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48results about How to "Improve volume effect" patented technology

Graphene-silicon composite lithium ion battery negative electrode and preparation method thereof

The invention provides a graphene-silicon composite lithium ion battery negative electrode and a preparation method thereof. The graphene-silicon composite lithium ion battery negative electrode is characterized by comprising copper foil and a multi-layer structure arranged on the copper foil, the multi-layer structure comprises graphene layers and silicon-carbon nanotube layers which are arrangedat intervals, and each silicon-carbon nanotube layer comprises silicon nanoparticles and carbon nanotubes, wherein the silicon nanoparticles are coated with the carbon nanotubes. The laminar composite can be applied to a lithium ion battery by serving as a negative electrode material. The negative electrode material has the advantages of being high in specific capacity, stable in cycling performance and the like. By means of the simple step, the silicon nanoparticles are successfully coated with the graphene and the carbon tubes, the volume effect of the silicon material in the charging and discharging process is improved through the laminar special structure, and the conductivity of the electrode is improved by means of the condition of the graphene and the carbon nanotubes, so that theelectrode material is high in specific capacity and coulomb efficiency and good in cycling performance finally.
Owner:上海超碳石墨烯产业技术有限公司 +1

Method for preparing spherical ultrafine nickel powder at room temperature

ActiveCN102962470AHigh specific surface activityImprove conductivityNickel saltMetallurgy
The invention relates to a method for preparing spherical ultrafine nickel powder at a room temperature, which belongs to the technical field of the preparation of function powder materials, and solves the problems of the prior art that the ultrafine nickel powder cannot be prepared at the room temperature. The method comprises the following steps of (1) placing surface active agent into aqueous solution of nickelous salt at the temperature of 20DEG C to 25DEG C to prepare nickel salt active solution; (2) placing aqueous alkali into hydrazine or hydrazine hydrate at the temperature of 20DEG C to 25DEG C, and adjusting the pH value to 12 to 14 to prepare the alkali reducing agent; (3) slowly adding the nickel salt active solution into the alkali reducing agent during the intense agitation process at the temperature of 20DEG C to 25DEG C to be reacted for 30min, and obtaining reaction mixture; and (4) pumping and filtering the reaction mixture at the temperature of 20DEG C to 25DEG C to obtain solids, washing the obtained solids to be neutral through the deionized water, washing the solids for three times through acetone, and then placing the solids into a drying box at the temperature of 60DEG C to be dried, and thus preparing the spherical ultrafine nickel powder. Due to the adoption of the method, the spherical ultrafine nickel powder can be prepared at the room temperature, the cost is low, and convenience in operation can be realized.
Owner:KUNMING SHUYANG TECH

Tin-based composite thin film material for lithium ion battery as well as preparation method and application of thin film material

The invention provides a tin-based composite thin film material for a lithium ion battery. The tin-based composite thin film material is composed of a copper foil base or a foam copper base and an Sn-M thin film by stacking, wherein the Sn-M thin film is a thin film with a single-layered structure, and is composed of two elements including Sn and M; the Sn is alpha-Sn or beta-Sn; the M is Ti, Al or Zn; the thickness of the Sn-M thin film is 0.01-10 microns. A preparation method comprises the following step of preparing the Sn-M thin film on the copper foil base or the foam copper base by adopting a simultaneous sputtering process of a metal target Sn and the metal M. The thin film is used as an electrode material of a lithium battery. The tin-based composite thin film material for the lithium ion battery has the advantages that compared with a pure Sn film, the metal M is added so that the volume effect problems caused by embedding lithium ions on an electrode and releasing the lithium ions are inhibited, the circulating performance of the Sn is improved and the cycle life of a thin film cathode is prolonged. The method adopts a simple thin film preparation process; the production cost is reduced and the repeatability of preparing a thin-film material is improved; the tin-based composite thin film material for the lithium ion battery is hopeful to be applied to thin film type lithium batteries with high energy and high power.
Owner:NANKAI UNIV

Titanium oxide@C hollow composite framework embedded with precious metal silver, and preparation method and application thereof

The invention belongs to the field of lithium metal battery negative electrode materials, and particularly discloses a titanium oxide@C hollow composite framework embedded with precious metal silver, and a preparation method and application thereof. The hollow composite framework comprises a titanium oxide hollow ball with an independent closed cavity, precious metal silver nanoparticles embedded in an inner cavity of the titanium oxide hollow ball, a carbon layer compounded on the surface of titanium oxide and a nitrogen-containing functional group. The preparation method comprises the following steps: preparing a SiO2@Ag composite template uniformly loaded with silver nanoparticles by using a silicon dioxide template, adding a titanium source, hydrolyzing, obtaining a titanium oxide precursor on the outer layer of the composite template, then carrying out in-situ polymerization to obtain a nitrogen-doped carbon-coated composite skeleton precursor, roasting at a certain temperature, and etching the silicon dioxide template with a strong alkali to obtain the titanium oxide@C hollow composite framework embedded with noble metal silver. The composite hollow framework material has a closed cavity structure, good conductivity and excellent gradient lithium affinity, the nucleation overpotential of lithium deposition is reduced, lithium metal is selectively induced to be deposited into the cavity structure, the interface side reaction and the volume effect are greatly avoided, the growth of lithium dendrites is inhibited, favorable conditions are created for uniform lithium deposition / dissolution, and the coulombic efficiency and the cycling stability of the lithium metal battery are remarkably improved.
Owner:CENT SOUTH UNIV

Lithium ion battery negative electrode and preparation method thereof

The invention discloses a lithium ion battery negative electrode and a preparation method thereof, and belongs to the technical field of lithium-ion batteries. The specific scheme is as follows: the lithium ion battery negative electrode comprises a negative electrode current collector and a negative electrode coating, the negative electrode coating comprises a coating I and a coating II which arerespectively coated on two surfaces of the negative electrode current collector, the coating I comprises a negative electrode active material I, a conductive agent, a thickening agent I, a dispersingagent I and a binding agent I, the coating II comprises a negative electrode active material II, a conductive agent, a thickening agent II, a dispersing agent II and a binding agent II, the viscosityof the thickening agent I is greater than that of the thickening agent II, the viscosity of the dispersing agent I is greater than that of the dispersing agent II, the elastic modulus of the bindingagent I is greater than that of the binding agent II, and the high-viscosity thickening agent I, the high-viscosity dispersing agent I and the high-elastic modulus binding agent I are used in negativeelectrode slurry A, so that the consumption of the thickening I, the dispersing agent I and the binding I can be reduced, the consumption of the conductive agent is increased, and the dynamic performance of a long coating paste layer of the negative electrode is further improved.
Owner:ZHUHAI COSMX BATTERY CO LTD

Method for preparing lithium battery silicon carbide negative electrode composite material

The invention discloses a method for preparing a lithium battery silicon carbide negative electrode composite material. The method comprises the following steps: ultrasonically cleaning silicon scrapsin a solvent to clean away surface dirt, and drying the cleaned silicon scraps to obtain a silicon material; crushing the obtained silicon material to a submicron level, and stirring and dispersing obtained silicon particles and a carbon source in a solvent to obtain a uniform turbid solution; carbonizing the obtained turbid solution a high temperature in an inert atmosphere to obtain a silicon carbide powder; and grinding the silicon carbide powder to obtain the lithium battery silicon carbide negative electrode composite material. Liquid state doping in the whole process is simple and is easy to implement; the obtained silicon carbide material is a porous spherical or spheroidal structure, and includes a porous Si-SiOx core and an amorphous carbon shell coating the surface of the core,so the volumetric effect of silicon is greatly improved, and the electrochemical stability is significantly improved; and the preparation method has the advantages of low preparation cost, simple andcontrollable process, and suitableness for large-scale industrial production.
Owner:HUNAN JIUHUA CARBON HI TECH

Preparation method of silicon carbon negative electrode material, silicon carbon negative electrode material and lithium ion battery

The invention belongs to the technical field of a lithium ion battery, and relates to a silicon carbon negative electrode material and a preparation method therefor, and the lithium ion battery. The preparation method for the silicon carbon negative electrode material comprises the following steps of (a), by taking silicon monoxide as the substrate material, performing heating treatment on siliconmonoxide to enable silicon monoxide to be subjected to a disproportionation reaction to generate c-SiO; (b), putting c-SiO into a chemical vapor deposition furnace, heating in protective atmosphere until a reaction temperature is reached, and pumping a carbon source to be subjected to a vapor deposition reaction to obtain c-SiO / C, wherein the carbon source is a liquid-state or solid-state compound; and (c), performing corrosion of the c-SiO / C by a corrosive liquid to obtain the silicon carbon negative electrode material c-SiO / Si / C. The preparation method is simple in process and easy to operate; and the prepared silicon carbon negative electrode material has the high lithium storage characteristic as the silicon type material and the high cycling stability as the carbon type material, aswell as high specific capacity, high conductivity and high cycling performance.
Owner:NORTHERN ALTAIR NANOTECH CO LTD +1
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