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192results about How to "High electrical conductivity" patented technology

Molybdenum disulfide nanosheet/nitrogen-doped carbon fiber hybrid material and preparation method therefor

The invention belongs to the technical field of carbon fiber materials, and particularly discloses a molybdenum disulfide nanosheet / nitrogen-doped carbon fiber hybrid material and a preparation method therefor. The molybdenum disulfide nanosheet / nitrogen-doped carbon fiber hybrid material is prepared by growing a molybdenum disulfide nanosheet on a nitrogen-doped carbon fiber with a three-dimensional network structure in situ by taking molybdenum salt and sulfosalt as precursors; A preparation process for the molybdenum disulfide nanosheet / nitrogen-doped carbon fiber hybrid material comprises: preparing the nitrogen-doped carbon fiber through in-situ oxidization-reduction reaction, freeze-drying and high-temperature carbonization; and growing the molybdenum disulfide nanosheet on the nitrogen-doped carbon fiber in situ through a one-step solvothermal method. According to the nitrogen-doped carbon fiber prepared by the preparation method, the wettability of the carbon fiber and a solvent is improved, and more active sites are provided for growth of inorganic particles; and moreover, the electrical conductivity of the carbon fiber is greatly improved, so that the migration rate for electrons in an electro-catalysis hydrogen-evolution process is increased. The molybdenum disulfide nanosheet / nitrogen-doped carbon fiber hybrid material prepared by the preparation method can be used as an ideal high-performance catalyst material and can be used for the electro-catalysis hydrogen-evolution field.
Owner:FUDAN UNIV

Flake MoS2/graphene composite aerogel and preparation method thereof

The invention relates to a flake MoS2/graphene composite aerogel and a preparation method thereof and belongs to the technical field of anode materials of lithium ion batteries. The preparation method comprises the following steps: ultrasonically dispersing a certain quantity of graphene oxide solution into deionized water, adding a certain quantity of water-soluble molybdate and thiourea, then adding 0.1-3mL organic amine solution, taking out a cylindrical product after hydrothermal reaction at the temperature of 160-240 DEG C, freeze-drying, and then carrying out thermal treatment for 2h in the mixed atmosphere of argon and hydrogen at the temperature of 800 DEG C to obtain the flake MoS2/graphene composite aerogel. According to the flake MoS2/graphene composite aerogel and the preparation method thereof disclosed by the invention, thin layers of graphene are connected with one another in a staggering mode to form a three-dimensional ordered conductive network and form micron pore canals, MoS2 is uniformly dispersed on the ultra-large superficial area, and thus, the problems of volume expansion and crushing materials are effectively solved; meanwhile, the structure stability and the cycle performance of the flake MoS2/graphene composite aerogel, serving as the anode material, are improved.
Owner:SHANGHAI UNIV

Ferrite-based ceramic composite material as well as preparation method and application thereof

ActiveCN102390989AMeet low temperature requirementsRealize the structureCeramic compositeStructure and function
The invention discloses a ferrite-based ceramic composite material as well as a preparation method and application thereof. The composite material is composed of ferrite, a carbon nanotube and a ceramic material, wherein the ferrite and the ceramic material are cladded on the tube wall of the carbon nanotube, and the ceramic material is one or several kinds of aluminum oxide, aluminum nitride, and silicon nitride. The three phases of materials, namely, the ferrite, the carbon nanotube and the ceramic, are compounded to make the advantages and disadvantages of all phases of materials complementary, so that the electrical conductance of the composite material is increased, the impedance matching performance of the composite material is improved, the wave absorption performance of the composite material is made adjustable, the structure and function integration of the ferrite-based ceramic material is realized, and thus, the application range of the composite material in the high-tech field is expanded. In addition, the powder of the composite material is prepared by adopting a coprecipitation hydrothermal method and is further prepared into a block material by adopting a microwave sintering method, and the ferrite-based ceramic composite material has the advantages that all phases are dispersed uniformly, the densification degree of the sintered material is high, the production cost is low, and the large-scale industrialization is easy to realize.
Owner:NINGBO INST OF MATERIALS TECH & ENG CHINESE ACADEMY OF SCI

Silicon-based composite anode material for lithium ion battery and preparation method thereof

The invention discloses a silicon-based composite anode material for a lithium ion battery and a preparation method thereof. The anode material comprises a graphite skeleton and an amorphous carbon layer which coats the graphite skeleton. The graphite skeleton is filled with a silicon material coated with a carbon-containing structure. The silicon material and the graphite skeleton are combined through a loose carbon material. The preparation method at least comprises the following steps: (1) preparing the silicon material coated with the carbon-containing structure; (2) preparing spherical particles with graphite as the main body; (3) coating the spherical particles with the amorphous carbon layer; and (4) granulating. According to the invention, the electric insulation problem of silicon anode due to its volume change can be solved, and it can be guaranteed that silicon active component can always be electrically contacted with a current collector during the charge-discharge cycle process. Meanwhile, huge stress effect caused by volume expansion/shrinkage of the active material silicon is further buffered. Then, the composite material has characteristics of high electrochemical cycle stability and regulable specific capacity.
Owner:GENERAL RESEARCH INSTITUTE FOR NONFERROUS METALS BEIJNG

Lithium ion battery gel electrolyte with multi-stage structure and preparation method thereof

The invention discloses lithium ion battery gel electrolyte with a multi-stage structure and a preparation method thereof. The lithium ion battery gel electrolyte with the multi-stage structure comprises a polymer network cross-linking framework and a liquid electrolyte in the network framework, wherein the polymer network physical cross-linking framework is composed of nano fibers of PVDF (Polyvinylidene Fluoride) electrostatic spinning, and the cross-linking framework is adsorbed to two sides of a base PE (Poly Ethylene) film. The preparation method comprises the following steps: 1) preparing an electrostatic spinning solution; 2) preparing a first-level framework structure by electrostatic spinning; 3) coating a polymer so as to prepare a second-level framework structure; and 4) carrying out high-temperature in-situ polymerization so as to prepare a PMMA (Polymethyl Methacrylate) gel polymer three-level framework structure. The gel frameworks are distributed in a level-by-level structure, and compared with a conventional gel system, the macromolecule cross-linking system of the multi-level structure has the advantages of high mechanical intensity, high fluid protection capability, high porosity of the network structure, high conductivity and the like, and paves the way for the research of a new generation of gel electrolytes.
Owner:TIANJIN JUYUAN NEW ENERGY TECH CO LTD

Acidic ionic liquid and method for separating and purifying rare earth or rare and precious metals by solvent extraction coupling electrolytic process

The invention relates to acidic ionic liquid and a method for obtaining objective metals or removing poisonous metals from metal solid-phase matters. The method comprises the following steps: (1) taking the acidic ionic liquid of the invention as an extraction agent, and carrying out solvent extraction on metal solid-phase matters; and (2) carrying out electrolysis on an extract of the step (1) to obtain the objective metals or remove the poisonous metals, wherein the metal solid-phase matters comprise the following components: (a) indissolvable oxide, chloride, phosphate compounds or hydroxide of the objective metals, (b) a mixture of indissolvable oxides of various metals, (c) spent fuels containing poisonous metals and the like. By the method, the use amount of acid and organic solvents can be reduced effectively. In addition, by characteristics of low volatility, high electric conductivity and the like of the acidic ionic liquid, required energy during electrolysis is reduced, costs and environmental harm in a metallurgical process are reduced, and environmental protection property of the process is improved. The method has great value on the industry.
Owner:中科新镧系(厦门)科技有限公司

Preparation method of nitrogen-doped graphene electrode

The invention provides a preparation method of a nitrogen-doped graphene electrode, which comprises the following steps: acquiring a graphene oxide suspension; mixing the graphene oxide suspension with a metal salt solution to obtain an electrolyte; putting at least one pair of electrode pieces connected with direct current into the electrolyte, switching on the direct current to carry out electrophoresis so as to obtain electrode pieces with graphene oxide deposited on the surface, and drying under vacuum conditions; reacting the graphene oxide deposited on the surface of the dried electrode pieces with ammonia gas to carry out nitrogen doping reaction, thereby obtaining a nitrogen-doped graphene electrode precursor; and in a hydrogen protective atmosphere, carrying out reduction reaction on the nitrogen-doped graphene electrode precursor and hydrogen to obtain the low-oxygen-content graphene-doped graphene electrode. The preparation method provided by the invention has the advantages of simple technique, high efficiency and low cost; and the nitrogen-doped graphene electrode prepared by the method has the advantages of low equivalent series resistance, high electric conductivity and low oxygen content in the nitrogen-doped graphene in the nitrogen-doped graphene electrode.
Owner:OCEANS KING LIGHTING SCI&TECH CO LTD +1

Silicon, silicon-oxygen-carbon and graphene-based composite material, and preparation method and application thereof

The invention relates to a silicon, silicon-oxygen-carbon and graphene-based composite material, which comprises a graphene-based material and a silicon nano-material, wherein the silicon nano-material is attached to the surface of the graphene-based material; and the silicon nano-material is connected with the graphene-based material through a silicon-oxygen-carbon chain structure. The invention further provides a preparation method of the composite material. The silicon-oxygen-carbon structure contained in the composite material provided by the invention can ensure that the silicon material is relatively uniformly and firmly distributed on the surface of a graphene-based material, and can still electrically contact the conductive graphene-based material in the charge-discharge process after a relatively large volume change; and the graphene-based material not only can ensure the overall conductivity of the material, but also can relieve stress of the silicon material caused by the volume change in the charge-discharge process through folds. The composite material provided by the invention is excellent in overall performance, and has the characteristics of high electrochemical cycle stability and adjustable specific capacity.
Owner:CHINA AUTOMOTIVE BATTERY RES INST CO LTD +1

Preparation method of niobium pentoxide/reduced graphene oxide composite negative electrode material

The invention discloses a preparation method of a niobium pentoxide/reduced graphene oxide composite negative electrode material. The preparation method comprises the following steps of (1) mixing graphene oxide nanosheets with water and carrying out stirring and ultrasonic dispersing to obtain graphene oxide nano-dispersion; (2) dissolving niobium pentachloride into water and stirring to obtain niobium pentachloride suspension, sequentially adding an organic cosolvent and hexamethyleneteramine into the niobium pentachloride suspension and stirring to obtain a white solution; (3) mixing the graphene oxide nano-dispersion with the white solution, stirring until uniform dispersion to obtain a mixed solution, putting the obtained mixed solution into a high pressure reactor to carry out hydrothermal reaction; (4) after hydrothermal reaction is completed, washing and drying the obtained sediments to obtain solid powder; and (5) carrying out thermal treatment on the solid powder in argon atmosphere. The preparation method is convenient to operate and controllable in reaction conditions; and a lithium battery provided with a negative electrode prepared from the obtained composite negativeelectrode material has excellent cycle performance and rate capability.
Owner:CENT SOUTH UNIV
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