The invention discloses a method for preparing mono-disperse 
polymer functional microspheres with a photochemical method. According to the invention, under the regulation of a reversible addition-fragmentation 
chain transfer (RAFT) 
reagent, 
polymer functional microspheres with various sizes such as nano-grade sizes and micron-grade sizes, and with uniform particle sizes are synthesized by using the photochemical method. First, mono-functional group carbon-carbon double-bond monomers, multifunctional group carbon-carbon double-bond cross-linking agents, monomers containing functional groups, a dispersing agent, a stabilizing agent, the RAFT 
reagent, a 
photoinitiator, a pore-forming agent, and the like are added into a mixed 
solvent; the mixture is subjected to 
ultrasonic emulsification, such that a uniform and stable dispersion liquid is produced; the dispersion liquid is transferred into a reaction 
bottle, and is stirred; 
vacuum pumping is carried upon the reaction 
bottle, and 
nitrogen is filled into the reaction 
bottle until 
constant pressure is achieved; the reaction bottle is irradiated by using an 
ultraviolet lamp under 
room temperature for approximately 8 hours, and the reaction is then stopped; an obtained reaction liquid is subjected to centrifugal 
sedimentation, washing, and 
drying, such that the mono-disperse 
polymer functional microspheres with uniform particle sizes are obtained. The preparation method provided by the invention is advantaged in high production efficiency, and is energy-saving and environment-friendly. According to different requirements, thousands of specifications of mono-disperse microspheres with particle sizes of 5 nanometers to 1000 micrometers can be prepared. The method is widely applied in fields related to paints, adhesives, biomedicines, and 
electronic information.