The invention belongs to the technical field of oil-proof paper, and discloses
fluoride-free oil-proof paper as well as a preparation method and an application thereof. The preparation method of the oil-proof paper comprises the following steps: putting a
sodium hydroxide /
urea / water solution into a refrigerator for precooling, moving out the
mixed solution, adding dissolved pulp, stirring the mixture at
room temperature, and then placing the mixture into the refrigerator for freezing treatment; moving out the mixture after a period of time, and unfreezing the mixture at
room temperature; carrying out centrifugal treatment, and collecting supernate to obtain a transparent
cellulose coating;
coating paper with the obtained
cellulose coating, then soaking the paper in a coagulating bath, andcoagulating the coating for a period of time at a certain temperature; and
drying the paper to obtain the
fluoride-free oil-proof paper. According to the invention, a
cellulose regeneration method isadopted to cover the surface of the paper, so that
hydrogen bonds among cellulose are rearranged, pores are reduced, and the paper has good barrier property on
grease, organic solvents,
water vapor and the like. The
fluoride-free oil-proof paper provided by the invention can be used in the field of
food packaging, and has a good application prospect in preparation of disposable tableware.