scheme, through synergistic interaction of all the components, rust can be removed, a layer of compact and continuous protective film can be formed on the metal surface, a very good anti-rust effect is achieved, benzotriazole and molybdate can also form an adsorption film, metal is protected through a large number of films of various types, the anti-corrosion effect of the protective film is improved, and the service life of the protective film is prolonged. The anti-rust effect is greatly improved.

The invention discloses a tetrathiomolybdate intercalated ternary iron-magnesium-zinc layered double hydroxide catalyst, a preparation method thereof and an application of the tetrathiomolybdate intercalated ternary iron-magnesium-zinc layered double hydroxide catalyst in degrading azo dyes by activating peroxymonosulfate. According to the method, a carbonate intercalated ternary LDH precursor is synthesized through a hydrothermal reaction, interlayer anions are replaced with nitrate and tetrathiomolybdate through ion exchange, and the target catalyst is obtained. In the catalyst, a unique Fe-Mg-Zn ternary metal laminate and a MoS < 2-> intercalation structure cooperatively construct a multi-active center, and MoS < 2-> is used as an electron donor to promote cyclic regeneration of Fe < 3 + > / Fe < 2 + >. The catalyst keeps ultrahigh activity in a wide range of pH (potential of hydrogen) of 3-9, can completely degrade 10 mg / L of acid orange 7 within 5 minutes, and is stable in structure and low in metal dissolution risk. The problems of low activity, slow Fe < 3 + > reduction, metal ion dissolution and the like under neutral and alkaline conditions in an advanced oxidation technology based on peroxymonosulfate are solved, and the method has important application value in the field of printing and dyeing wastewater treatment.

The invention is suitable for the technical field of MCA, and provides an MCA / PA6 flame-retardant composite material and a preparation method thereof. Comprising the following components in parts by weight: 50-60 parts of MCA, 15-20 parts of PA6, 15-25 parts of long glass fiber, 3-8 parts of metal hydroxide, 0.5-1.5 parts of titanium dioxide, 0.3-0.6 part of an antioxidant, 1-2 parts of nano silicon dioxide, 1-3 parts of zinc molybdate, 2-5 parts of aluminum hypophosphite, 1-2 parts of silicone resin, 0.5-1 part of carbodiimide and 5-8 parts of a toughening agent. The MCA / PA6 flame-retardant composite material disclosed by the invention combines the flame-retardant property of MCA and the excellent physical property of PA6, so that the flame-retardant property of the material is remarkably improved, and meanwhile, the original characteristics of light weight, good toughness, chemical resistance, good durability and the like of PA6 are maintained. By adding the long glass fiber, the metal hydroxide, the titanium dioxide, the antioxidant, the nano silicon dioxide, the zinc molybdate, the aluminum hypophosphite, the silicone resin, the carbodiimide, the flexibilizer and other components, the strength, the heat resistance and the flame retardant effect of the composite material are further enhanced.

The invention discloses a Mo in-situ doped transition metal layered double hydroxide derivative catalyst. The Mo in-situ doped transition metal layered double hydroxide derivative catalyst is of a nanometer two-dimensional layered structure; nitrate, aluminum nitrate and molybdate are used as raw materials, and a series of nano flaky Mo-X / Al2O3 composite metal oxide catalysts with high activity, high selectivity and high stability are obtained through co-hydrothermal precipitation and one-step roasting reduction. The invention further discloses a preparation method and application of the Mo in-situ doped transition metal layered double hydroxide derivative catalyst. According to the invention, macromolecules in biomass or biomass waste can be effectively depolymerized and liquefied into high-calorific-value bio-oil, so that the effect of turning waste into wealth from oriented conversion of the waste into bio-fuel is realized, and meanwhile, the bidirectional positive effects of avoiding environmental pollution caused by direct emission of the biomass waste and realizing comprehensive utilization of resources are realized; and a path with more economic benefits is provided for conversion from biomass wastes to renewable energy sources.

The invention discloses an iron oxide pigment with super weather resistance and corrosion resistance and a preparation method thereof, and relates to the technical field of weather-resistant and corrosion-resistant iron oxide pigments. The invention discloses an iron oxide pigment with super weather resistance and corrosion resistance. The iron oxide pigment is prepared from the following components in parts by mass: 100 parts of iron oxide, 1.5 to 3 parts of silane coupling agent, 2 to 4 parts of aluminum zirconate, 0.5 to 1.5 parts of weather-resistant antioxidant, 0.8 to 2 parts of molybdate corrosion inhibitor, 0.5 to 2 parts of nano silicon dioxide and 0.3 to 1 part of organic bentonite. Through an innovative composite formula and a preparation process, the stability of the iron oxide pigment in severe environments such as ultraviolet rays, damp heat and salt mist is greatly enhanced, excellent weather resistance and corrosion resistance are shown, the service life of the material can be effectively prolonged, and the maintenance cost can be reduced.

The invention relates to the technical field of fine chemical engineering, and discloses a fuel cell cooling liquid and a preparation method thereof, and the preparation method comprises the following steps: preparation of a basic liquid, construction of a corrosion inhibition system, ion inhibition treatment, addition of a functional auxiliary agent and post-treatment. According to the composite corrosion inhibitor, zinc ions are anchored to gap sites of a silicate framework through the surface loading effect of sodium silicate and nano-zinc oxide under the shear dispersion condition, a compact composite passivation film is formed on the surface of a metal pipeline, and an electrode potential active area is covered; meanwhile, molybdate ions are subjected to a self-repairing reaction at the defect position of a passivation film preferentially by virtue of the oxidation-reduction characteristic of the molybdate ions, and formation of a galvanic corrosion microbattery is blocked by dynamically filling microcracks, so that the integrity of a corrosion inhibition system is improved; all the components of the composite corrosion inhibitor generate a synergistic effect in a specific proportion, so that the cooling liquid can maintain stable corrosion resistance for a long time.

The invention discloses a post-treatment liquid and application thereof in an anode foil formation post-treatment process, and the post-treatment liquid comprises the following components in percentage by mass: 0.1-5% of a main film-forming agent, 0.05-3% of a synergistic stabilizer and the balance of a solvent, the main film-forming agent is selected from at least one of a waterborne polyurethane emulsion and a silane coupling agent; the synergistic stabilizer is selected from at least one of organophosphate, molybdate and tungstate. The main film-forming agent and the synergistic stabilizer are compounded to obtain the post-treatment liquid, on one hand, the synergistic stabilizer is firmly combined with an aluminum oxide substrate to carry out deep passivation treatment on an oxidation film on the surface of the anode foil, and on the other hand, the synergistic stabilizer is subjected to network crosslinking with a hydrophobic protection layer formed by the main film-forming agent; the three-dimensional composite protective film can effectively isolate water molecules, repair microdefects on the surface of an oxidation film, prevent the phenomena of specific volume attenuation, leakage current increase and the like of the anode foil, and improve the long-term working reliability of the capacitor.

The invention discloses a green and environment-friendly superfine bentonite anticorrosive coating and a preparation process thereof. The anticorrosive paint is prepared from 40 to 70 parts of water-based film forming matter, 0.3 to 3.0 parts of composite bentonite, 1.0 to 8.0 parts of a green corrosion inhibition system, 2.0 to 12.0 parts of an auxiliary agent, 0.30 to 0.40 part of a surface modifier, 10 to 30 parts of deionized water and 0.5 to 5 parts of a cosolvent. The composite bentonite is prepared by compounding sodium bentonite, nano titanium dioxide and a natural antibacterial extract according to the mass ratio of 100: (3-5): (0.3-2.0); the green corrosion inhibition system is formed by compounding molybdate, an organic corrosion inhibitor and a silane co-condensation compound. The preparation process comprises four key steps of preparation of a composite bentonite suspension, surface functionalization treatment, gradient shearing dispersion and coating blending. The salt spray resistance of the anticorrosive paint can reach 1150 hours, the VOC content is as low as 35 g / L, the antibacterial rate of the natural antibacterial extract is 97.2%, and the anticorrosive paint has excellent anticorrosive performance and green and environment-friendly characteristics.

The invention belongs to the technical field of photocatalysis and environmental governance, and particularly relates to a composite photocatalyst, in particular to a graphite-phase carbon nitride / molybdenum trioxide composite photocatalyst as well as a preparation method and application thereof. The method comprises the following steps: S1, dispersing ammonium heptamolybdate in deionized water, adjusting the pH value of the solution to 0.5 + / -0.3 by using sulfuric acid, stirring and centrifuging the formed system, and carrying out vacuum drying to obtain a molybdic acid precursor; s2, mixing melamine and the molybdic acid precursor, calcining the formed mixture, and naturally cooling to room temperature after calcining is finished, so as to obtain the composite photocatalyst. Tests prove that the prepared catalyst has excellent cycling stability, still keeps high catalytic activity after being recycled for multiple times, and has a good industrial application prospect.

The invention relates to the technical field of anaerobic methanogenesis, and provides a polyurethane foam filler as well as a preparation method and application thereof. The polyurethane foam filler comprises a polyurethane foam body and auxiliaries dispersed in the polyurethane foam body, and the auxiliaries comprise nano zero-valent iron, molybdate and a conductive carbon material. According to the polyurethane foam filler provided by the invention, through the synergistic effects of filler surface hydrophilicity, reducing atmosphere, inhibition on sulfate reduction reaction, promotion on interspecific electron transfer and the like, the starting of an anaerobic methanogenesis process can be accelerated, the impact resistance is enhanced, the efficiency of the anaerobic methanogenesis process and the reaction operation stability are effectively improved, and the service life of the polyurethane foam filler is prolonged. And the method has wide practical value and application prospect.

The invention discloses nanoparticles for synergistically treating tumors and a preparation method of the nanoparticles, and relates to the technical field of preparation of drugs containing inorganic active ingredients. The nanoparticles are composite nanoparticles Mo-PDA prepared by mixing and reacting inorganic active ingredients of phosphomolybdic acid Mo-POM and dopamine; the preparation method comprises the following steps: taking Mo-POM (phosphomolybdic acid), then loading Mo-PDA-coated GOx nanoparticles with a spherical structure formed by glucose oxidase (GOx), and carrying out mixing reaction by taking Mo-POM, adding deionized water, then adding dopamine, continuously stirring for 1 hour, and continuously reacting for 14-18 hours at the temperature of 150-170 DEG C. According to the preparation method disclosed by the invention, PDA is combined with Mo-containing polyacid salt and externally loaded with glucose oxidase (GOx), so that the PTT-modified CDT-hunger nanoparticle Mo-PDA-GOx for cooperatively treating tumors is synthesized, and the PTT-modified CDT-hunger nanoparticle Mo-PDA-GOx has excellent photo-thermal conversion efficiency which reaches 67.2%. The nanoparticles effectively exert synergistic treatment, and the treatment effect on tumors is improved.

The invention relates to a preparation method of molybdenum-lanthanum alloy powder, belongs to the technical field of metallurgy, and solves at least one of the following problems in an existing method: (1) the particle size is not easy to refine; (2) doping elements are not uniformly distributed; (3) ammonia gas is generated to pollute the environment; and (4) the process is complex. The preparation method comprises the following steps: (1) mixing a peroxymolybdic acid solution with a lanthanum compound, evaporating, crystallizing and roasting to obtain a molybdenum-lanthanum alloy powder precursor with a needle-like crystal structure; and (2) hydrogen reduction is conducted on the molybdenum-lanthanum alloy powder precursor twice, and the molybdenum-lanthanum alloy powder is obtained. According to the method, the particle size of the molybdenum-lanthanum alloy powder can be refined, the lanthanum element can be more evenly distributed in the alloy, the situation that the environment is polluted due to the fact that ammonia gas is generated in the preparation process of the molybdenum-lanthanum alloy is avoided, and the material mixing technology is relatively simple and suitable for large-scale production.

The invention relates to an application of a high-magnification nanocrystallization iron molybdate sodium ion battery positive electrode material, and the nanocrystallization iron molybdate sodium ion battery positive electrode material is an iron molybdate positive electrode material subjected to nanocrystallization optimization and is used for preparing a sodium ion battery. The reversible specific capacity of the nanocrystallized iron molybdate sodium ion battery positive electrode material in a sodium ion battery reaches up to 91 mAh / g, most of the capacity is kept under high current, and the capacity retention rate still can exceed 80% after 100 times of circulation. The nano-fibers are sintered into nano-particles, and the loading capacity can be controlled, so that the nano-fibers are used in the sodium-ion battery positive electrode material. Besides, by virtue of the greatly improved ion diffusion rate and structural stability of the nano-sized iron molybdate, high specific capacity, excellent rate capability and long cycle life can be realized at the same time, and the nano-sized iron molybdate is a high-performance sodium battery positive electrode material with great potential.

The invention belongs to the technical field of battery materials, and particularly relates to a method for determining iron phosphide in a phosphate positive electrode material, the positive electrode material and application. Comprising the following steps: preparing standard solutions of a series of phosphate positive electrode materials with different iron phosphide contents; respectively collecting and purifying magnetic substances in the standard solutions, and adding a quimocilidone reagent to determine the corresponding quinoline phosphomolybdate precipitate; drawing a standard curve according to the mass of the iron phosphide and the mass of the quinoline phosphomolybdate precipitate in the standard solutions with different iron phosphide contents; preparing a to-be-detected solution, collecting and purifying magnetic substances in the to-be-detected solution, adding a quinmolybdenum citronone reagent to determine the mass of the quinoline phosphomolybdate precipitate, and calculating the content of iron phosphide in the to-be-detected phosphate positive electrode material. By means of the method, the content of trace iron phosphide in the phosphate positive electrode material can be efficiently, accurately and quantitatively analyzed, the content of iron phosphide in the phosphate positive electrode material can be quantitatively regulated and reduced, and the electrochemical performance of the phosphate positive electrode material is improved.

The present application relates to the technical field of copper clad laminates, and discloses a copper clad laminate, a resin composition for the copper clad laminate, and spherical silicon and a preparation method therefor. The spherical silicon of the present application is composed of spherical silicon dioxide and zinc molybdate particles dispersedly grown on the surface of the spherical silicon dioxide in situ and has a diameter of less than 10 microns and a D50 of 0.6-6 microns. The content of zinc molybdate per unit area on the surface of the spherical silicon dioxide is 0.03-1 g / m2, and the size of the zinc molybdate particles is less than or equal to 400 nm. The preparation method comprises: enabling spherical silicon dioxide to come into contact with / be mixed with a soluble molybdate and a zinc salt in an aqueous reaction system; and reacting the soluble molybdate with the zinc salt in situ on the surface of the spherical silicon dioxide, so as to form spherical silicon chemically coated with zinc molybdate particles. In the present application, by directly synthesizing the zinc molybdate in situ on the surface of the spherical silicon dioxide by means of a hydrothermal method, the structural morphology of the obtained spherical silicon and the size of the zinc molybdate particles can be effectively controlled, thereby ensuring that the wear of a drill bit during the drilling of the copper clad laminate is effectively mitigated.

The invention provides a resin sheet, a metal base substrate and a power module. The resin sheet, the metal base substrate and the power module have excellent thermal conductivity and low residual volatile component amount and can maintain insulation reliability. Provided is a metal base substrate comprising a resin sheet and a copper plate, the resin sheet containing an epoxy resin (A), an inorganic filler (B), and a curing agent (C), and the copper plate having a surface roughness Ra of 0 [mu] mlt; ra < = 2.0 [mu] m, and the inorganic filler (B) contains talc (B-1) the surface of which is coated with zinc molybdate.

The application discloses a homopolymolybdate hybrid resistive random access memory material based on a tetraphenylstyrene molecule and a preparation method and application thereof. The preparation method comprises the following steps: dissolving a mixture of 0.05 mmol of homopolymolybdate and 0.1 mmol of the tetraphenylstyrene molecule in 10 mL of water, stirring for 2 hours, adjusting the pH to 5.0 by using HCl to obtain a mixed solution; moving the mixed solution into a 25 mL stainless steel reaction kettle lined with polytetrafluoroethylene, reacting at 160 DEG C for 3 days, and obtaining a colorless block crystal after cooling; and after filtration, washing and drying, the homopolymolybdate hybrid resistive random access memory material based on the tetraphenylstyrene molecule is obtained. The method is simple and easy to operate, raw materials are easy to obtain, and the method is easy to realize. No harmful product is generated in the preparation process, and the method is an environment-friendly green synthesis. A multi-level controllable memory storage material is prepared, and the material can be applied to a multi-level memristor.

The invention discloses a preparation method of a metal organic framework catalyst and application of the metal organic framework catalyst in biomass furfural hydrogenation, and belongs to the technical field of catalytic hydrogenation. The preparation method of the metal organic framework catalyst comprises the following steps: S1, dissolving cobaltous acetate, L-glutamic acid and phosphomolybdic acid in distilled water to obtain a solution marked as a solution A; dissolving 1, 3, 5-benzenetricarboxylic acid (BTC) in ethanol to obtain a solution B, pouring the solution B into the solution A, stirring, and centrifuging to collect a precipitate; and S2, calcining the precipitate in an inert atmosphere to obtain the metal organic framework catalyst. The specific steps of applying the catalyst to the furfural hydrogenation reaction are as follows: adding the prepared catalyst and furfural into deionized water, performing heating and pressurizing reaction through a hydrogenation reaction kettle to obtain a solution, extracting the solution with ethyl acetate, and performing GC quantitative detection on the product after the extraction reaction. The method is mild in reaction condition, has an efficient furfural hydrogenation effect, and can completely convert FFA within 2 hours under the condition that 50 mg of catalyst is added.

The invention relates to an amorphous bismuth molybdate photocatalytic material as well as a preparation method and application thereof, and belongs to the technical field of photocatalytic materials. The preparation method of the amorphous bismuth molybdate photocatalytic material comprises the following steps: (1) dissolving Bi (NO3) 3.5 H2O in an HAC solution, uniformly mixing and stirring at room temperature, and marking as a solution A; dissolving Na2MoO4 in water, adding a water-soluble anionic polymer, uniformly stirring, and marking as a solution B; and (2) slowly dropwise adding the solution B into the solution A, carrying out a co-precipitation reaction under the conditions of normal temperature and normal pressure, after dropwise adding is completed, maintaining heating and stirring for a period of time, then carrying out normal-temperature stirring, and after stirring is completed, carrying out centrifugation, washing and drying to obtain the amorphous bismuth molybdate photocatalytic material A-Bi2MoO6. The modified amorphous A-Bi2MoO6 provided by the invention has a relatively large specific surface area and more mesoporous structures, so that the adsorption of rhodamine B is enhanced, and the adsorbed dye can be efficiently catalyzed and degraded under the action of illumination.

The application provides a catalytic denitration agent and a preparation method thereof, and comprises the following components: a reducing base: urea 30-60 parts, ammonium carbamate 10-25 parts, ammonium carbonate 5-15 parts, ammonium bicarbonate 5-15 parts; a phase change catalytic component: ammonium dihydrogen phosphate 2-6 parts, di-ammonium hydrogen phosphate 1-5 parts, molybdate 0.05-0.5 parts, tungstate 0.1-0.8 parts, organic acid metal salt 0.1-0.8 parts, modified zeolite 1-8 parts; a functional additive: dispersant 0.2-1.0 parts, surfactant 0.1-0.6 parts, corrosion inhibitor 0.05-0.2 parts. The application constructs a multi-component complex catalytic system, and the prepared high-molecular catalytic denitration agent can realize the unity of wide-temperature high-efficiency denitration, low corrosion, low ammonia escape and high operation stability while significantly reducing the phase change temperature and energy consumption, and effectively solves the multiple problems of harsh reaction conditions, unstable efficiency and equipment corrosion in the prior art.

The application relates to a catalyst for catalytically synthesizing propylene acid from propane and application thereof, and the catalyst is represented by the following general formula: Mo a V b Te c Nb d Ni e O x Wherein, a, b, c, d and e respectively represent the atom numbers of Mo, V, Te, Nb and Ni, and the molar ratio of a:b:c:d:e is 7.0-9.0:1.7-2.5:1.0-1.5:1.7-2.3:0.1-1.0, and the value of x is determined by the oxidation state of each element; Ni is introduced by nickel molybdate, Mo is introduced by a molybdate and the nickel molybdate, and the nickel molybdate is prepared by co-precipitation of a molybdate and a nickel salt in the presence of an organic acid. According to the application, the content of different valence metals on the surface of the catalyst can be adjusted by introducing nickel into the catalyst through nickel molybdate, so that the content of high-valence elements Mo 6+ , V 5+ and Ni 2+ in the catalyst and the oxygen vacancy are increased, and the redox capacity of the catalyst is enhanced.