The invention relates to the technical field of
sodium ion battery positive
electrode materials, in particular to a high-
voltage positive
electrode material, a preparation method thereof, a positive
electrode plate and a
sodium ion battery. The high-
voltage positive
electrode material comprises an O3-phase layered
oxide matrix material and a
coating layer
coating the surface of the O3-phase layered
oxide matrix material, the
chemical formula of the O3-phase layered
oxide base material is NaaNixAyMnpGqO2, A comprises a
metal element with the valence of + 2 and / or + 3, and G comprises a
metal element with the valence of + 4; and modification elements in the
coating layer comprise at least one of Al, B, Ca, Co, Ce, La, Mg, Mo, Nb, Sr, Sn, W, Y, Zr, Zn, Bi and Ti. The material has reversible
phase change under
high voltage, can work under
high voltage, and has excellent cycle performance.