949 results about "Molybdic acid" patented technology

The invention discloses an aerogel fire extinguishing agent for fire fighting, a fire extinguishing device and a releasing method.The aerogel fire extinguishing agent for fire fighting is prepared from, by mass, 8-12 parts of silicon dioxide aerogel powder, 40-45 parts of perfluorohexanone, 1.5-2 parts of zinc molybdate, 0.8-1.2 parts of nano cerium oxide, 2-3 parts of hyperbranched polysiloxane and 0.2-0.3 part of 18-crown-6 ether. Solid-phase silicon dioxide aerogel powder is matched with liquid-phase perfluorohexanone, zinc molybdate, nano cerium oxide, hyperbranched polysiloxane, 18-crown-6 ether and the like are compounded to serve as auxiliaries, efficient fire extinguishing can be conducted on precise electrical elements, residues are few, loss of instruments and equipment is small, and the fire extinguishing agent is suitable for being applied to the electrical field.

The invention belongs to the field of magnetic refrigeration materials, and particularly discloses a gadolinium-based molybdate magnetic refrigeration material and a preparation method and application thereof. The gadolinium-based molybdate magnetic refrigeration material comprises GdXMoO4, wherein X is F, Cl, Br or I; the magnetic phase change temperature of the gadolinium-based molybdate magnetic refrigeration material is less than 2K, and the maximum magnetic entropy change of the gadolinium-based molybdate magnetic refrigeration material is greater than or equal to 12J. Kg <-1 >. K <-1 > when the magnetic field change is 0-50kOe. The gadolinium-based molybdate magnetic refrigeration material disclosed by the invention has extremely low magnetic phase transition temperature, has relatively high magnetocaloric efficiency in a low magnetic field, is an extremely low temperature region magnetic refrigeration material with excellent performance, and has a wide application prospect in the field of extremely low temperature magnetic refrigeration.

The invention relates to the technical field of molybdenum metallurgy, and particularly discloses a crystal preparation method of ammonium heptamolybdate, which comprises the following steps: taking low-grade molybdenite, crushing, ball-milling, and calcining to obtain molybdenum calcine. And dispersing the molybdenum calcine with a sodium hydroxide solution, and filtering to obtain a leaching solution. And then adding a compound chelating agent into the leachate, carrying out adsorption and desorption treatment to obtain a sodium molybdate solution, then adjusting the pH value, carrying out ammonia leaching, and then carrying out cooling crystallization to obtain ammonium heptamolybdate. By adopting the prepared compound chelating agent, the purity of ammonium heptamolybdate prepared by taking low-grade molybdenite as a raw material can be improved, and after desorption treatment, separated precipitates can be used as the compound chelating agent again for adsorbing molybdate radicals, so that the aim of cyclic utilization is achieved.

The invention relates to the field of anticorrosive paint, in particular to anticorrosive paint containing lanthanum cerium oxide and a preparation method of the anticorrosive paint. The invention relates to an anticorrosive coating containing lanthanum cerium oxide. The anticorrosive coating is prepared from the following raw materials: 28 to 45 parts of ultraviolet stable composite film forming matter, 5 to 10 parts of composite rare earth filler, 6 to 12 parts of supported synergistic antirust agent, 18 to 30 parts of mixed solvent, 0.8 to 2.5 parts of dispersing agent, 2.7 to 5.3 parts of functional additive and 0.5 to 1.2 parts of nano montmorillonite, the composite rare earth filler is lanthanum cerium oxide-hydroxyapatite composite powder with a core-shell structure, wherein lanthanum cerium oxide is used as a core, hydroxyapatite is used as a shell, and the thickness of the shell layer is 10-20 nm; the ultraviolet stable composite film forming substance comprises epoxy resin and ultraviolet grafting modified polyurethane in a weight ratio of 1: (0.6-2.2); the supported synergistic antirust agent is a mixture of mesoporous silica supported benzotriazole and zinc molybdate. And the obtained coating is high in adhesive force and long in service life.

The invention relates to the technical field of total phosphorus detection, in particular to a method for determining total phosphorus in water, which comprises the following steps: 1) digestion treatment: adding an oxidant into a water sample to be detected, and then performing microwave digestion treatment to obtain digested water; a molybdate reagent is added into the digested water, then an improved ascorbic acid solution is added, a chromogenic reaction is completed at the set temperature, and the improved ascorbic acid solution is obtained by mixing an ascorbic acid solution and sodium ethylene diamine tetracetate; measuring the concentration: measuring the absorbance value of the obtained color development product by using a spectrophotometer and a long-optical-path cuvette; and drawing a standard curve: using a phosphorus standard solution as a quality control sample, adding a plurality of calibration points in a low-concentration interval of 0.0-0.1 mg / L, carrying out colorimetric determination, and establishing quadratic equation fitting according to absorbance and concentration so as to determine the total phosphorus content of the water sample to be detected, and the method has the advantages of high sensitivity and good accuracy in total phosphorus testing.

According to the method, phosphomolybdic acid, copper chloride and ferric chloride serve as precursors, copper and iron-containing phosphomolybdic acid nano-enzyme (Cu, Fe-PMs) with peroxidase-like activity is synthesized through a microwave method, under the acidic condition, on one hand, the surface of Cu and Fe-PMs carries negative charges, high affinity is generated between Cu and Fe-PMs and a substrate TMB with positive charges, and on the other hand, the surface of Cu and Fe-PMs has negative charges; on the other hand, Cu / Fe / Mo three-metal redox couple accelerates the regeneration of Fe < 2 + > and plays an important role in the activity of peroxidase, and meanwhile, due to the introduction of sodium dehydroacetate, Cu and Fe in Cu and Fe-PMs and pyranoid ring and keto O in sodium dehydroacetate interact through coordinate bonds to cause electron interaction, so that the peroxidase-like activity of Cu and Fe-PMs is enhanced, and the peroxidase-like activity of Cu and Fe-PMs is improved. And the Fenton reaction is enhanced through transfer of electrons among the sodium dehydroacetate, the Cu and the Fe-PMs. When Cu and Fe-PMs oxidize TMB and H2O2, sodium dehydroacetate enhances the absorbance of the system, and on the basis, a novel colorimetric rapid detection method of sodium dehydroacetate is established.

The invention relates to a composite reverse osmosis membrane acidic cleaning agent, a preparation method and a cleaning process thereof, and belongs to the technical field of environment-friendly water treatment. The cleaning agent comprises the following components in percentage by mass: 4-8% of inorganic acid, 20-40% of organic acid, 1-3% of a surfactant, 0.5-1% of a chelating agent, 0.5-1% of a compound corrosion inhibitor and the balance of deionized water. The composite corrosion inhibitor is formed by compounding 2-mercaptobenzothiazole and the like according to a specific mass ratio, the molecular weight of polyaspartic acid is 5000, and the molar ratio of Zn to Mo in the zinc-molybdate compound is 2: 1. The preparation method comprises the following four steps: firstly preparing a compound corrosion inhibitor premix, then preparing an acidic base solution, and then sequentially adding the components to finally obtain the cleaning solution. According to the cleaning process, a cleaning agent and deionized water are mixed, the membrane flux recovery rate is larger than or equal to 85% through cleaning of a specific process, the reverse osmosis membrane can be effectively cleaned, and the performance of the reverse osmosis membrane can be recovered.

The invention discloses a high-initial-efficiency fast-charge graphite composite material and a preparation method thereof, the composite material is of a core-shell structure, the core is graphite, and the shell is lithium sulfonate / lithium molybdate and an amorphous carbon coating layer thereof; the mass ratio of the shell is 5-15 wt% according to the mass ratio of the composite material being 100%. The preparation method comprises the following steps: adding a molybdenum compound into a solvent to prepare a solution, adding graphite oxide, an inorganic lithium salt and a carbon nanotube conductive solution, reacting for 2-12 hours at the temperature of 50-120 DEG C, filtering, carbonizing filter residues to obtain a lithium molybdate conductive agent coated graphite material, and depositing a lithium sulfonate derivative on the surface of the lithium molybdate conductive agent coated graphite material by an atomization method to obtain the lithium molybdate conductive agent coated graphite material. The electron and ion conductivity of the material can be improved, and the rate and the first efficiency of the material can be improved.

The invention discloses a supported iron-molybdenum catalyst for formaldehyde production and a preparation method and application thereof, and belongs to the field of catalysts.The catalyst comprises a core-shell structure, the core of the catalyst is a carrier, molybdenum trioxide is supported on the carrier, and the shell of the catalyst is iron molybdate. The carrier is selected from at least one of silicon dioxide, aluminum oxide, titanium oxide, magnesium oxide, magnesium silicate, a molecular sieve, white carbon black and hydroxyapatite; the preparation method comprises the following steps: firstly, loading molybdenum trioxide on a carrier, then dispersing the carrier in deionized water, dropwise adding a molybdenum source solution and an iron source solution in a parallel flow manner under stirring to perform deposition loading of iron molybdate, and performing aging, drying, forming and calcining to obtain the catalyst. The catalyst is used for preparing formaldehyde by oxidizing methanol, dimethyl ether and methylal; according to the catalyst disclosed by the invention, the raw material cost and the pollutant treatment capacity are obviously reduced due to the reduction of the dosage of molybdenum and iron components, and the catalyst has relatively good activity and stability.

The invention provides a visual detection method for interface water droplet induced electron generation in a high-temperature and high-pressure hydrocarbon-water system, and belongs to the technical field of in-situ analysis of electrons in mixed fluid. The detection method comprises the following steps: preparing a fused quartz capillary reaction cavity; loading a sample in a fused quartz capillary reaction cavity: sequentially inserting a thin capillary syringe filled with a silicomolybdic acid aqueous solution and a thin capillary syringe filled with a hydrocarbon liquid into the fused quartz capillary reaction cavity, and injecting the silicomolybdic acid aqueous solution and the hydrocarbon liquid; and carrying out visual detection on the water droplets. Through the visual fused quartz capillary thermal simulation experiment device, the color change of the water droplets at the interface of the silicomolybdic acid aqueous solution and the hydrocarbon fluid under the conditions of high temperature and high pressure is visually displayed, and the color characteristics of the water droplets are observed in real time by using a microscope, so that whether the water droplets induce electron generation or not is judged; the problem that electrons generated by water droplets cannot be directly observed and detected under high-temperature and high-pressure conditions is solved.

The invention relates to the technical field of hazardous waste utilization, in particular to a comprehensive utilization method of a waste catalyst. The method specifically comprises the following steps: sequentially carrying out oxidizing roasting, wet ball milling and pressure leaching on the waste catalyst to obtain a first leaching solution and leaching residues; the first leachate is extracted in a multi-stage counter-current extraction mode, molybdenum and tungsten in the first leachate are extracted, and back extraction is conducted to obtain back extraction liquid containing molybdenum and tungsten; the strip liquor is subjected to standing deoiling, evaporation concentration and multi-stage counter-current extraction vanadium removal in sequence, and raffinate and vanadium-containing strip liquor are obtained; the raffinate mainly contains molybdate radicals and tungstate radicals; determining a separation mode according to different molar ratios of molybdenum and tungsten; carrying out acid leaching on the leaching residues by utilizing a sulfuric acid solution at normal temperature and normal pressure to obtain a second leaching solution; and a cobalt extraction agent and a nickel extraction agent are respectively used for extraction, and a cobalt sulfate product and a nickel sulfate product are obtained after reverse extraction and evaporative crystallization. According to the method provided by the invention, metal resources such as vanadium, tungsten, cobalt, molybdenum and nickel in the waste catalyst can be recycled.

The invention discloses a sodium ion battery layered oxide positive electrode material based on surface reconstruction and a preparation method thereof, and belongs to the field of sodium ion batteries. The positive electrode material comprises a positive electrode material body with a layered structure and a reconstruction layer with a disordered rock salt structure on the surface of the body, and the whole positive electrode material is of a disordered rock salt / layered heterostructure; the positive electrode material body is Na < 0.71 > Li < 0.2 > M < x > Mn < 0.8-x > O < 2 >, x is more than or equal to 0.05 and less than or equal to 0.25, and M is any one element of Al, Fe and Ni; the reconstructed layer of the disordered rock salt structure is obtained by quenching the positive electrode material body in a molybdate aqueous solution, and the thickness of the reconstructed layer of the disordered rock salt structure is 2-5nm. The sodium ion battery layered positive electrode material provided by the invention has the characteristics of high specific capacity and high cycle stability.

The invention relates to the technical field of electro-catalysis oxygen evolution, and particularly discloses a nickel-molybdenum foam composite oxygen evolution electro-catalysis material with high-valence nickel induced by molybdate radicals and a preparation method of the nickel-molybdenum foam composite oxygen evolution electro-catalysis material aiming at the problem that an existing oxygen evolution electro-catalysis material is insufficient in comprehensive performance or poor in performance stability. Soaking in a NaCl aqueous solution, and taking out; s2, mixing the nickel-molybdenum alloy foam with a K3 [Fe (CN) 6] aqueous solution, heating, and carrying out a hydrothermal reaction; and S3, finally, the nickel-molybdenum alloy foam is placed in the air or oxygen atmosphere and heated to 350-450 DEG C, heat preservation treatment is conducted for 2 h, and the nickel-molybdenum foam composite oxygen evolution electro-catalysis material is obtained. Molybdate anions are adopted as a sustainable induction source to be coupled with a NixOy / Fe3O4 heterogeneous interface, integrated construction is achieved on a nickel-molybdenum foam framework, and the nickel-molybdenum foam composite material has the advantages of being low in overpotential, high in stability, high in activity, high in binding force and long-term in durability and meanwhile being simple in process, easy to amplify on a large scale and the like.

The invention provides a synergistic accelerant suitable for SNCR (selective non-catalytic reduction) denitration and application of the synergistic accelerant. The synergistic accelerant comprises the following components in parts by weight: 2-80 parts of an activating agent, the activating agent is selected from at least one of sodium glycinate, sodium glutamate, sodium iminodiacetate, sodium aspartate, sodium aminopropionate, sodium aspartate and potassium aspartate; 3-12 parts of a catalyst, wherein the catalyst is selected from soluble heteropolyacid; 1-10 parts of a catalytic promoter; the catalytic promoter is selected from at least one of soluble tungstate and molybdate. A trace amount of synergistic accelerant is added into a common SNCR denitration solution, so that the reaction speed of NOx and reducing agents such as ammonia or urea can be increased, a temperature window of SNCR reaction moves downwards, the application range of the traditional SNCR technology is expanded, the removal efficiency of NOx is improved, and a low-cost and high-efficiency method is provided for pollution abatement of nitric oxide in waste gas.

The invention relates to a water-based recoatable low-surface-energy coating for a steel structure surface and a preparation method of the water-based recoatable low-surface-energy coating, and belongs to the technical field of coating preparation. The paint is composed of the water-based silica sol, the acrylic resin, the modified anti-rust pigment and the like, the modified anti-rust pigment is prepared by dispersing mica iron oxide, aluminum triphosphate and bismuth molybdate in fluorocarbon resin and methacrylic resin, and the paint has excellent anti-rust performance. The low-surface-energy additive is prepared by mixing raw materials such as perfluoroalkyl ethanol and perfluoroalkyl acrylate, so that the coating is endowed with the characteristic of low surface energy. The preparation method comprises the following steps: mixing and dispersing the deionized water, the dispersing agent, the defoaming agent and the modified anti-rust pigment, adding the water-based silica sol, the acrylic resin, the flatting agent and the low-surface-energy auxiliary agent, and continuously stirring to finally obtain the coating. The coating has the characteristics of excellent rust resistance, low surface energy and recoatability, is suitable for coating the surface of a steel structure, and can improve the corrosion resistance and prolong the service life of the steel structure.

The invention discloses a method for preparing a core-shell structure phase hydrorefining catalyst, comprising the following contents: (1) gelling, aging and filtering a first precipitant, a sodium molybdate solution and a solution containing Ni and Si to obtain a filter cake of a first slurry, and then treating it with a mixed aqueous solution of aluminum salt and organic alcohol to obtain a mixed slurry; (2) adding a Ni-containing solution, a sodium tungstate solution, a second precipitant and the mixed slurry obtained in step (1) to a reactor containing water and an oily liquid to gel and age them to generate a second slurry; (3) filtering, drying and molding the slurry to obtain a molded product; (4) soaking the molded product in an organic acid solution, and desalting the soaked molded product to obtain a catalyst. The preparation process of the method is clean and pollution-free, and the prepared catalyst has a core-shell structure, a large pore volume and a large pore size, and is used in processes such as distillate hydrodesulfurization and denitrogenation, and has high hydrodesulfurization and hydrodenitrogenation reaction performance.

The invention relates to the technical field of catalysts, in particular to a molybdenum-based oxide / carbide / GO heterojunction catalyst, a preparation method thereof and application of the molybdenum-based oxide / carbide / GO heterojunction catalyst in the field of fuel oxidation desulfurization. The preparation method comprises the following steps: S1, adding dimethylimidazole and metal salt into a graphene oxide aqueous solution, and stirring for reaction; s2, adding an aniline monomer and an initiator, dropwise adding phosphomolybdic acid as a molybdenum source, and centrifuging, washing and freeze-drying a product after the reaction is finished to obtain a polyaniline modified ZIFs / GO composite precursor adsorbed with the molybdenum source; and S3, performing high-temperature pyrolysis on the composite precursor in a protective atmosphere to obtain the catalyst. The invention provides a mode of constructing a molybdenum-based oxide / carbide heterostructure by enhancing the electron-donating capability and conductivity of a carrier through double-doped electron-donating elements, and develops a catalyst with high catalytic activity and low cost. The catalytic efficiency in the oxidative desulfurization process can be effectively improved.

The invention provides a preparation method of high-purity molybdenum trioxide, which belongs to the technical field of molybdenum trioxide production and comprises the following steps: S1, crushing, grinding and roasting molybdenum ore sand to obtain crude molybdenum oxide, adding the crude molybdenum oxide into a sodium hydroxide solution, heating, stirring and filtering to obtain a crude sodium molybdate solution; s2, adjusting the pH value of the crude sodium molybdate solution to 5.5-7.0, introducing the crude sodium molybdate solution into an exchange column of macroporous cation exchange resin, then adjusting the pH value of the solution to 7.0-8.5, and introducing the crude sodium molybdate solution into an exchange column filled with anion exchange resin to obtain a high-purity sodium molybdate solution; s3, excessive ammonia water is added into the high-purity sodium molybdate solution, ammonium molybdate is separated out, washing and drying are conducted, and high-purity ammonium molybdate is obtained; and S4, the high-purity ammonium molybdate is put into a rotary calcining furnace, rare earth oxide is sprayed on the inner wall of a furnace tube, and the high-purity molybdenum trioxide is prepared by adopting a calcining mode of firstly heating, then cooling and then heating. According to the invention, the purpose of producing high-purity molybdenum trioxide is realized.

The invention discloses cobalt molybdenum nitride / cobalt modified nitrogen-doped hollow carbon microspheres as well as preparation and application thereof, and relates to the technical field of electrochemical energy storage devices. Carboxylated polystyrene microspheres, soluble zinc salt and cobalt salt, phosphomolybdic acid and 2-methylimidazole are dispersed in methanol, a PMA (at) ZnCo-ZIFs / PS precursor of a spherical structure is obtained, then the PMA (at) ZnCo-ZIFs / PS precursor is placed in an inert atmosphere for carbonization treatment, and the cobalt molybdenum nitride / cobalt modified nitrogen-doped hollow carbon microsphere material is obtained. According to the structure and the preparation method, the nitride / metal cobalt component and the nitrogen-doped sodium affinity sites are introduced at the same time, uniform transportation and nucleation of sodium ions are effectively induced, sodium metal is guided to deposit in a specific three-dimensional structure, growth of sodium dendrites is effectively inhibited, volume expansion of metal sodium in the reaction process is relieved, the preparation method is simple and convenient, and the preparation method is suitable for industrial production. The cost is low, the electrochemical performance of the sodium metal battery assembled by using the composite material can be remarkably improved, and the composite material has a good large-scale application prospect.

The invention provides a double-defect-modified porous carbon nitride photocatalyst prepared by one step from ferromolybdic acid as well as a preparation method and application of the double-defect-modified porous carbon nitride photocatalyst. The catalyst is of a thin-layer porous structure, so that the specific surface area of the catalyst is increased, and more surface active sites are provided for adsorption and reaction; compared with pure g-C3N4, the visible light absorption intensity of the catalyst is obviously enhanced, due to the existence of surface N vacancies and defects formed by doping of metal oxides, effective charge separation is enhanced, the photon-generated carrier separation and transfer capacity is higher under visible light irradiation, and the catalytic activity is remarkably improved. When the photocatalyst is applied to degradation of tetracycline antibiotic pollutants, photocatalytic degradation of tetracycline can be realized only under the condition of low-power 5W LED visible light, the preparation process is simple, and the cost is lower.

The invention relates to the technical field of molybdenum slag resource recycling, in particular to a molybdenum slag resource recycling method which comprises the following steps: performing crushing, washing and drying pretreatment on molybdenum slag; naCl, KCl and NaF serve as fused salt, the fused salt, the cathode and the anode form a fused salt electrochemical system, the pretreated molybdenum slag is added into the fused salt for an electrochemical reduction reaction, and molybdenum in the molybdenum slag is reduced and separated out at the cathode; washing the precipitated metal molybdenum, and drying to obtain Mo powder. Resourceful treatment of the molybdenum-containing solid waste residues is achieved by adopting a molten salt electrochemical reduction recovery mode, and molybdenum elements are efficiently recovered into a metal state from complex molybdenum residues through electrochemical selective reduction in a molten salt system.

The invention discloses a preparation method of a chemical composite plating solution based on nano niobium carbide. The preparation method comprises the following steps: step 1, pretreating niobium carbide (NbC) powder; step 2, preparing a chemical plating solution, wherein every 1L of the chemical plating solution contains 30g of nickel chloride, 20g of sodium hypophosphite, 10g of sodium citrate, 5g of glycine, 10g of sodium acetate, 0.3 g of sodium dodecyl benzene sulfonate and 80mg of zinc molybdate; fixing the volume to 1L by using distilled water; 3, measuring the niobium carbide suspension liquid, mixing the niobium carbide suspension liquid with the chemical plating solution, and fixing the volume, so that the content of niobium carbide in the chemical composite plating solution is 0.01-0.3 g / L; adjusting the pH value of the solution to 5.8; according to the method, niobium carbide nanoparticles are added into the chemical composite plating solution, so that the surface of a plated part and metal gold are combined with the particles, and the hardness and wear resistance of a base material are effectively improved; the effect on a 60-80-micron nickel-phosphorus coating in the industry is achieved through the ultrathin chemical composite coating (8-10 microns), so that the corrosion resistance and the wear resistance of the product are enhanced.

The invention discloses a preparation method of chromium-free fingerprint-resistant liquid for an aluminized zinc plate, and relates to the technical field of metal surface treatment materials.The preparation method comprises the steps that a benzotriazole-cerium molybdate composite corrosion inhibition system is constructed, and multiple layers of adsorption films are formed through intermolecular pi-pi accumulation and rare earth ion coordination; meanwhile, a graphene oxide / nano silicon dioxide synergistic enhancement system is introduced, graphene sheet layers are directionally arranged to form a physical barrier, and micropores are filled with nano particles to improve compactness; and meanwhile, a lanthanide rare earth compound is adopted for modifying the flash-rust inhibitor, the stability of a passivation film on the metal surface is enhanced through the empty orbital characteristic of rare earth elements, the nanometer material gradient dispersion technology is combined with the ultrasonic-mechanical coupling dispersion technology, filler uniform distribution and interface bonding strengthening are achieved, and the fingerprint resistance, corrosion resistance and the like of the film layer are effectively guaranteed.

The invention relates to the technical field of cables, in particular to fire-resistant silicone rubber, a preparation method thereof and a cable, and the fire-resistant silicone rubber is composed of a matrix resin composite system, a composite flame-retardant system, a nanometer enhancement and smoke suppression system and an interface and vulcanization system, the matrix resin composite system comprises methyl vinyl silicone rubber, vinyl silicone rubber and macromolecular polyethylene, the composite flame-retardant system comprises nano aluminum hydroxide, zinc borate and transition metal nitride, and the nano enhancement and smoke suppression system comprises modified nano silicon dioxide, organic montmorillonite and zinc molybdate. The interface and vulcanization system comprises a silane coupling agent, dicumyl peroxide and a platinum catalyst. Therefore, the problems that in the prior art, fire resistance is insufficient, toxic gas is released during combustion, the mechanical property is poor, machining is complex, and environment friendliness is low are solved.

The invention discloses a super-lubricity microcapsule, a composite material thereof and preparation methods of the super-lubricity microcapsule and the composite material. The super-smooth microcapsule comprises a core material and a wall material coating the core material, the core material comprises a component A and a component B; the component A comprises oxymolybdenum dialkyl dithiophosphate, molybdenum dialkyl dithiocarbamate, a molybdenum amine complex, molybdenum naphthenate, molybdenum alkyl salicylate, nitrogen-containing oxymolybdenum dialkyl dithiophosphate, molybdenum bisphenol, molybdenum thiophosphate, molybdenum hydroximic acid, molybdenum fatty acid, organic molybdate, molybdenum schiff base, tripolymolybdenum salt, ethyl thiotungstate and propyl thiotungstate; one or more of butyl thiotungstate and butyl thiotungstate; and the component B is ionic liquid or lubricating oil. The super-lubricity microcapsule composite material is prepared from a super-lubricity microcapsule and a base material with a core-shell structure, wherein the base material comprises a solid lubricant core material and a polymer shell material coating the core material. The preparation method disclosed by the invention is simple, feasible and high in operability, can realize macroscopic super-lubricity in an atmospheric environment, and has a very high application value.

The invention provides a preparation method of a high-temperature-resistant graphite pipe for spectral analysis, and belongs to the technical field of spectral analysis, and the preparation method comprises the following steps: S1, preparing a high-purity graphite pipe matrix and carrying out surface activation treatment; s2, preparing composite sol, wherein the composite sol is formed by mixing silica sol, molybdate and phytic acid; s3, infiltrating the composite sol into the graphite matrix by adopting a vacuum-pressurization alternate impregnation process; s4, carrying out stepped heating heat treatment in an inert environment to form a SiC-MoSi composite reinforced phase; and S5, depositing a pyrolytic carbon layer on the inner wall of the graphite pipe. The silica sol, the molybdate and the phytic acid have a synergistic effect to form a SiC-MoSi composite phase, the phytic acid can prevent the molybdate from gathering and can promote the growth of SiC whiskers in heat treatment, so that the anti-oxidation temperature of the graphite pipe is increased, the temperature resistance and the heat stability of the graphite pipe are improved, and the anti-oxidation performance of the graphite pipe is improved. And finally, the use frequency of the graphite pipe is greatly increased.

The invention relates to a samarium molybdate / reduced graphene oxide electro-catalytic material, a preparation method and application thereof and an electrochemical sensor, and relates to the technical field of electro-catalytic materials and electrochemical sensors, the preparation method comprises the following steps: dispersing GO in water, and stirring to obtain a GO suspension; the preparation method comprises the following steps: separately adding Sm (NO3) 3.6 H2O and Na2MoO4. 2H2O into water for ultrasonic dissolution, and mixing to obtain a first mixture; stirring and mixing the GO suspension and the first mixture to obtain a second mixture, and the like. The samarium molybdate / reduced graphene oxide electro-catalytic material is synthesized by a hydrothermal synthesis method and is used for modifying a glassy carbon electrode so as to be applied to electrochemical detection of FZD for the first time. Compared with a traditional detection method, the detection method has the advantages of being simple, efficient, green, environmentally friendly, sensitive in response and portable, and a new way is provided for detection of carcinogenic residues.

The present invention relates to a Glycol based antifreeze liquid composition for combustion engines, electric vehicles, industrial and submersible motors. More particularly, the present invention relates to a Glycol based corrosion-inhibited antifreeze liquid composition, the said liquid composition comprises glycols, deionized water, alkali molybdate, alkali metal octoate or neodecanoate, rare-metal octoate or neodecanoate, dyes. The liquid composition of the present invention is environment-friendly, ready to use composition that will improve efficiency of combustion engines, industrial and submersible motors to the great extent and also provides excellent corrosion protection to the internal parts of the cooling system of combustion engines, electric vehicles and industrial and submersible motors.

The invention relates to a preparation method of an oxygen vacancy-rich bismuth molybdate / bismuth vanadate composite photo-anode and a product and application thereof, and belongs to the technical field of photoelectrocatalysis. The invention discloses a preparation method of an oxygen vacancy-rich bismuth molybdate / bismuth vanadate (Bi2Mo2O9 / BiVO4) composite photo-anode, which mainly comprises the following steps: immersing a fluorine ion-doped tin dioxide (FTO) conductive glass substrate into a Bi < 3 + > ion solution and an I <-> ion solution to form a bismuth oxyiodide (BiOI) film, dropwise adding a dimethyl sulfoxide solution of vanadyl acetylacetonate (VO (acac) 2), and putting into a muffle furnace to prepare the BiVO4 photo-anode. And then vertically immersing into a Bi < 3 + > ion solution and a Mo < 6 + > ion solution, and carrying out annealing treatment in an argon atmosphere to prepare the Bi2Mo2O9 / BiVO4 composite photoanode rich in oxygen vacancies. The Bi2Mo2O9 / BiVO4 material rich in oxygen vacancies is a metal oxide composite photo-anode, the photoelectrocatalysis efficiency can be improved, and hydrogen peroxide (H2O2) can be continuously generated in natural seawater through photoelectrocatalytic oxidation of water for a long time.

The invention provides an anodic oxidation passivation method of a neodymium-iron-boron permanent magnet zinc coating, which comprises the following steps of: performing electrochemical anodic oxidation by taking a neodymium-iron-boron permanent magnet with a zinc coating on the surface as an anode, a Pt sheet as a cathode and a passivation solution as an electrolyte, forming a passivation layer on the surface of the neodymium-iron-boron permanent magnet with the zinc coating on the surface, and cleaning and drying to obtain the neodymium-iron-boron permanent magnet with the zinc coating on the surface. A chromium-free passivation film is formed on the neodymium-iron-boron permanent magnet zinc coating, and passivation of the neodymium-iron-boron permanent magnet zinc coating is completed; the passivation solution is prepared from 10 g / L to 20 g / L of molybdate, 10 g / L to 15 g / L of ammonium fluozirconate, 1 g / L to 10 g / L of etidronic acid, 1 g / L to 10 g / L of sodium dihydrogen phosphate, 1 g / L to 10 g / L of nitric acid, 1 g / L to 10 g / L of phosphoric acid and the balance distilled water. According to the method disclosed by the invention, a complete, uniform and compact passivation film is formed on the surface of the zinc coating after passivation, the corrosion potential is improved while the corrosion current is effectively reduced, and the time for generating a rust spot in a salt spray test exceeds 72 hours.