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531results about How to "Avoid chalking" patented technology

Preparation method of continuous oxide fiber reinforced oxide ceramic based composite

ActiveCN105254320AAvoid Density GradientsAvoid fiber strength loss or pulverizationSolventOxide ceramic
The invention belongs to the preparation technology of a continuous fiber reinforced ceramic based composite, and relates to a preparation method of a continuous oxide fiber reinforced oxide ceramic based composite. The technology comprises the steps that an organic ceramic precursor solution is utilized to serve as solvent to prepare slurry with ceramic powder, the slurry is smeared on the surface of oxide fiber fabric to prepare oxide fiber prepreg, the technological processes of laminating, mold pressing and sintering are conducted on the prepreg, a low-porosity ceramic based composite preform is obtained, the repeated processes of soaking and splitting are conducted by adopting an organic ceramic precursor, and the continuous fiber reinforced ceramic based composite with the ideal density is obtained. According to the preparation method of the continuous oxide fiber reinforced oxide ceramic based composite, the organic ceramic precursor is adopted to serve as the solvent to prepare the ceramic slurry, the organic ceramic precursor can play a role of bonder for bonding the ceramic powder, low-temperature inorganic characteristics of the organic ceramic precursor can be utilized, fiber is protected against thermal damage caused by high temperature in the composite preparation process, and the composite strength is improved.
Owner:AVIC BEIJING AERONAUTICAL MFG TECH RES INST +1

Silicon-carbon composite material for lithium ion battery and preparation method thereof

The invention discloses a silicon-carbon composite material for a lithium ion battery and a preparation method for the silicon-carbon composite material, and belongs to the field of lithium ion batteries. The silicon-carbon composite material is characterized in that carboxymethylcellulose sodium is used as a bonding agent, a liquid phase coating technology is used for silicon-carbon compounding, and a spray drying technology is used for drying granulation to prepare the silicon-carbon composite material with uniform granularity and excellent performance for the lithium ion battery. The silicon-carbon composite material and the preparation method thereof have the advantages that 1, the composite material for the lithium ion battery is prepared through a silicon-carbon compounding technology, and the capacity of the composite material is higher than that of the conventional graphite cathode material, reaches over 500mAh / g, and can meet requirements on the growing of the market of lithium ion batteries; 2, carboxymethylcellulose is used as a bonding agent which can be effectively coated and bonded on the silicon-carbon material to prevent efflorescence caused by silicon during charging and discharging, so that the cycling performance of the silicon-carbon composite material is effectively improved; and 3, the liquid phase coating and spray drying granulation technologies are adopted, so that the silicon-carbon material can be uniformly coated and bonded, has uniform granules, and is small in specific area, and the cycling performance of the silicon-carbon composite material is further improved.
Owner:JIANGXI ZHENGTUO NEW ENERGY TECH CO LTD

Stain-resistant heat-insulation coating and preparation method thereof

The invention discloses a special electric stain-resistant heat insulation coating. The special electric stain-resistant heat insulation coating comprises the following components in parts by weight: 15-50 parts of a film formation emulsion, 5-30 parts of nano oxide powder, 10-20 parts of heat reflection pigment, 5-25 parts of hollow ceramic microbeads, 8-15 parts of a filler, 5-15 parts of additives and a proper amount of deionized water. The purposes of resisting stains and insulating heat can be achieved by introducing components such as nano oxide powder into the heat insulation coating. The invention also discloses a preparation method of the stain-resistant heat insulation coating. The preparation method of the stain-resistant heat insulation coating comprises the following steps: adding deionized water, part of the additives, the nano oxide powder, the hollow ceramic microbeads, the heat reflection pigment and filler into a grinder for grinding to obtain slurry; transferring the prepared slurry into a dispersing machine, adding the film formation emulsion and the rest of additives into the slurry, stirring and dispersing the slurry, filtering the slurry by a screen to obtain the stain-resistant heat insulation coating. The preparation method of the stain-resistant heat insulation coating is simple in process, easy to implement and simple and convenient to operate.
Owner:STATE GRID CORP OF CHINA +3

Application of high-molecular coating in aluminium negative electrode, aluminium negative electrode, preparation method thereof and secondary battery

The invention discloses application of a high-molecular coating in an aluminium negative electrode, the aluminium negative electrode, a preparation method thereof and a secondary battery and relates to the field of electrochemical energy storage devices. For the application of the high-molecular coating in the aluminium negative electrode, the aluminium negative electrode is used as a negative current collector and a negative active material simultaneously. The aluminium negative electrode is used as the negative current collector and the negative active material simultaneously and is coated with the high-molecular coating; the secondary battery comprises the aluminium negative electrode. The application disclosed by the invention has the beneficial effects that the problems that the volume of the aluminium negative electrode used as the negative current collector and the negative active material is expanded and the capacity is attenuated due to an unstable solid electrolyte membrane are relieved; after the high-molecular coating is applied on the aluminium negative electrode, electrolytic solution and the aluminium negative electrode can be effectively isolated, the aluminium negative electrode can be prevented from being eroded and reacted, the coulombic efficiency is effectively improved, the irreversible capacity can be reduced, the cyclic stability of the battery can be improved, simultaneously certain role is played in inhibiting powdering of the aluminium negative electrode in the process of volume expansion, and the integrity of the aluminium negative electrode structure can be ensured.
Owner:SHENZHEN INST OF ADVANCED TECH

Silicon-carbon composite material and preparation method thereof

The invention discloses a silicon-carbon composite material which is a composite material similar to a dragon fruit structure. The silicon-carbon composite material comprises a base core, a silicon-carbon composite housing and a coating layer. The silicon-carbon composite housing is formed by uniformly dispersing a plurality of nano silicon particles in conductive carbon. The nano silicon particles are formed by pyrolysis of a silicon source. The conductive carbon is formed by pyrolysis of an organic carbon source. The coating layer is a carbon coating layer. At least one carbon coating layeris provided. The thickness of a single carbon coating layer is 0.2 to 3[mu]m. Compared with the prior art, a silicon-carbon composite material precursor is formed by using vapor phase synchronous deposition, and carbon coating is performed to form the silicon-carbon composite material similar to the dragon fruit structure. The silicon-carbon composite material has a high first effect, low expansion and long circulation, slows down the silicon material grain growth during the heat treatment process, avoids the powdering of the material during the cycle, alleviates the volume expansion effect ofthe silicon-based material, and is improved in the cycle performance, the electrical conductivity and the rate performance.
Owner:DONGGUAN KAIJIN NEW ENERGY TECH

Pomegranate-like structured composite material preparation method

The invention discloses a pomegranate-like structured composite material preparation method which comprises the following steps: S1, taking a polyacrylonitrile solution, adding silica nanoparticles, and fully dispersing; S2, adding deionized water after stirring for emulsification to obtain a mud like precursor; S3, heating the mud like precursor obtained in the S2, and annealing to obtain a solid composite; and S4, grinding the solid composite obtained in the S3 into micron particles, adding a hydrogen fluoride solution for corrosion for a certain period of time, washing hydrogen fluoride, and drying to obtain a pomegranate-like structured composite material. According to the method, polyacrylonitrile is used for coating the silica particle surface, the polyacrylonitrile is emulsified when meeting water, so that the coated silicon particles are agglomerated, the coated silicon particles are carbonized and ground for formation of the pomegranate shaped structured silicon carbon composite material, HF is used for direct corrosion of the silicon nanoparticles in the material for preparation of the hollow pomegranate-like structured composite material, and detailed structure characterization and electrochemical performance testing of the material show that the material is good in performances.
Owner:SUN YAT SEN UNIV

Hollow/porous structure silicon-based composite material and preparation method thereof

The invention discloses a hollow / porous structure silicon-based composite material. The composite material comprises a hollow / porous structure, a silicon-carbon composite layer and a coating layer, the silicon-carbon composite layer is formed by evenly dispersing nano silicon or silica in a conductive carbon network, the conductive carbon network in the silicon-carbon composite layer is formed with binder through pyrolysis, the coating layer is a carbon coating layer, and at least one carbon coating layer is provided. The composite material provided by the invention is prepared through a method of evenly mixing the nano silicon / silica, the binder and salt, then, performing spray granulation, high temperature sintering, water desalination and coating treatment. The composite material provided by the invention is a lithium ion battery silicon-carbon cathode material with the advantages, such as high first effect, low expansion and long cycle; grain growth of the silicon material in a thermal treatment process is slowed, powdering of the material in a cycle process is avoided effectively, volume expansion effect of the silicon-based material is remitted, cycle performance is promoted,and conductivity and rate capability of the material are improved.
Owner:DONGGUAN KAIJIN NEW ENERGY TECH

Preparation method of silicon-based negative electrode active material, silicon-based negative electrode active material, lithium ion battery negative electrode material and lithium ion battery

InactiveCN108598413ASmall volume changeAvoid pulverization and electrode collapseCarbon compoundsCell electrodesCarbon coatingCvd graphene
The invention provides a preparation method of a silicon-based negative electrode active material, the silicon-based negative electrode active material, a lithium ion battery negative electrode material and a lithium ion battery, and relates to the technical field of lithium ion batteries. The preparation method comprises the steps of adding a macromolecule protection agent during the process of coating a silicon dioxide layer outside nanometer silicon, coating a grapheme oxide layer outside the silicon dioxide layer, add finally, performing hydrofluoric acid etching to obtain a Si/void/SiO2/void/Graphene composite material which takes the nanometer silicon as a core and which the silicon dioxide layer and the graphene layer are sequentially coated from inside to outside, and the technicalproblem that the silicon-based negative electrode active material with greatly-improved performance is difficult to obtain by traditional methods of single silicon nanocrystallization or carbon coating and porous structure preparation is reduced; and with the silicon-based negative electrode active material prepared by the method provided by the invention, the volume change of the nanometer coreduring the charge-discharge process can be reduced, and moreover, the conductivity and the dynamic flexibility of the silicon-based negative electrode active material can be improved.
Owner:桑德新能源技术开发有限公司 +1

Method for preparing nano tin/carbon composite nanofibers through electrospinning technology

The invention discloses a method for preparing nano tin / carbon composite nanofibers through the electrospinning technology. The method includes the steps that first, stannous chloride, polymethyl methacrylate and polyacrylonitrile are prepared into composite nanofibers through the electrospinning technology; then calcination is conducted under the nitrogen atmosphere, so that the polyacrylonitrile is carbonized, SnCl2 is decomposed, the polymethyl methacrylate is subjected to pyrolysis, accordingly, a porous structure is formed, and the nano tin / carbon composite nanofibers are obtained. The method has the advantages that the preparation technology is simple, the reaction condition is easy to control, and the repetitive rate is high; obtained Sn particles are only 1-2 nm and are evenly inlaid N-doped porous carbon nanofibers, and the mass percent of the Sn can reach 60-65%. The composite material is of a three-dimensional net structure which is formed by interweaving nanofibers from the microcosmic view, the composite material can be directly used as the negative electrode of a sodium-ion battery without a binding agent, high electrochemistry sodium storage reversible capacity can be achieved, excellent rate capability and cycling stability are achieved, and the application prospect is very bright.
Owner:NANKAI UNIV

Method for preparing tin dioxide/graphene-compounded anode material of lithium ion battery

The invention discloses a method for preparing a tin dioxide/graphene-compounded anode material of a lithium ion battery. The method comprises the following steps: uniformly mixing choline chloride, ethylene glycol and graphene oxide to obtain a mixed solution, adding stannous chloride to the mixed solution, performing ultrasonic oscillating reaction, and performing post-processing to obtain the product. According to the method for preparing the tin dioxide/graphene-compounded anode material of the lithium ion battery, a normal-pressure and normal-temperature one-step method is adopted, the adopted raw materials are simple in components and common and easy to obtain, the reaction conditions are mild and controllable, the reaction can be performed at normal temperature and normal pressure, and the preparation process is simple and practicable, has low requirements for equipment so as to be free from geographical restrictions, and is suitable for large-scale industrial production. The prepared tin dioxide/graphene-compounded anode material of the lithium ion battery has excellent electrochemical properties, and can be used as an active electrode substance for preparing an anode of the lithium ion battery so as to have a wide market application prospect.
Owner:SHENZHEN KEXIN COMM TECH

Lithium battery silicon-carbon nanotube composite cathode material as well as preparation method and application thereof

The invention discloses a lithium battery silicon-carbon nanotube composite cathode material as well as a preparation method and application of the lithium battery silicon-carbon nanotube composite cathode material. The preparation method of the lithium battery silicon-carbon nanotube composite cathode material comprises the following steps of: mixing and uniformly stirring an organic carbon source and nanometer silicon based on the mass ratio of (0.4-9): 1, adding a catalyst to obtain mixed slurry, drying by a closed circulation spray dryer to obtain a precursor, insulating the precursor for 1-5 hours at the temperature of 300-700 DEG C to obtain a sample, feeding the sample in a tube furnace, increasing the temperature to 500-900 DEG C under the mixed gas of gaseous organic carbon source and N2 and Ar2, and naturally cooling to obtain the lithium battery silicon-carbon nanotube composite cathode material. The lithium battery silicon-carbon nanotube composite cathode material has excellent electrochemical properties, high first charge-discharge efficiency up to more than 2000mAh/g, reversible specific capacity of about 1100mAh/g after cycle of 50 weeks, and good specific capacity and cycle performance, and the problems of low first efficiency, large irreversible capacity loss and poor conductivity of silicon when being used to prepare a lithium ion battery cathode are successfully solved.
Owner:SOUTH CHINA NORMAL UNIVERSITY

Preparation method and application of shell-core carbon-coated metal phosphide nanometer composite particle

The invention provides a preparation method of a shell-core carbon-coated metal phosphide nanometer composite particle. The obtained composite particle is used as a lithium ion battery negative electrode material to be applied to the field of a lithium ion battery. The preparation method comprises the steps of adding a certain proportion of a substance containing a carbon source and inert gas into automatic control DC arc metal nanometer powder production equipment, and evaporating a metal raw material to obtain a carbon-coated metal nanometer particle precursor; mixing and placing the precursor and red phosphorus powder in a high-pressure sealing reaction kettle for thermal treatment to obtain a carbon-coated metal phosphide nanometer composite material; and fabricating a lithium ion electrode plate by taking the carbon-coated nickel phosphide nanometer composite material as an active substance. The preparation method has the advantages that the carbon-coated nickel nanometer particle synthesized in an in-situ way is used as the precursor, the carbon-coated nickel phosphide nanometer composite particle is obtained by low-temperature phosphorization, and the composite particle has relatively high intercalation/de-intercalation lithium capacity density and cycle stability, is low in raw material cost and simple in process, can be prepared on a large scale and is suitable for industrial production.
Owner:CHANGZHOU INST OF DALIAN UNIV OF TECH

Method for preparing composite cathode material of silicon-carbon nanotube of lithium ion battery

The invention discloses a method for preparing a composite cathode material of a silicon-carbon nanotube of a lithium ion battery. According to the method, firstly, the surface of nano silicon is coated with a carbon source, carbon nanotubes are generated in microwave treatment, and furthermore the surface of silicon is also coated with an introduced catalyst, so that the carbon nanotubes which are coated with the carbon source and are generated through catalytic cracking are very uniformly distributed on the surface of nano silicon, the problems that in the prior art the nano silicon is high in volume expansion effect, low in first charge/discharge efficiency and poor in circulation stability are solved, and both the conductivity and the mechanical property of the composite cathode material prepared by using the method disclosed by the invention are greatly improved and the circulation property, the multiplying power charge and discharge performance and the initial charge-discharge efficiency of the composite cathode material as a lithium lion battery cathode material are all greatly improved when being compared with those of a silicon-carbon nanotube cathode material which is mixed in a mechanical ball-milling manner as silicon and carbon nanotubes are compounded in an in-situ manner in the method disclosed by the invention. In addition, the method disclosed by the invention is simple in process, and the energy consumption is greatly reduced due to the adoption of a simple and efficient microwave chemical method.
Owner:FUJIAN XFH NEW ENERGY MATERIALS CO LTD
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