The invention provides
solvent-free nonionic waterborne
polyurethane resin as well as a preparation method and application thereof. The
solvent-free nonionic waterborne
polyurethane resin is prepared from the following raw materials:
polymer polyol, diisocyanate, nonionic hydrophilic
polyol, an emulsifier, an amine chain
extender and an amino
silane coupling agent, non-ionic hydrophilic
polyol is adopted as an internal hydrophilic chain
extender, and an emulsifier is added for synergistic emulsification, so that the
water resistance of the obtained waterborne
polyurethane resin is effectively improved, the water swelling property of the waterborne polyurethane resin is reduced, the
jungle stability of the waterborne polyurethane resin is improved, and the waterborne polyurethane resin has the characteristics that the
solid content is relatively high, and
acetone does not need to be removed; the
water resistance and alkali resistance of the obtained waterborne polyurethane resin are further improved by further introducing an amine chain
extender and an amino
silane coupling agent, so that the waterborne polyurethane resin is applied to the field of waterborne
microfiber leather, and the prepared waterborne
microfiber leather is good in hand feeling, fine in crease, good in resilience and qualified in
jungle test.